Publications Prof. Dr. Waldemar Adam

Publications

Prof. Dr. Waldemar Adam

Acylic Peroxides - Azoalkanes - CIDNP - Chemical Education - Chemiluminscence - Computational - Cyclic Peroxide - Cycloaddition - DNA Oxidations - Dioxetanes - Dioxiranes - Diradicals - Electron Transfer - Energy Transfer - Enolates - Enzymes - Lactones - Metal-Catalyzed Oxidations - Miscellaneous - Oxidations (not metals) - Patents - Peroxy Lactones - Photobiology - Photochemistry (185 nm) - Photochemistry (General) - Photochemistry (Laser) - Photochemistry (multiple photons) - Polyradicals - Radical Cations - Radicals - Reviews - Singlet Oxygen - Sulfur - Thianthrene 5-Oxide - Triazolinediones - Triplets - Valence Isomerizations - X-Ray - Zeolites -

Acylic Peroxides(158)

1001
Kilic, H.; Adam, W.; Alsters, P.L.
Effect of Additives on Chemoselectivity and Diastereoselectivity in the Catalytic Epoxiation of Chiral Allylic Alcohols with Hydrogen Peroxide and Binuclear Manganese Complexes
J. Org. Chem., 2009, 74, 1135-1140

999
Alsters, P.L.;Witte, P.T.; Neumann, R.; Rozner, D.S.; Adam, W.; Zhang, R.; Reedijk, J.; Gamez, P.; ten Elshof, J.T.; Chowdhury, S.R.
Fine-Tuning and Recycling of Homogeneous Tungstate and Polytungstate Epoxydation Catalysts
in Mechanisms in Homogeneous and Heterogeneous Epoxydation Catalysis, Oyama S. T.,Ed.; Elsevier B.V.: Amsterdam 2008; Chap. 16, pp. 415-428

991
Aubry, J.-M.; Adam, W.; Alsters, P.L.; Borde, C.; Queste, S.; Marko, J.; Nardello, V
Dark Singlet Oxygenation of Organic Substrates in Single-Phase and Multiphase Microemulsion Systems
Tetrahedron, 2006, 62, 10753-10761

980
Adam, W.; Kazakov, D.V.; Kazakov, V.P.
Singlet-Oxygen Chemiluminescence in Peroxide Reactions
Chem. Rev., 2005, 105, 3371-3387

978
Pastor, A.; Adam, W.; Wirth, T.; Tóth, G.
Diastereoselective Reactions of the Tiglic-Acid Functionality Mediated by the Oxazolidine Chiral Auxiliary: A Mechanistic Comparison of the DMD and m-CPBA Epoxidations versus the Singlet-Oxygen and PTAD Ene Reactions
Eur. J. Org. Chem., 2005, 3075-3084

974
Adam, W.; Kazakov, V.P.; Kazakov, D.V.; Latypova, R.R.; Maistrenko, G.Y.; Mal'zev, D.V.; Safarov, F.E.
On the Role of Singlet-Oxygen Dimol Chemiluminescence in Oxirane Reactions.
In Proceedings of the 13th International Symposium on Bioluminescence and Chemiluminescence; Tsuji, A., Maeda, M., Matsumoto, 2005; pp 135-138

973
Adam, W.; Zhang, A.
Chiral-Auxiliary-Controlled Stereoselective Epoxidation of CC Double Bonds
Synlett, 2005, 1047-1073

970
Nardello, V.; Caron, L. ; Aubry, J.-M.; Bouttemy, S.; Wirth, T.; Saha-Möller, C.R. ; Adam, W.
Reactivity, Chemoselectivity and Diastereoselectivity of the Oxyfunctionalization of Chiral Allylic Alcohols and Derivatives in Microemulsions : Comparison of the Chemical Oxidation by the Hydrogen Peroxide/Sodium Molybdate System with the Photooxygenation
J. Am. Chem. Soc., 2004, 126, 10692-10700

965
Adam, W.; Bosio, S.G.; Turro, N.J.; Wolff, B.T.
Enecarbamates as Selective Substrates in Oxidations: Chiral-Auxiliary-Controlled Mode Selectivity and Diastereoselectivity in the [2+2] Cycloaddition and Ene Reaction of Singlet Oxygen and in the Epoxidation by DMD and mCPBA
J. Org. Chem., 2004, 69, 1704-1715

955
Griesbeck, A.G.; Bartoschek, A.; Adam, W.; Bosio, S.G.
Photooxygenation of 1,3-Dienes
In Handbook of Organic Photochemistry and Photobiology, 2nd ed.; Horspool, W. M., Lenci, F. (Eds.); CRC Press, Inc.: London 2003; Chap. 25, pp 1-19

954
Griesbeck, A.G.; El-Idressy, T.T.; Adam, W.; Krebs, O.
Ene Reactions with Singlet Oxygen
In Handbook of Organic Photochemistry and Photobiology, 2nd ed.; Horspool, W. M.; Lenci, F.(Eds.); CRC Press, Inc.: London 2003; Chap. 8, pp 1-20

953
Adam, W.; Gogonas, E.P.; Hadjiarapoglou, L.P.
A Facile Diastereoselctive Synthesis of Functionalized 1,2,3-Trisubstituted Benzocyclopentenes through the Cycloaddition of Bis(phenylsulfonyl)iodonium Ylides to Cyclic Alkenes
J. Org. Chem., 2003, 68, 9155-9159

949
Sinicropi, A.; Page, C.S.; Adam, W.; Olivucci, M.
A Computational Study on the Origin of the Stereoselectivity for the Photochemical Denitrogenation of Diazabicycloheptene
J. Am. Chem. Soc., 2003, 125, 10947- 10959

944
Griesbeck, A.G.; Adam, W.; Bartoschek, A.; El-Idreesy, T.T.
Photooxygenation of Allylic Alcohols: Kinetic Comparison of Unfunctionalized Alkenes with Prenol-Type Allylic Alcohols, Ethers and Acetates
Photochem. Photobiol. Sci., 2003, 2, 877-881

940
Adam, W.; Beck, A.K.; Pichota, A.; Saha-Möller, C.R.; Seebach, D.; Vogl, N.; Zhang, R.
Control of Enantioselectivity Through a Hydrogen-Bonded Template in the Vanadium(V)-Catalyzed Epoxidation of Allylic Alcohols by Optically Active Hydroperoxides
Tetrahedron: Asymmetry, 2003, 14, 1355-1361

938
Adam, W.; Bosio, S.G.; Wolff, B.T.
Chiral-Auxiliary-Controlled Diastereoselectivity in the Epoxidation of Enecarbamates with DMD and m-CPBA
Org. Lett., 2003, 5, 819-822

937
Adam, W.; Alsters, P.L.; Neumann, R.; Saha-Möller, C.R.; Seebach, D.; Zhang. R.
Highly Efficient Catalytic Asymmetric Epoxidation of Allylic Alcohols by an Oxovanadium-Substituted Polyoxometalate with a Regenerative TADDOL-Derived Hydroperoxide
Org. Lett., 2003, 5, 725-728

930
Bach, R.D.; Dmitrenko, O.; Adam, W.; Schambony, S.B.
Relative Reactivity of Peracids versus Dioxiranes (DMDO and TFDO) in the Epoxidation of Alkenes. A Combined Experimental and Theoretical Analysis
J. Am. Chem. Soc., 2003, 125, 924-934

921
Stratakis, M.; Nencka, R.; Rabalakos, C.; Adam, W.; Krebs, O.
Thionin-Sensitized Intrazeolite Photooxygenation of Trisubstituted Alkenes: Substituent Effects on the Regioselectivity As Probed Through Isotopic Labelling
J. Org. Chem., 2002, 67, 8758-8763

920
Adam, W.; Bosio, S.G.; Turro, N.J.
Control of the Mode Selectivity (Ene Reaction versus [2+2] Cycloaddition) in the Photooxygenation of Ene Carbamates: Directing Effect of an Alkenylic Nitrogen Functionality
J. Am. Chem. Soc., 2002, 124, 14004-14005

919
Adam, W.; Alsters, P.L.; Neumann, R.; Saha-Möller, C.R.; Sloboda-Rozner, D.; Zhang, R.
A New Highly Selective Method for the Catalytic Epoxidation of Chiral Allylic Alcohols by Sandwich-Type Polyoxometalates with Hydrogen Peroxide
Synlett, 2002, 2011-2014

918
Adam, W.; Bottke, N.; Krebs, O.; Lykakis, I.; Orfanopoulos, M.; Stratakis, M.
Ene Reaction of Singlet Oxygen, Triazolinedione and Nitrosoarene with Chiral Deuterium-Labelled Allylic Alcohols: The Interdependence of Diastereoselectivity and Regioselectivity Discloses Mechanistic Insights into the Hydroxy-Group Directivity
J. Am. Chem. Soc., 2002, 124, 14403-14409

912
Adam, W.; Bosio, S.G.; Degen, H.-G.; Krebs, O.; Schumacher, D.; Stalke, D.
A Comparative Study on the Diastereofacial Control in the [4+2] Cycloaddition of Sorbates and the Ene Reaction of Tiglates with Singlet Oxygen and PTAD by a Variety of Chiral Auxiliaries
Eur. J. Org. Chem., 2002, 3944-3953

911
Adam, W.; Degen, H.-G.; Krebs, O.; Saha-Möller, C.R.
Efficient p-Facial Control in the Ene Reaction of Nitrosoarene, Triazolinedione and Singlet Oxygen with Tiglic Amides of the Bornane-Derived Sultam as Chiral Auxiliary: An Economical Synthesis of Enantiomerically Pure Nitrogen- and Oxygen-Functionalized Acrylic Acid Derivatives
J. Am. Chem. Soc., 2002, 124, 12938-12939

882
Adam, W.; Bheema, Rao; P.; Degen, H.-G.; Saha-Möller, C.R.
Asymmetric Weitz-Scheffer Epoxidation of a,b-Enones by Optically Active Hydroperoxides: Control of Enantioselectivity through Metal-Coordinated or Hydrogen-Bonded Templates
Eur. J. Org. Chem., 2002, 630-639

880
Adam, W.; Bheema Rao, P.; Degen, H.-G.; Lévai, A.; Patonay, T.; Saha-Möller, C.R.
Asymmetric Weitz-Schefffer Epoxidation of Isoflavones with Hydroperoxides, Mediated by Optically Active Phase-Transfer Catalysts
J. Org. Chem., 2002, 67, 259-264

876
Bolm, C.; Beckmann, O.; Kühn, T.; Palazzi, C.; Adam, W.; Bheema Rao, P.; Saha-Möller, C.R.
Influence of Hydroperoxides on the Enantioselectivity of the Metal-Catalyzed Asymmetric Baeyer-Villiger Oxidation and Epoxidation with Chiral Ligands
Tetrahedron: Asymmetry, 2001, 12, 2441-2446

874
Adam, W.; Saha-Möller, C.R.; Schmid, K.S.
The Synthesis of 4,6-Dideoxyfuranoses through the Regioselective and Diastereoselective Oxyfunctionalization of a Dimethylphenylsilyl-Substituted Chiral Homoallylic Alcohol
J. Org. Chem., 2001, 66, 7365-7371

859
Adam, W., Bheema Rao, P.; Degen, H.-G.; Saha-Möller, C.R.
Asymmetric Weitz-Scheffer Epoxidation of Conformationally Flexible and Fixed Enones with Sterically Demanding Hydroperoxides Mediated by Optically Active Phase-Transfer Catalysts
Tetrahedron: Asymmetry, 2001, 12, 121-125

853
Adam, W.; Kurz, A.; Saha-Möller, C.R.
Peroxidase-Catalyzed Oxidative Damage of DNA and 2'-Deoxyguanosine by Model Compounds of Lipid Hydroperoxides: Involvement of Peroxyl Radicals
Chem. Res. Toxicol., 2000, 13, 1199-1207

847
Adam, W.; Degen, H.-G.; Pastor, A.; Saha-Möller, C.R.; Schambony, S.B.; Zhao, C.-G.
Preparative Use of Peroxidic Oxidants for Oxygen-Transfer Reactions
In DFG Research Report on Peroxide Chemistry: Mechanistic and Preparative Aspects of Oxygen Transfer; Adam, W., Ed; Wiley-VCH 2000; pp 78-112

842
Adam, W.; Bach, R.D.; Dmitrenko, O.; Saha-Möller, C.R.
A Computational Study of the Hydroxy-Group Directivity in the Peroxyformic Acid Epoxidation of the Chiral Allylic Alcohol (Z)-3-Methyl-3-penten-2-ol: Control of threo Diastereoselectivity through Allylic Strain and Hydrogen Bonding
J. Org. Chem., 2000, 65, 6715-6728

829
Adam, W.; Peters, K.; Peters, E.-M., Schambony, S.B.
Diastereoselective and Regioselective Singlet-Oxygen Ene Reaction of Oxazolidine-Substituted Alkenes: Control through Hydrogen Bonding Mediated by the Urea Functionality of Chiral Auxiliaries
J. Am. Chem. Soc., 2000, 122, 7610-7611

821
Adam, W.; Bheema Rao, P.; Degen, H.-G., Saha-Möller, C.R.
Metal-Template Effect in the Asymmetric Weitz-Scheffer Epoxidation of a,ß Enones by an Optically Active Hydroperoxide
J. Am. Chem. Soc., 2000, 122, 5654-5655

820
Adam, W.; Lukacs, Z.; Saha-Möller, C.R.; Schreier, P.
Biocatalytic Kinetic Resolution of Racemic Hydroperoxides through the Enantioselective Reduction with Free and Immobilized Microorganisms
J. Am. Chem. Soc., 2000, 122, 4887-4892

797
Adam, W.; Saha-Möller, C.R.; Schmid, K.S.
Preparation of Optically Active Allylic Hydroperoxy Alcohols and 1,3 Diols by Enzyme-Catalyzed Kinetic Resolution and Photooxygenation of Chiral Homoallylic Alcohols
J. Org. Chem., 2000, 65, 1431-1433

792
Andina, E.S.; Kyagova, A. A.; Yurikova, N.N.; Neklyukova, M.B.; Potapenko, A.Y.; Adam, W.; Saha-Moeller, C.R.
Immunosuppression Induced by the Photooxidation Products of Furocoumarins (Psoralens)
In Proceedings of the Symposium on Biologic Effects of Light; Holick, M.F., Jung, E.G. , Eds.;. Kluwer Academic Publishers: H 1999; pp 213-216

787
Adam, W.; Lazarus, M.; Saha-Möller, C.R.; Schreier, P.
Biocatalytic Synthesis of Optically Active a-Oxyfunctionalized Carbonyl Compounds
Acc. Chem. Res., 1999, 32, 837-845

786
Adam, W.; Saha-Möller, C.R.; Schambony, S.; Schmid, K.S.; Wirth, T.
Stereocontrolled Photooxygenations - A Valuable Synthetic Tool
Photochem. Photobiol., 1999, 70, 476-483

780
Adam, W.; Mock-Knoblauch, C.; Saha-Möller, C.R.
Asymmetric Synthesis with the Enzyme Coprinus Peroxidase: Kinetic Resolution of Chiral Hydroperoxides and Enantioselective Sulfoxidation
J. Org. Chem., 1999, 64, 4834-4839

775
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.
Regio- and Diastereoselective Catalytic Epoxidation of Acyclic Allylic Alcohols with Methyltrioxorhenium: A Mechanistic Comparison with Metal (Peroxy and Peroxo Complexes) and Nonmetal (Peracids and Dioxirane) Oxidants
J. Org. Chem., 1999, 64, 3699-3707

770
Adam, W.; Lukacs, Z.; Saha-Möller, C.R.; Schreier, P.
Biotransformation of (1-Phenyl)ethyl Hydroperoxide with Aspergillus Niger: A Model Study on Enzyme Selectivity and on the Induction of Peroxidase Activity
Biochim. Biophys. Acta, 1999, 1427, 236-244

767
Potapenko, A.-Y.; Kyagova, A.A.; Andina, E.S.; Zhuravel, N.N.; Lysenko, E.P.; Möller, M.; Stopper, H.; Adam, W.; Saha-Möller, C.R.
Photohemolysis Sensitized by the Furocoumarin Imperatorin and its Oxyfunctionalized Derivatives
Photochem. Photobiol., 1999, 69, 410-420

765
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.
Steric and Electronic Effects in the Diastereoselective Catalytic Epoxidation of Cyclic Allylic Alcohols with Methyltrioxorhenium (MTO)
Eur. J. Org. Chem., 1999, 785-790

763
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.; Weichold, O.
Host-Guest Chemistry in a Urea Matrix: Catalytic and Selective Oxidation of Triorganosilanes to the Corresponding Silanols by Methyltrioxorhenium and the Urea/Hydrogen Peroxide Aduct
J. Am. Chem. Soc., 1999, 121, 2097-2103

761
Adam, W.; Stegmann, V.R.; Saha-Möller, C.R.
Regio- and Diastereoselective Epoxidation of Chiral Allylic Alcohols Catalyzed by Manganese(salen) and Iron(porphine) Complexes
J. Am. Chem. Soc., 1999, 121, 1879-1882

759
Adam, W.; Degen, H.-G.; Saha-Möller, C.R.
Regio- and Diastereoselective Catalytic Epoxidation of Chiral Allylic Alcohols with Hexafluoroacetone Perhydrate. Hydroxy-Group Directivity through Hydrogen Bonding
J. Org. Chem., 1999, 64, 1274-1277

755
Häring, D.; Schüler, E.; Adam, W.; Saha-Möller, C.R.; Schreier, P.
Semisynthetic Enzymes in Asymmetric Synthesis: Enantioselective Reduction of Racemic Hydroperoxides
J. Org. Chem., 1999, 64, 832-835

753
Adam, W.; Lazarus, M.; Saha-Möller, C.R.; Weichold, O.; Hoch, U.; Häring, D.; Schreier, P.
Biotransformations with Peroxidases.
In Advances in Biochemical Engineering/Biotechnology; Faber, K., Ed.; Springer Verlag: Heidelberg, 1998; Vol. 63, pp 73-108

741
Adam, W.; Boss, B.; Harmsen, D.; Lukacs, Z.; Saha-Möller, C.R.; Schreier, P.
The Kinetic Resolution of Chiral Hydroperoxides: Hydrogen-Peroxide-Mediated Screening of Peroxidase-Active Soil Bacteria
J. Org. Chem., 1998, 63, 7598-7599

740
Adam, W.; Boland, W.; Hartmann-Schreier, J., Humpf, H.-U.; Lazarus, M.; Saha-Möller, C.R.; Saffert, A.; Schreier, P.
a Hydroxylation of Carboxylic Acids with Molecular Oxygen Catalyzed by the a Oxidase of Peas (Pisum sativum): A Novel Biocatalytic Synthesis of Enantiomerically Pure (R)-2-Hydroxy Acids
J. Am. Chem. Soc., 1998, 120, 11044-11048

737
Adam, W.; Arnold, M.A.; Grimm, G.N.; Saha-Möller, C.R.; Dall'Acqua, F.D.; Miolo, G.; Vedaldi, D.
4-tert-Butylperoxymethyl-9-methoxypsoralen as Intercalating Photochemical Alkoxyl-Radical Source for Oxidative DNA Damage
Photochem. Photobiol., 1998, 68, 511-518

733
Adam, W.; Lazarus, M.; Hoch, U.; Korb, M.N.; Saha-Möller, C.R.; Schreier, P.
Horseradish-Peroxidase-Catalyzed Enantioselective Reduction of Racemic Hydroperoxy Homoallylic Alcohols: A Novel Enzymatic Method for the Preparation of Optically Active, Unsaturated Diols and Hydroperoxy Alcohols
J. Org. Chem., 1998, 63, 6123-6127

732
Adam, W.; Grimm, G.N.; Saha-Möller, C.R.; Dall'Acqua, F.; Miolo, G.; Vedaldi, D.
DNA Damage by tert-Butoxyl Radicals Generated in the Photolysis of a Water-Soluble, DNA-Binding Peroxyester as Radical Source
Chem. Res. Toxicol., 1998, 11, 1089-1097

724
Adam, W.; Korb, M.N.; Roschmann, K.J.; Saha-Möller, C.R.
Titanium-Catalyzed, Asymmetric Sulfoxidation of Alkyl Aryl Sulfides with Optically Active Hydroperoxides
J. Org. Chem., 1998, 63, 3423-3428

717
Aubry, J.M.; Nardello, V.; Bouttemy, S.; Wirth, T.; Linker, T.; Adam, W.
The Luminous and the Dark Side of Singlet Oxygen: Comparison Between Photochemical and Chemical Sources of Singlet Oxygen (¹O₂, 1Dg) in Organic Synthesis
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier Eds.; Vieweg Verlag: Braunschweig 1998; pp 277-281

716
Elias, H.; Stock, F.; Adam, W.; Mitchell, C.M.; Neuburger, M.
Salen-Type Oxo Vanadium Complexes as Catalysts for Sulfoxidation and Epoxidation Reactions with Hydroperoxides
In Selective Reactions of Metal-Activated Molecules; H.Werner; P. Schreier Eds.; Vieweg Verlag: Braunschweig 1998; pp 251-255

695
Adam, W.; Renze, J.; Wirth, T.
Stereoelectronic Control of the Diastereoselectivity in the Photooxygenation (Schenck Ene Reaction) of an Electron-Poor Allylic Alcohol and its Ethers
J. Org. Chem., 1998, 63, 226-227

692
Adam, W.; Andler, S.; Saha-Möller, C.R.
DNA Cleavage Induced by Oxyl Radicals Generated in the Photosensitized Decomposition of Fatty Ester Hydroperoxides Derived from Oleic and Linoleic Acid
Arch. Biochem. Biophys., 1998, 349, 261-266

685
Adam, W.; Wirth, T.
Electronic, Steric and Stereoelectronic Effects in the Diastereoselective Photooxygenation (Schenck Ene Reaction) of Acyclic Chiral Alkenes
In Actas de la 26a Reunion Bienal de la Real Sociedad Espanola de Quimica, C. M. Gordillo, Ed.; Servicio de Publicaciones de 1997; pp 191-198

683
Adam, W.; Blancafort, L.; Saha-Möller, C.R.
Kinetic Resolution of Racemic Halohydrins, Precursors of Optically Active Di- and Trialkyl-Substituted Epoxides, with Lipase from Pseudomonas sp.
Tetrahedron: Asymmetry, 1997, 8, 3189-3192

678
Adam, W.; Groer, P.; Mielke, K.; Saha-Möller, C.R.; Kiefer, W.; Nagel, V.; Schneider, F.W.; Ballmaier, D.; Schleger, Y.; Epe, B.
Photochemical and Photobiological Studies with Acridine and Phenanthridine Hydroperoxides in Cell-Free DNA
Photochem. Photobiol., 1997, 66, 26-33

675
Adam, W.; Mock-Knoblauch, C.; Saha-Möller, C.R.
Biocatalytic Kinetic Resolution of Hydroperoxy Vinylsilanes by Horseradish Peroxidase (HRP) and Lipases, a Comparative Study
Tetrahedron: Asymmetry, 1997, 12, 1947-1950

667
Adam, W.; Peters, K.; Renz, M.
Titanium-Catalyzed Diastereoselective Epoxidations of Ene Diols and Allylic Alcohols with b-Hydroperoxy Alcohols as Novel Oxygen Donors
J. Org. Chem., 1997, 62, 3183-3189

665
Hoch, U.; Humpf, H.-U.; Schreier, P.; Saha-Möller, C.R.; Adam, W.
Configurational Assignment of Optically Active Hydroperoxy Homoallylic Alcohols and the Corresponding Diols by Circular Dichroism and Multidimensial Gas Chromatography
Chirality, 1997, 69-74

664
Adam, W.; Korb, M.
The Titanium-Catalyzed, Asymmetric Epoxidation of Allylic Alcohols with Optically Active Hydroperoxides in the Presence of Achiral Diol Ligands
Tetrahedron: Asymmetry, 1997, 8, 1131-1142

661
Hoch, U.; Adam, W.; Fell, R.T.; Saha-Möller, C.R.; Schreier, P.
Horseradish Peroxidase - A Biocatalyst for the One-Pot Synthesis of Enantiomerically Pure Hydroperoxides and Alcohols
J. Mol. Cat., 1997, 117A, 321-328

654
Kyagova, A.A.; Zhuravel, N.N.; Malakhov, M.V.; Lysenko, E.P.; Adam, W.; Saha-Möller, C.R.; Potapenko, A.Y.
Suppression of Delayed Type Hypersensitivity and Hemolysis Induced by Previously Photooxidized Psoralen: Effect of Fluence Rate and Psoralen Concentration
Photochem. Photobiol., 1997, 65, 694-700

648
Schulz, M.; Liebsch, S.; Kluge, R.; Adam, W.
Organo Sulfonic Peracids, 41: The Reaction of Arenesulfonylimidazoles with H₂O₂ in the Presence of Ketones - A New Entry to Dioxetanes
J. Org. Chem., 1997, 62, 188-193

644
Reddy, T.I.; Adam, W.; Renz, M.
Diastereoselective Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by Titanium Silicate (TS-1 or Ti-beta)
In Book of Abstracts, 211th ACS National Meeting, New Orleans; American Chemical Society: Washington, D. C., 1996; Abstract ORGN-160

642
Adam, W.; Hoch, U.; Humpf, H.-U.; Saha-Möller, C.R., Schreier, P.
Horseradish- Peroxidase(HRP)-Catalyzed Enantioselective Reduction of Racemic Hydroperoxy Homoallylic Alcohols: A Novel Enzymatic Method for the Preparation of Optically Active, Unsaturated Diols and Hydroperoxy Alcohols
Chem. Commun., 1996, 2701-2702

635
Adam, W.; Corma, A.; Martinez, A.; Renz, M.
The Mechanism of the Double-Bond Cleavage in the Titanium-Zeolite-Catalyzed Oxidation of a-Methylstyrene by Hydrogen Peroxide: The b-Hydroperoxy Alcohol as Intermediate
Chem. Ber., 1996, 129, 1453-1455

629
Adam, W.; Golsch, D.; Sundermeyer, J.; Wahl, G.
Activation of Bis(trimethylsilyl) Peroxide and tert-Butyl Hydroperoxide with Oxo and Peroxo Complexes of Vanadium, Molybdenum and Tungsten for the Sulfoxidation of Thianthrene 5-Oxide
Chem. Ber., 1996, 129, 1177-1182

626
Adam, W.; Lazarus, M.; Saha-Möller, C.R., Schreier, P.
Enantioselective a Hydroxylation of Carboxylic Acids with Molecular Oxygen Catalyzed by the a-Oxidation Enzyme System of Young Pea Leaves (Pisum Sativum): A Substrate Selectivity Study
Tetrahedron: Asymmetry, 1996, 7, 2287-2292

625
Adam, W.; Diáz, M.T.; Fell, R.T.; Saha-Möller, C.R.
Kinetic Resolution of Racemic a-Hydroxy Ketones by Lipase-Catalyzed Irreversible Transesterification
Tetrahedron: Asymmetry, 1996, 7, 2207-2210

622
Adam, W.; Andler, S.; Saha-Möller, C.R.; Schönberger, A.
Inhibitory Effect of Ethyl Oleate Hydroperoxide and Alcohol in Photosensitized Oxidative DNA Damage
J. Photochem. Photobiol., 1996, 34B, 51-58

621
Adam, W.; Halász, J.; Jámbor, Z.; Lévai, A.; Nemes, C.; Patonay, T.; Tóth, G.
Stereoselective Epoxidation of 2-Arylidene-1-indanones and 2-Arylidene-1-benzosuberones
Monatshefte, 1996, 127, 683-690

618
Adam, W.; Berger, M.; Cadet, J.; Dall'Acqua, F.; Epe, B.; Frank, S.; Ramaiah, D.; Raoul, S.; Saha-Möller, C.R.; Vedaldi, D.
Photochemistry and Photobiology of Furocoumarin Hydroperoxides Derived from Imperatorin: Novel Intercalating Photo-Fenton Reagents for Oxidative DNA Modification by Hydroxyl Radicals
Photochem. Photobiol., 1996, 63, 768-778

599
Ganeshpure, P.A.; Adam, W.
a-Hydroxy Hydroperoxides (Perhydrates) as Oxygen Transfer Agents in Organic Synthesis
Synthesis, 1996, 179-188

595
Adam, W.; Brünker, H.-G.; Sampath Kumar, A.; Peters, E.-M.; Peters, K.; Schneider, U.; von Schnering, H.G.
Diastereoselective Singlet-Oxygen Ene Reaction (Schenck Reaction) and Diastereoselective Epoxidation of Heteroatom-Substituted Acyclic Chiral Olefins: A Mechanistic Comparison
J. Am. Chem. Soc., 1996, 118, 1899-1905

592
Prein, M.; Adam, W.
The Schenck Ene Reaction: Diastereoselective Oxyfunctionalization with Singlet Oxygen in Synthetic Applications
Angew. Chem., 1996, 108, 519-538; Angew. Chem., Int. Ed. Engl., 1996, 35, 477-494

587
Andler, S.; Adam, W.; Saha-Moeller, C.R.
Inhibition of Photosensitized Oxidative DNA Damage by Ethyl Oleate Hydroperoxide and Alcohol
In Book of Abstracts, 210th ACS National Meeting, Chicago; American Chemical Society: Washington, D. C., 1995; Abstract ORGN-378

586
Adam, W.; Fell, R.T.; Hoch, U.; Saha-Moeller, C.R.; Schreier, P.
Kinetic Resolution of Chiral Hydroperoxides with Horseradish Peroxidase
In Book of Abstracts, 210th ACS National Meeting, Chicago; American Chemical Society: Washington, D. C., 1995; Abstract ORGN-057

583
Adam, W.; Ganeshpure, P.A.
Bis(trimethylsilyl) Monoperoxysulfate (CH₃)₃SiOSO₂OOSi(CH₃)₃
In Encyclopedia of Reagents for Organic Synthesis; L.A. Paquette, Ed.; John Wiley and Sons: Chichester 1995; Vol. 1, pp 599-600

582
Adam, W.; Kumar, A.S.; Saha-Möller, C.R.
Synthesis of a-Methylene-b-hydroperoxy Sulfoxides by Regioselective Photooxygenation (Schenck Reaction) of Racemic Vinyl Sulfoxides
Synthesis, 1995, 1525-1528

581
Adam, W.; Griesbeck, A.G.
Formation of C-O Bonds by Allylic Oxidation with Singlet Molecular Oxygen
In Methods of Organic Chemistry (Houben Weyl), Stereoselective Synthesis; G. Helmchen, R.W. Hoffmann, J. Mulzer, E. Schauman, 1995; Vol. 21e, pp 4928-4946

579
Adam, W.; Hoch, U.; Lazarus, M.; Saha-Möller, C.R.; Schreier, P.
Enzyme-Catalyzed Asymmetric Synthesis: Kinetic Resolution of Racemic Hydroperoxides by Enantioselective Reduction to Alcohols with Horseradish Peroxidase
J. Am. Chem. Soc., 1995, 117, 11898-11901

575
Möller, M.; Stopper, H.; Häring, M.; Schleger, Y.; Epe, B.; Adam, W.; Saha-Möller, C.R.
Genotoxicity Induced by Furocoumarin Hydroperoxides in Mammalian Cells upon UVA Irradiation
Biochem. Biophys. Res. Commun., 1995, 216, 693-701

564
Adam, W.; Brünker, H.-G.
Diastereoselective Synthesis of Merucathin: The Singlet-Oxygen Ene Reaction (Schenck Reaction) as Key Step Towards an E-Configured b-Amino Allylic Alcohol
Synthesis, 1995, 1066-1067

546
Adam, W.; Fell, R.T.; Hoch, U.; Saha-Möller, C.R.; Schreier, P.
Kinetic Resolution of Chiral a-Hydroperoxy Esters by Horseradish-Peroxidase-Catalyzed Enantioselective Reduction to a-Hydroxy Esters
Tetrahedron: Asymmetry, 1995, 6, 1047-1050

541
Schulz, M.H.; Kluge, R.; Schüßler, M.; Adam, W.; Prechtl, F.
Stereoselective a-Hydroxylation of Ketones via Titanium Enolates by Using Organic Peroxides
In Selective Reactions of Metal-Activated Molecules. J. Sundermeyer; H. Werner, Eds.; Vieweg-Verlag: Braunschweig 1995; pp 45-48

539
Hoch, U.; Scheller, G.; Schmitt, M.; Schreier, P.; Adam, W.; Saha-Möller, C.R.
Enzymes in Synthetic Organic Chemistry: Selective Oxidoreductions Catalyzed by the Metalloenzymes
In Selective Reactions of Metal-Activated Molecules. J. Sundermeyer; H. Werner, Eds.; Vieweg Verlag: Braunschweig 1995; pp 33-38

538
Brünker, H.-G.; Adam, W.
Diastereoselective and Regioselective Singlet-Oxygen Ene Oxyfunctionalization (Schenck Reaction): Photooxygenation of Allylic Amines and Their Acyl Derivatives
J. Am. Chem. Soc., 1995, 117, 3976-3982

537
Prein, M.; Maurer, M.; Peters, E.-M.; Peters, K.; von Schnering H. G.; Adam, W.
Diastereoselective Synthesis of 4-Hydroperoxy-3,5-cyclohexanediones in the Photooxygenation of Hydroxyethyl-Substituted Phenols
Chem. Eur. J., 1995, 1, 89-94

535
Höft, E.; Hamann, H.-J.; Kunath, A.; Adam, W.; Hoch, U.; Saha-Möller, C.R.; Schreier, P.
Enzyme-Catalyzed Kinetic Resolution of Racemic Secondary Hydroperoxides
Tetrahedron: Asymmetry, 1995, 6, 603-608

525
Adam, W.; Cadet, J.; Dall'Acqua, F.; Epe, B.; Ramaiah, D.; Saha-Möller, C.R.
Photosensitized Formation of 8-Hydroxy-2'-desoxyguanosine in Salmon Testes DNA by Furocoumarin Hydroperoxides: A Novel, Intercalating Photo-Fenton Reagent for Oxidative DNA Damage
Angew. Chem., 1995, 107, 91-94; Angew. Chem., Int. Ed. Engl., 1995, 34, 107-110

522
Hoch, U.; Adam, W.; Saha-Möller, C.R.; Schreier, P.
Kinetische Racematspaltung chiraler Hydroperoxide mit Meerrettichperoxidase
Lebensmittelchemie, 1994, 48, 87-91

510
Adam, W.; Klug, P.
Regio- and Diastereoselective Synthesis of Stannyl Epoxy Alcohols by Direct Hydroxy-Epoxidation of Vinylstannanes
Chem. Ber., 1994, 127, 1441-1445

496
Adam, W.; Richter, M.J.
Highly Regio- and Diastereoselective One-Pot Synthesis of Silyl Epoxy Alcohols and Vinylsilanes by Direct Hydroxy-Epoxidation
J. Org. Chem., 1994, 59, 3341-3346

495
Adam, W.; Richter, M.J.
Regioselectivity of the Singlet Oxygen Ene Reaction (Schenck Reaction) with Vinylsilanes
J. Org. Chem., 1994, 59, 3335-3340

494
Adam, W.; Klug, P.
A Convenient Stereoselective Synthesis of a-Tributylstannyl Enones by Photooxygenation of Vinylstannanes and Dehydration of the Resulting Hydroperoxides
Synthesis, 1994, 557-559

491
Adam, W.; Klug, P.
(Z)-3-Alkylidene-4,5-dihydro-4-hydroxy-5-methyl-2-(3H)-furanones by Regio- and Diastereoselective Ene Reaction of Singlet Oxygen (Schenck Reaction) with g-Hydroxy Vinylstannanes: An Enantioselective Synthesis of Dihydromahubanolide B
Synthesis, 1994, 567-572

485
Adam, W.; Klug, P.
b-Stannyl Allylic Alcohols through Photooxygenation (Schenck Reaction) of Vinylstannanes and Reduction of the Resulting Allylic Hydroperoxides: Synthesis and Selected Transformations
J. Org. Chem., 1994, 59, 2695-2699

483
Adam, W.; Peters, K.; Renz, M.
Tridentate b-Hydroperoxy Alcohols as Novel Oxygen Donors for the Titanium-Catalyzed Epoxidation of g,d-Unsaturated a,b-Diols: A Direct Diastereoselective Synthesis of Epoxy Diols
Angew. Chem., 1994, 106, 1159-1161; Angew. Chem., Int. Ed. Engl., 1994, 33, 1107-1108

482
Adam, W.; Ahrweiler, M.; Sauter, M.
Ring Cleavage of Benzofurans and Tetrahydrobenzofurans by m-Chloroperbenzoic Acid Epoxidation
Chem. Ber., 1994, 127, 941-946

477
Adam, W.; Gevert, O.; Klug, P.
Photooxygenation of g-Hydroxy Vinylstannanes and their Acyl Derivatives: Mechanistic Insight into the Hydroxy-Directing Effect
Tetrahedron Lett., 1994, 35, 1681-1684

475
Adam, W.; Richter, M.J.
Metal-Catalyzed Direct Hydroxy-Epoxidation of Olefins
Acc. Chem. Res., 1994, 27, 57-62

474
Adam, W.; Richter, M.J.
One-Pot Synthesis of a-Trimethylsilyl Enones from Vinylsilanes
Synthesis, 1994, 176-180

470
Adam, W.; Richter, M.J.
On the Origin of Geminal Regioselectivity in the Ene Reaction of Singlet Oxygen with Substituted Alkenes
Tetrahedron Lett., 1993, 34, 8423-8426

468
Adam, W.; Hoch, U.; Saha-Möller, C.R.; Schreier, P.
Enzyme-Catalyzed Asymmetric Synthesis: Kinetic Resolution of Chiral Hydroperoxides by Enantioselective Reduction to Alcohols with Horseradish Peroxidase
Angew. Chem., 1993, 105, 1800-1801; Angew. Chem., Int. Ed. Engl., 1993, 32, 1737-1739

467
Epe, B.; Häring, M.; Ramaiah, D.; Stopper, H.; Abou-Elzahab, M.A.; Adam, W.; Saha-Möller, C.R.
DNA Damage Induced by Furocoumarin Hydroperoxides Plus UV (360 nm)
Carcinogenesis, 1993, 14, 2271-2276

458
Adam, W.; Epe, B.; Mosandl, T.; Ramaiah, D.; Saha-Möller, C.R.; Wild, D.
Furocoumarin Dioxetanes and Hydroperoxides as Novel Photobiological DNA-Damaging Agents
Quimica Nova, 1993, 316-319

456
Adam, W.; Nestler, B.
Direct Epoxy-Hydroxylation of Hydroperoxy Homoallylic Alcohols: Multidentate Oxygen-Donor and Oxygen-Acceptor Substrates in Ti(IV)-Catalyzed Epoxidations
J. Am. Chem. Soc., 1993, 115, 7226-7231

453
Adam, W.; Klug, P.
Photooxygenation of Vinylstannanes: Tin-Substituted Allylic Hydroperoxides through the Regio- and Diastereoselective Ene Reaction with Singlet Oxygen
J. Org. Chem., 1993, 58, 3416-3420

452
Adam, W.; Nestler, B.
Hydroxy-Directed Regio- and Diastereoselective Ene Reaction of Singlet Oxygen with Chiral Allylic Alcohols
J. Am. Chem. Soc., 1993, 115, 5041-5049

447
Adam, W.; Nestler, B.
Titanium-Catalyzed Epoxy-Hydroxylation of Allylic Alcohols: A Convenient Diastereoselective Synthesis of Epoxy Diols
Angew. Chem., 1993, 105, 767-769; Angew. Chem., Int. Ed. Engl., 1993, 32, 733-735

443
Adam, W.; Brünker, H.-G.
Diastereoselective and Regioselective Photooxygenation of a Chiral Allylic Amine and its Acyl Derivatives: Stereochemical Evidence for a Steering Effect by the Amino Group in the Ene Reaction of Singlet Oxygen
J. Am. Chem. Soc., 1993, 115, 3008-3009

439
Adam, W.; Ganeshpure, P.A.
Oxidation of Arenes to para-Quinones with Hydrogen Peroxide Catalyzed by Hexafluoroacetone Hydrate
Synthesis, 1993, 280-282

433
Adam, W.; Nestler, B.
(Z)-3-Methyl-3-penten-2-ol as Stereochemical Probe for 1,2- versus 1,3-Allylic Strain in the Photooxygenation and Epoxidation of Chiral Allylic Alcohols
Tetrahedron Lett., 1993, 34, 611-614

422
Adam, W.
Introductory Remarks
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chichester 1992

418
Adam, W.; Schönberger, A.
Application of the Marcus Theory on the Reaction of Substituted Benzoyl Peroxides with Hydroquinones: Evidence for an Inner-Sphere Electron-Transfer (ET) Mechanism
Chem. Ber., 1992, 125, 2149-2153

416
Adam, W.; Nestler, B.
Photooxygenation of Chiral Allylic Alcohols: Hydroxy-Directed Regio- and Diastereoselective Ene Reaction
J. Am. Chem. Soc., 1992, 114, 6549-6550

406
Adam, W.; Richter, M.
Highly Regio- and Diastereoselective Synthesis of Epoxy Alcohols Directly from Vinylsilanes by Photooxygenation and Titanium-Catalyzed Oxygen Transfer
Tetrahedron Lett., 1992, 33, 3461-3464

395
Adam, W.; Griesbeck, A.G.; Wang, X.
Photooxygenation of a-Ionone and Oxygen Transfer Reactions of the Resulting Allylic Hydroperoxides
Liebigs Ann. Chem., 1992, 193-197

383
Adam, W.; Wang, X.
E/Z Isomerization, Solvolysis, Addition, and Cycloaddition Reactions of (E)-tert-Butylketene Methyl tert-Butyldimethylsilyl Acetal
J. Org. Chem., 1991, 56, 7244-7250

368
Abou-Elzahab, M.M.; Adam, W.; Saha-Möller, C.R.
Photooxygenation of Some Potentially Skin-Photosensitizing Furocoumarines: Imperatorin, Alloimperatorin and its Methyl Ether and Acetate Derivatives
Liebigs Ann. Chem., 1991, 967-970

365
Adam, W.; Wang, X.
Photooxygenation of Silyl Ketene Acetals: Dioxetanes as Precursors to a-Silylperoxy Esters in the Silatropic Ene Reaction
J. Org. Chem., 1991, 56, 4737-4741

360
Abou-Elzahab, M.; Adam, W.; Saha-Möller, C.R.
Epoxidation of Allylic Hydroperoxides by Dimethyldioxirane and Peroxy Acids
Liebigs Ann. Chem., 1991, 445-450

359
Adam, W.; Brünker, H.-G.; Nestler, B.
Photooxygenation of 2-Alkenyl-Substituted Chiral Oxazolines: Stereochemical Evidence Favoring the cis Effect in the Regio-Selective Ene Reaction of Singlet Oxygen with a,b-Unsaturated Carbonyl Derivatives
Tetrahedron Lett., 1991, 32, 1957-1960

346
Adam, W.; Nestler, B.
A Regio- and Diastereoselective Ene Reaction of Singlet Oxygen with Dialkyl-Substituted Acrylic Esters
Liebigs Ann. Chem., 1990, 1051-1053

332
Adam, W.; Kades, E.; Wang, X.
Photooxygenation of 3- and 2-Silyloxybenzofurans Rearrangement of Dioxetanes via a-Silylperoxy Ketones into Ketoester Cleavage Products
Tetrahedron Lett., 1990, 31, 2259-2262

331
Adam, W.; Wang, X.
Photooxygenation of 1,2-Bis(Silyloxy)cycloalkenes
Tetrahedron Lett., 1990, 31, 1245-1248

318
Adam, W.; Catalani, L.H.; Saha-Möller, C.R.; Will, B.
Synthesis of Trialkylsilylated a-Hydroperoxy Aldehydes and Ketones via Ozonolysis of Protected Allylic Hydroperoxides
Synthesis, 1989, 121-124

316
Adam, W.; Braun, M.; Griesbeck, A.; Lucchini, V.; Staab, E.; Will, B.
Photooxygenation of Olefins in the Presence of Titanium (IV) Catalyst: A Convenient One-Pot Synthesis of Epoxy Alcohols
J. Am. Chem. Soc., 1989, 111, 203-212

312
Adam, W.; Kömmerling, S.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Schwarm, M.; Staab, E.; Zahn, A.
Regioselective Ene Reaction in the Photooxygenation of Symmetrically Tetrasubstituted Ethenes and the Ti(IV)-Catalyzed Epoxy-Hydroxylation of their Allylic Hydroperoxides
Chem. Ber., 1988, 121, 2151-2155

303
Adam, W.; Staab, E.
Regio- and Stereo-Controlled Oxygen Functionalization of Cholesterol by Photooxygenation in the Presence of Tetraisopropoxide
Liebigs Ann. Chem., 1988, 757-759

298
Adam, W.; Catalani, L.H.; Griesbeck, A.G.
Trialkylsilyl Protecting Groups in the Synthesis of a-Hydroperoxy Carbonyl Compounds
In Silicon Chemistry: Corey, E.J., Corey, J.Y., Gaspar, P.P., Eds.; Ellis Horwood Ltd.: Chichester, England 1988; pp 15-24

295
Adam, W.; Lupón, P.
Quinol Epoxides from p-Cresol and Estrone by Photooxygenation and Titanium(IV)- or Vanadium(V)-Catalyzed Oxygen Transfer
Chem. Ber., 1988, 121, 21-25

294
Adam, W.; Grabowski, S.; Hinz, R.F.; Lucchini, V.; Peters, E.-M.; Peters, K.; Rebollo, H.; von Schnering, H.G.
Synthesis and Transformations of Urazoles Derived from 7,7-Dicarboxynorcaradiene: Formation of 2,4-Dioxahexahydro-1,3,5-triazines via an Unusual Base-Catalyzed Rearrangement
Chem. Ber., 1987, 120, 2075-2079

272
Adam, W.; Pasquato, L.
3,4-Epoxy-5-hydroxycyclopentene via Titanium(IV)-Catalyzed Photooxygenation and its Pyrolysis to 2,4-Pentadienoic Acid
Tetrahedron Lett., 1987, 28, 311-314

268
Adam, W.; Griesbeck, A.
Regioselective Synthesis of 3-Hydroperoxy-2-methylenebutyric Acid Functionalities via Photooxygenation of Tiglic Acid Derivatives
Synthesis, 1986, 1050-1052

258
Adam, W.; Griesbeck, A.G.; Staab, E.
A Convenient One-Pot Synthesis of Epoxy Alcohols via Photooxygenation of Olefins in the Presence of Titanium(IV) Catalyst
Tetrahedron Lett., 1986, 27, 2839-2842

256
Adam, W.; Griesbeck, A.G.; Staab, E.
A Simple Access to 2-Epoxy Alcohols: Titanium(IV)-Catalyzed Oxygen Transfer from Allylic Hydroperoxides
Angew. Chem., 1986, 98, 279-280; Angew. Chem., Int. Ed. Engl., 1986, 25, 269-270

138
Adam, W.; Del Fierro, J.; Quiroz, F.; Yany, F.
Singlet Oxygenation of Ketene Acetals: Formation of 1,2-Dioxetanes and Their Thermal Rearrangmeent to a-Peroxy Esters
J. Am. Chem. Soc., 1980, 102, 2127-2128

130
Adam, W.; Rodriguez, A.
Bis(trimethylsilyl) Monoperoxysulfate: Convenient Baeyer-Villiger Oxidant
J. Org. Chem., 1979, 44, 4969-4970

101
Adam, W.; Bloodworth, A.J.
Organic Peroxides, Biological and Synthetic Aspects
Ann. Reports (B), 1978, 342-369

100
Adam, W.
Singlet Molecular Oxygen and its Role in Organic Peroxide Chemistry
W.M. Weigert, Ed., Hüthig Verlag: Heidelberg, 1978

84
Adam, W.; del Fierro, J.
Synthesis of a-Hydroperoxy Esters by Singlet Oxygenation of Ketene Acetals
J. Org. Chem., 1978, 43, 1159-1161

70
Adam, W.; Cueto, O.
A Convenient and Efficient Preparation of Aromatic a-Hydroperoxy Acids via Oxygenation of a-Lithio Enolates, Prepared by Direct a-Lithiation of Arylacetic Acids
J. Org. Chem., 1977, 42, 38-40

69
Duran, N.; Pernas, A.; Adam, W.
Espectrometria de Masas de g-Hidroperoxi Alcoholes y g-Dioles
Rev. Latinoam. Quim., 1976, 7, 106-111

67
Adam, W.; Cueto, O.; Ehrig, V.
a-Hydroperoxy Acids via Direct Oxygenation
J. Org. Chem., 1976, 41, 370-371

54
Batich, C.; Adam, W.
The Photoelectron Spectra of Alkyl Peroxides
Tetrahedron Lett., 1974, 1467-1470

28
Adam, W.; Sanabia, J.
Differential Scanning Calorimetry Applied to the Thermolysis of Peroxalates
Thermal Analysis, 1971, 2, 475-485

24
Adam, W.; Rios, A.
Perhydrolysis of Epoxides
Chem. Commun., 1971, 822-823

21
Adam, W.; Rios, A.
Ionic Peroxide Reactions. The Mechanism of the Reaction of Peroxycarbonates with Trivalent Phosphorus Nucleophiles
J. Org. Chem., 1971, 36, 407-411

4
Greene, F.D.; Adam, W.
Diacyl Peroxide-Olefin Reactions. Epoxidation of Tetramethylethylene by an Aroyl Peroxide
J. Org. Chem., 1964, 29, 136-139

2
Greene, F.D.; Adam, W.
Autoxidation of Galvinoxyl
J. Org. Chem., 1963, 28, 3550-3551

1
Greene, F.D.; Adam, W.; Cantrill, J.E.
Diacyl Peroxide-Olefin Reactions. Evidence for a Direct Reaction
J. Am. Chem. Soc., 1961, 83, 3461-3468

Azoalkanes(159)

968
Adam, W.; Diedering, M., Trofimov, A.V
The Intriguing Double-Inversion Stereochemistry in the Denitrogenation of 2,3-Diazabicyclo[2.2.1]heptene-Type Azoalkanes (DBH): A Model Mechanistic Study in Physical Organic Chemistry
J. Physorg. Chem., 2004, 17, 643-655

966
Adam, W.; Ortega Schulte, C.M.
Captodative Stabilization in Geminally Substituted Allylic Radicals Assessed by Means of the EPR-Spectral D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
Eur. J. Org. Chem., 2004, 1482-1491

962
Abe, M.; Adam, W.; Borden, W.T.; Hattori, M.; Hrovat, D.A.; Nojima, M.; Nozaki,K.; Wirz, J.
Effects of Spiroconjugation on the Calculated Singlet-Triplet Energy Gap in 2,2-Dialkoxycyclopentane-1,3-diyls and on the Experimental Electronic Absorption Spectra of Singlet 1,3-Diphenyl Derivatives. Assignment of the Lowest-Energy Electronic Transition of Singlet Cyclopentane-1,3-diyls
J. Am. Chem. Soc., 2004, 126, 574-582

957
Simon, A,; Tóth, G.; Librera, C.P.; Adam, W.
¹H, ¹³C and ¹⁵N NMR Investigation of a New , Condensed Hexahydro-1,3,5-triazine
Magn. Reson. Chem., 2003, 41, 541-544

956
Adam, W.; Trofimov, A.V.
Photomechanistic Aspects of Bicyclic Azoalkanes: Triplet States, Photoreduction and Double Inversion
In Handbook of Organic Photochemistry and Photobiology, 2nd ed.; Horspool, W. M.; Lenci, F. (Eds.); CRC Press, Inc.: London 2003; Chap. 93, pp 1-16

946
Adam, W.: Librera, C.; Trofimov, A.V.
Stereochemical Memory versus Curtin-Hammett Behavior in the Rearrrangement of
J. Am. Chem. Soc., 2003, 125, 5741-5744

945
Adam, W.; Trofimov, A.V.
Viscosity as a Valuable Experimental Tool to Study the Mechanism of Stereoselective and Product-Selective Chemical Transformation through Frictional Impositions
Acc. Chem. Res., 2003, 36, 571-579

943
Adam, W.; Sajimon, M.C.; Trofimov, A.V.
Viscosity-Dependent Diastereoselectivity and Product Selectivity in the Photodenitrogenation of a Spirocyclopropyl-Substituted DBH-Type Azoalkane
Photochem. Photobiol. Sci., 2003, 2, 677-680

939
Adam, W.; Diedering, M.
Enhanced Formation of Inverted Housane through Steric Effects by Rotationally Unsymmetric Bridgehead Substituents in the Ring Closure of Triplet Cyclopentane-1,3-diyl Diradicals, Generated Photolytically from 2,3-Diazabicyclo[2.2.1]heptene(DHB)-Type azoalkanes
Photochem. Photobiol. Sci., 2003, 2, 393-397

934
Abe, M.; Adam, W.; Minamoto, T.; Ino, Y.; Nojima, M.
Mechanism of an Alcohol-Trapping Reaction in the Direct and Benzophenone-Sensitized Photodenitrogenation of a Spiroepoxy-Substituted Azoalkane: Solvent Effects and Stereochemical Deuterium Labeling
J. Org. Chem., 2003, 68, 1796-1803

932
Adam, W.; Ortega Schulte, C.M.
Spin Delocalization by Triple Bonds, Assessed from the EPR-Spectral D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
J. Org. Chem., 2003, 68, 1007-1011

929
Adam, W.; Diedering M.; Sajimon, M.C.; Trofimov, A.V.
Structural Dependence on the Stereoselective Formation of Inverted Housane in the Viscosity-Controlled Photodenitrogenation of DBH-Type Azoalkanes
Phys. Chem. Chem. Phys., 2003, 5, 329-332

926
Adam, W.; Diedering, M.; Marti, V.
Preferred Formation of anti Housane (Retention) in the Sensitized Photodenitrogenation of Cyclopentane-Annellated DBH-Type Azoalkanes through Long-Range Steric Effects in the Cyclization of the Triplet Cyclopentane-1,3-diyl Diradicals
Eur. J. Org. Chem., 2003, 592-596

916
Adam, W.; Corley, D.A.; Trofimov, A.V.; White, R.C.
Viscosity Dependence of the Denitrogenation Quantum Yield in Azoalkane Photolysis: Experimental Evidence for Reversible Formation of the Diazenyl Diradical
Org. Lett., 2002, 4, 4277-4280

909
Adam, W.; Garcia, H.; Diedering, M.; Marti, V.; Olivucci, M.; Palomares, E.
Stereochemical Memory in the Temperature-Dependent Photodenitrogenation of Bridgehead-Substituted DBH-Type Azoalkanes: Inhibition of Inverted-Housane Formation in the Diazenyl Diradical through the Mass Effect (Inertia) and Steric Hindrance
J. Am. Chem. Soc., 2002, 124, 12192-12199

907
Adam, W.; Librera, C.P.; Trofimov, A.V.
Viscosity-Controlled, Product-Selective Rearrangement of the Cyclopentane-1,3-diyl Radical Cation Derived from an Annelated Housane by Electron Transfer: A Case of Curtin-Hammett Behavior
J. Am. Chem. Soc., 2002, 124, 11936-11939

899
Adam, W.; Ortega Schulte, C.M.
Spin Delocalization in 1-Heteroallyl Monoradicals as a Measure of Radical Stabilization by Heterovinyl Substituents, Assessed through the EPR-Spectral Zero-Field D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
J. Org. Chem., 2002, 67, 4569-4573

898
Marquez, F.; Marti, V.; Palomares, E.; Garcia, H.; Adam, W.
Observation of Azo-Chromophore Fluorescence and Phosphorescence Emissions from DBH by Applying Exclusively the Orbital Confinement Effect in Siliceous Zeolites Devoid of Charge-Balancing Cations
J. Am. Chem. Soc., 2002, 124, 7264-7265

897
Abe, M.; Adam, W.; Hara, M.; Hattori, M.; Majima, T.; Nojima, M.; Tachibana, K.; Tojo, S.
On the Electronic Character of Localized Singlet 2,2-Dimethoxycyclopentane-1,3-diyl Diradicals: Substituent Effects on the Lifetime
J. Am. Chem. Soc., 2002, 124, 6540-6541

895
Adam, W.; Diedering, M; Trofimov, A. V.
Photochemical versus Thermal Skeletal Inversion: Viscosity-Controlled Photodenitrogenation of a Bridgehead-Substituted DBH-Type Azoalkane and Thermal syn-to-anti Housane Isomerisation
J. Am. Chem. Soc., 2002, 124, 5427-5430

885
Adam, W.; Diedering, M.; Trofimov, A.
Solvent Effects in the Photodenitrogenation of the Azoalkane Diazabicyclo[2.2.1]hept-2-ene: Viscosity- and Polarity-Controlled Stereoselectivity in the Housane Formation from the Diazenyl Diradical
Phys. Chem. Chem. Phys., 2002, 4, 1036-1039

881
Adam, W.; Librera, C.P.
The Rearrangement of Annelated Housanes to Triquinane-Like Hydrocarbons by Electron Transfer (1,3-Cyclopentanediyl Radical Cations) and Acid Catalysis (Cyclopentyl Carbenium Ions)
J. Org. Chem., 2002, 67, 576-581

878
Adam, W.; Diedering, M.; Trofimov, A.V.
Pressure Dependence of the Stereoselectivity in the Photodenitrogenation of Diazabicyclo[2.2.1]hept-2-ene in Supercritical Fluids: Evidence for the Diazenyl Diradical
Chem. Phys. Lett., 2001, 350, 453-458

870
Adam, W.; Grüne, M.; Diedering, M.; Trofimov, A.V.
Temperature and Viscosity Dependence in the Stereoselective Formation of Inverted Housane for the Photochemical Nitrogen Loss from the Deuterium-Stereolabeled Parent Diazabicyclo[2.2.1]hept-2-ene
J. Am. Chem. Soc., 2001, 123, 7109-7112

864
Adam, W.; Marti, V.; Sahin, C.; Trofimov, A.V.
Stereoselective Formation of Inverted Housane in the Denitrogenation of the Diazenyl Diradical Photolytically Derived from a Stereolabeled Diazabicyclo[2.2.1]hept-2-ene with Bridgehead Substituents as a Function of Solvent- and Temperature-Varied Viscosity
Chem. Phys. Lett., 2001, 26-32

851
Adam, W.; Diedering, M.
The Generation, Detection and Chemical Fate of 1,3-Cyclopentanediyl Radical Cations
In Atualidades de Fisico-Quimica Organica, 1999; Humeres, E., Ed.; Univ. Fed. St. Catarina: Florianopolis, Brazil 2000; Vol. 12, pp 15-34

849
Adam, W.; Maas, W.; Nau, W.M.
Wavelength-Selective Photodenitrogenation of Azoalkanes to High-Spin Polyradicals with Cyclopentane-1,3-diyl Spin-Carrying Units and their Photobleaching: EPR/UV Spectroscopy and Product Studies of the Matrix-Isolated Species
J. Org. Chem., 2000, 65, 8790-8796

846
Uppili, S.; Marti, V.; Nikolaus, A.; Jockusch, S.; Adam, W.; Engel, P.S.; Turro, N.J.; Ramamurthy, V.
Heavy-Cation-Induced Phosphorescence of Alkanones and Azoalkanes in Zeolites as Hosts: Induced S₁ (np^*) to T₁ (np^*) Intersystem Crossing and S₀ to T₁ (np^*) Absorption
J. Am. Chem. Soc., 2000, 122, 11025-11026

844
Adam, W.; Maas, W.
EPR-Spectral Determination of Electronic Substituent Effects on the D Values of Hydrocarbon Polyradicals (Quintet and Septet Spin States) Composed of Localized 1,3-Cyclopentanediyl Spin-Carrying Units Linked by 1,3-Di- and 1,3,5-Trimethylenebenzene Ferromagnetic Couplers
J. Org. Chem., 2000, 65, 7650-7655

836
Adam, W.; Emmert, O.
Steric Influence of E- or Z-Monosubstituted and Terminally Disubstituted Vinyl Groups in Matrix-Isolated Cyclopentane-1,3-diyl Triplet Diradicals as Probed by the Zero-Field EPR D Parameter
J. Org. Chem., 2000, 65, 5664-5667

828
Adam, W.; Emmert, O.
The D Parameter of Vinyl-Substituted 1,3-Cyclopentanediyl Triplet Diradicals as a Sensititve Tool to Determine Electronic Substituent Effects in Allylic Radicals
J. Org. Chem., 2000, 65, 4127-4130

824
Adam, W.; Baumgarten, M.; Maas, W.
A Hydrocarbon Hexaradical with Three Localized 1,3-Cyclopentanediyl Triplet Diradicals Linked by 1,3,5-Trimethylenebenzene as Ferromagnetic Coupler: Synthesis of the Azoalkane Precursor, Photochemical Generation of the Polyradical and EPR Characterization of its Septet-Spin Ground State
J. Am. Chem. Soc., 2000, 122, 6735-6738

823
Abe, M.; Adam, W.; Ino, Y.; Nojima, M.
Stereochemical Deuterium Labeling as Mechanistic Probe for Differentiating the Singlet- and Triplet-Diradical Spin States in the Rearrangement of the 2-Spiroepoxy-1,3-cyclopentanediyl to Oxetanes
J. Am. Chem. Soc., 2000, 122, 6508-6509

819
Adam, W.; Marti, V.; Sahin, C.; Trofimov, A.V.
Viscosity-Controlled Stereoselective Inversion in the Photochemical Denitrogenation of a Stereolabeled Diazabicyclo[2.2.1]heptene (DBH)-Type Azoalkane
J. Am. Chem. Soc., 2000, 122, 5002-5003

811
Adam, W.; Garcia, H.; Marti, V.; Moorthy, J.N.; Peters, K.; Peters, E.-M.
Photochemical Denitrogenation of Norbornene-Annelated 2,3-Diazabicyclo[2.1.1]hept-2-ene-Type Azoalkanes: Crystal-Lattice versus Zeolite-Interior Effects
J. Am. Chem. Soc., 2000, 122, 3536-3537

805
Peters, K.; Peters, E.-M.; Adam, W.; Köver, P.; Lévai, A.; Patonay, T.
Crystal Structure of [1S, 2S]-cis-6-Chloro-2-methyl-1-thiochroman-4-one 1-oxide, C₉H₆SO₂(CH₃)Cl
Z. Kristallogr., 2000, 215, 217-218

803
Peters, K.; Peters, E.-M.; Adam,W.; Marti, V.
Crystal Structure of (c-4a,c-8a)-1,4,4a5,8,8a-hexahydro-1,4,10,10-tetramethyl-r-1,c-4:t-5,t-8-dimethanophthalazine, [C₇H₈N₂][C₃N₂(CH)₄]
Z. Kristallogr., 2000, 215, 210

801
Adam, W.; Barneveld van, C.; Emmert, O.
The EPR D Parameter as a Measure of Spin Delocalization in 1,3-Cyclopentanediyl Triplet Diradicals with Extendedly Conjugated p-Type Substituents
J. Chem. Soc., Perkin Trans. 2, 2000, 4, 637-641

799
Abe, M.; Adam, W.; Heidenfelder, T.; Nau, W.M.; Zhang, X.
Intramolecular and Intermolecular Reactivity of Localized Singlet Diradicals: The Exceedingly Long-Lived 2,2-Diethoxy-1,3-diphenylcyclopentane-1,3-diyl
J. Am. Chem. Soc., 2000, 122, 2019-2026

796
Adam, W.; Nikolaus, A.
Photoreduction of Polycyclic DBO-Type Azoalkane with Amines to Hydrazine Products
J. Am. Chem. Soc., 2000, 122, 884-888

791
Adam, W.; Barneveld van, C.
The Importance of Spin Polarization in Electronic Substituent Effects of the Zero-Field EPR D Parameter in 1,3-Diarylcyclopentane-1,3-diyl Triplet Diradicals
J. Am. Chem. Soc., 1999, 121, 10820-10827

790
Blancafort, L.; Adam, W.; González, D.; Olivucci, M.; Vreven, T.; Robb, M.A.
Theoretical Study of the 1,2 Rearrangement of Housane Radical Cations: Key Role of a Transient Cyclopentane-1,3-diyl Intermediate
J. Am. Chem. Soc., 1999, 121, 10583-10590

789
Adam, W.; Barneveld van, C.; Gerke, J.-S.; Klärner, F.-G.
The EPR D-Parameter of 1,3-Cyclopentanediyl Triplet Diradicals as a Probe for Steric Substituent Effects in Benzyl-Type Radicals
J. Chem. Soc., Perkin Trans. 2, 1999, 2723-2728

788
Adam, W.; Heidenfelder, T.
Regio- and Diastereoselective Rearrangement of Cyclopentane-1,3-diyl Radical Cations Generated by Electron Transfer
Chem. Soc. Rev., 1999, 28, 359-366

784
Adam, W.; Garcia, H.; Marti, V.; Moorthy, J.N.
Homolytic Substitution (S_H2) versus Triplet Diradical (ISC) in the Photochemical Denitrogenation of a DBH Azoalkane: Temperature-Dependent syn/anti Diastereoselectivity as a Mechanistic Probe for the Doubly-Inverted Housane
J. Am. Chem. Soc., 1999, 121, 9475-9476

783
Kita, F.; Adam, W.; Jordan, P.; Nau, W.M.; Wirz, J.
1,3-Cyclopentanediyl Diradicals: Substituent and Temperature Dependence of Triplet-Singlet Intersystem Crossing
J. Am. Chem. Soc., 1999, 121, 9265-9275

774
Adam, W.; Nikolaus, A.; Sauer, J.
Influence of Bridgehead Substitution and Ring Annelation on the Photophysical Properties of Polycyclic DBO-Type Azoalkanes
J. Org. Chem., 1999, 64, 3695-3698

773
Adam, W.; Emmert, O.; Heidenfelder, T.
The EPR-Spectral D Parameter of Photochemically Generated Cyclopentane-1,3-diyl Triplet Diradicals as a Quantitative Measure of Spin Delocalization in Vinyl-, Phenyl- and Carbonyl-Substituted Radicals
J. Org. Chem., 1999, 64, 3417-3421

747
Adam, W.; Heidenfelder, T.
Electronic Substituent Effects for the Fine-Tuning of the Regioselectivity in the Diastereoselective Rearrangement of 1,3-Cyclopentanediyl Radical Cations Generated from Tricyclo[3.3.0.0^2,4]octanes (Housanes) by Chemical Electron Transfer (CET)
J. Am. Chem. Soc., 1998, 120, 11858-11863

742
Abe, M.; Adam, W.; Nau, W.M.
Photochemical Generation and Methanol Trapping of Localized 1,3 and 1,4 Singlet Diradicals Derived from a Spiroepoxy-Substituted Cyclopentane-1,3-diyl
J. Am. Chem. Soc., 1998, 120, 11304-11310

736
Adam, W.; Häfner, A.; Nikolaus, A.; Sauer, J.; Schneider, F.W.
Structural Effects on the Photopersistence of Ester- and Phenyl-Substituted DBO-Type Polycyclic Azoalkanes with Cyclopropyl and Norbornyl Annelation
J. Inf. Rec., 1998, 24, 185-190

734
Adam, W.; Nikolaus, A.
Fluorescence Quenching of Ester-Substituted DBO-Type Azoalkanes by Olefins and Arenes: Electronic and Steric Effects, Exciplex Formation and Hydrogen Abstraction
Eur. J. Org. Chem., 1998, 2177-2179

729
Adam, W.; Harrer, H.M.; Kita, F.; Nau, W.M.
The EPR-Spectroscopic D Parameter of Localized Triplet Diradicals as Probe for Electronic Effects in Benzyl-Type Monoradicals
Adv. Photochem., 1998, 24, 205-254

721
Abe, M.; Adam, W.
Electronic Substituent Effects on the EPR-Spectral D Parameter of Trimethylenemethane (TMM) Triplet Diradicals Compared with Localized Cyclopentane-1,3-Diyls
J. Chem. Soc., Perkin Trans. 2, 1998, 1063-1068

698
Adam, W.; Handmann, V.-I.; Kita, F.; Heidenfelder, T.
Divergent Pathways in the Rearrangement of Tricyclo[3.3.0.0^2,4]octanes (Housanes) on Chemical Electron Transfer (CET) versus Acid Catalysis: A Comparison of Radical Cations and Carbocations
J. Am. Chem. Soc., 1998, 120, 831-832

696
Adam, W.; Borden, W.T.; Burda, C.; Foster, H.; Heidenfelder, T.; Heubes, M.; Hrovat, D.A.; Kita, F.; Lewis, S.B.; Scheutzow, D.; Wirz, J.
Transient Spectroscopy of a Derivative of 2,2-Difluoro-1,3-diphenylcylopentane-1,3-diyl - A Persistent Localized Singlet 1,3-Diradical
J. Am. Chem. Soc., 1998, 120, 593-594

691
Adam, W.; Harrer, H.M.
Electronic Substituent Effects in Radical Chemistry: The DD Scale for Benzyl-Type Radicals
Anales de Quimica, 1997, 93, 271-276

687
Adam, W.; Moorthy, J.N.; Nau, W.M.; Scaiano, J.C.
Photoreduction of Azoalkanes by Direct Hydrogen Abstraction from 1,4-Cylohexadiene, Alcohols, Stannanes, and Silanes
J. Org. Chem., 1997, 62, 8082-8090

684
Adam, W.; Kammel, T.; Toubartz, M.; Steenken, S.
Detection of Phenyl-Substituted Radical Cations Derived from Cyclopentyl- and Urazole-Type Azoalkanes by Pulse Radiolysis: Influence of Heteroatom Substitution on the Radical-Cation Reactivities
J. Am. Chem. Soc., 1997, 119, 10673-10676

682
Adam, W.; Harrer, H.M.; Maas, W.
Additivity of the Electronic meta-Substituent Effect in 3,5-Disubstituted Cumyl Radicals Assessed by the EPR D Parameter of 1,3-Arylcyclopentane-1,3-diyl Triplet Radicals
J. Org. Chem., 1997, 62, 7263-7266

677
Nau, W.M.; Adam, W.; Klapstein; D.; Sahin, C.; Walter, H.
Correlation of Oxidation and Ionization Potentials for Azoalkanes
J. Org. Chem., 1997, 62, 5128-5132

676
Adam, W; Moorthy, J.N.; Nau, W.M.; Scaiano, J.C.
Charge-Transfer-Induced Photoreduction of Azoalkanes by Amines
J. Am. Chem. Soc., 1997, 119, 6749-6756

672
Adam, W.; Moorthy, J. M.; Nau, W.; Scaiano, J.C.
Solvent Effect on the Product Distribution in the Photochemical Pathways of a-CN versus b-CC Cleavage of n,p^*-Triplet-Excited Azoalkanes
J. Am. Chem. Soc., 1997, 119, 5550-5555

671
Adam, W.; van Barneveld, C.; Emmert, O.; Harrer, H.M.; Kita, F.; Sampath Kumar, A.; Maas, W.; Nau, W.M.; Reddy, S.H.K.; Wirz, J.
About Monoradicals, Triplet Diradicals and Higher Spin States: Understanding Electronic Substituent Effects through EPR and Time-Resolved UV Spectroscopy
Pure & Appl. Chem., 1997, 69, 735-742

660
Adam, W.; Emmert, O.; Harrer, H.M.
Photochemically Generated Cyclopentane-1,3-diyl Triplet Diradicals as Model Systems for the Assessment of Spin Delocalization in Heteroaryl-Substituted Benzyl-Type Monoradicals through the EPR-Spectral D Parameter
J. Chem. Soc., Perkin Trans. 2, 1997, 687-694

653
Adam, W.; Harrer, H.M.; Kita, F.; Korth, H.-G.; Nau, W.M.
Electronic Effects of para and meta Substituents on the EPR D Parameter in 1,3-Arylcylopentane-1,3-diyl Triplet Diradicals. A New Spectroscopic Measure of a Spin Densities and Radical Stabilization Energies in Benzyl-Type Monoradicals
J. Org. Chem., 1997, 62, 1419-11426

651
Adam, W.; Harrer, H.M.; Kita, F.; Nau, W.M.
Localized Triplet Diradicals as Probe for Electronic Substituent Effects in Benzyl-Type Radicals: The D Scale
Pure & Appl. Chem., 1997, 69, 91-96

638
Adam, W.; Moorthy, J.N.; Nau, W.M.; Scaiano, J.C.
Photoreduction of Azoalkane Triplet States by Hydrogen Atom and Charge Transfer
J. Org. Chem., 1996, 61, 8722-8723

632
Adam, W.; Harrer, H.M.; Heidenfelder, T.; Kammel, T.; Kita, F.; Nau, W.M.; Sahin, C.
The D Parameter ( Zero-Field Splitting) as a Direct Measure of Structural and Electronic Effects in Localized 1,3-Diradicals
J. Chem. Soc., Perkin Trans. 2, 1996, 2085-2089

631
Adam, W.; Harrer, H.M.; Kita, F.; Nau, W.M.; Zipf, W.
The D Parameter (EPR Zero-Field Splitting) of Localized 1,3-Cyclopentanediyl Triplet Diradicals as a Measure of Electronic Substituent Effects on the Spin Densities in para-Substituted Benzyl-Type Radicals
J. Org. Chem., 1996, 61, 7056-7065

619
Nau, W.M.; Adam, W.; Scaiano, J.C.
Fluorescence Quenching of Azoalkanes by Solvent-Assisted Radiationless Deactivation Involving CH Bonds
Chem. Phys. Lett., 1996, 253, 92-96

610
Adam, W.; van Barneveld, C.; Bottle, S.E.; Engert, H.; Hanson, G.R.; Harrer, H.M.; Heim, C.; Nau, W.M.; Wang, D.
EPR Characterization of the Quintet State for a Hydrocarbon Tetraradical with Two Localized 1,3-Cyclopentanediyl Biradicals Linked by meta-Phenylene as Ferromagnetic Coupler
J. Am. Chem. Soc., 1996, 118, 3974-3975

601
Nau, W.M.; Adam, W.; Scaiano, J.C.
Singlet-Oxygen Production from Excited Azoalkanes
J. Am. Chem. Soc., 1996, 118, 2742-2743

594
Adam, W.; Kammel, T.; Steenken, S.
Generation of a Heterocyclic 1,3-Cyclopentanediyl Radical Cation Derived from the Corresponding Housane by Chemically Induced Electron Transfer Oxidation and Pulse Radiolysis
Angew. Chem., 1996, 108, 582-584; Angew. Chem., Int. Ed. Engl., 1996, 35, 543-545

580
Adam, W.; Fragale, G.; Klapstein, D.; Nau, W.M.; Wirz, J.
Phosphorescence and Transient Absorption of Azoalkane Triplet States
J. Am. Chem. Soc., 1995, 117, 12578-12592

561
Kita, F.; Nau, W.M.; Adam, W.; Wirz, J.
Effect of Donor-Acceptor Substitution on Intersystem-Crossing Rates of 1,3-Diaryl-1,3-cyclopentanediyl Triplet Biradicals
J. Am. Chem. Soc., 1995, 117, 8670-8671

553
Adam, W.; Sahin, C.
Photochemical Decomposition of Cyclic Azoalkanes
In CRC Handbook of Organic Chemistry and Photobiology; W.M. Horspool, P.-S. Song, Eds.; CRC Press Inc.: London 1995; pp 937-953

542
Gernert, D.; Kiefer, W.; Kammel, T.; Nau, W.; Adam, W.
Matrix-Isolation Raman Spectroscopy and Semiempirical Calculations of 2,3-Diazabicyclo[2.2.1]hept-2-ene (DBH) and its Photoproduct Bicyclo[2.1.0]pentane (BCP)
J. Mol. Struct., 1995, 348, 333-336

531
Adam, W.; Sahin, C.; Schneider, M.
Mechanism of the Diastereoselective, Boron-Trifluoride-Catalyzed Cyclization of Olefinic Tosylhydrazones to Stereolabeled, Bridgehead-Substituted Azoalkanes
J. Am. Chem. Soc., 1995, 117, 1695-1702

527
Adam, W.; Goller, K.; Kammel, T.; Peters, K.
Urazole-Bridged Bicyclic Azoalkanes: Generation, Nitroxyl Trapping and ESR Spectra of the Heterosubstituted 4,5-Diaza-1,3-cyclopentanediyl Diradicals through Direct and Benzophenone-Sensitized Photochemical Deazetation
J. Org. Chem., 1995, 60, 308-316

520
Nau, W.M.; Harrer, H.M.; Adam, W.
Radical Stabilization and Ground-State Polar Substituent Effects in the Thermal Decomposition of Azoalkanes
J. Am. Chem. Soc., 1994, 116, 10972-10982

519
Adam, W.; Ammon, H.; Nau, W.M.; Peters, K.
4-Halo-4H-pyrazoles: Cycloaddition with Cyclopentadiene to Azoalkanes of the 2,3-Diazabicyclo[2.2.1]hept-2-ene Type versus Electrophilic Addition with Cyclopentene
J. Org. Chem., 1994, 59, 7067-7071

518
Adam, W.; Sahin, C.
Tris(aryl)aminium Hexachloroantimonates: Convenient One-Electron Oxidants for Chemical Electron Transfer with Bicyclic Azoalkanes and Bicyclo[2.1.0]pentanes
Tetrahedron Lett., 1994, 35, 9027-9030

506
Adam, W.; Nau, W.M.; Sendelbach, J.
Temperature Dependence on the a versus b Bond Cleavage in the Direct and Triplet-Sensitized Photolysis of Azoalkanes of the 2,3-Diazabicyclo[2.2.1]hept-2-ene Type
J. Am. Chem. Soc., 1994, 116, 7049-7054

502
Adam, W.; Harrer, H.M.; Nau, W.M.; Peters, K.
Electronic Substituent Effects on the Acid-Catalyzed [4+2] Cycloaddition of Isopyrazoles with Cyclopentadiene and the Photochemical and Thermal Denitrogenation of the Resulting 1,4-Diaryl-7,7-dimethyl-2,3-diazabicyclo[2.2.1]hept-2-ene Azoalkanes to Bicyclo[2.1.0]pentanes
J. Org. Chem., 1994, 59, 3786-3797

479
Adam, W.; Sahin, C.; Sendelbach, J.; Walter, H.; Chen, G.-F.; Williams, F.
Regioselective Rearrangement of Bridgehead-Methyl-Substituted Radical Cations Derived from Bicyclo[2.1.0]pentanes and 2,3-Diazabicyclo[2.2.1]hept-2-enes through Photoinduced Electron Transfer and Radiolytic Oxidation: Product Distribution and Matrix ESR Studies
J. Am. Chem. Soc., 1994, 116, 2576-2584

469
Adam, W.; Nau, W.M.; Sendelbach, J.; Wirz, J.
Identification of a Remarkably Long-Lived Azoalkane Triplet State
J. Am. Chem. Soc., 1993, 115, 12571-12572

465
Adam, W.; Fröhlich, L.; Nau, W.M.; Wirz, J.
Effects of Symmetrical Diaryl Substitution on Intersystem Crossing in 1,3-Cyclopentanediyl Triplet Biradicals
J. Am. Chem. Soc., 1993, 115, 9824-9825

464
Adam, W.; Sendelbach, J.
Denitrogenation of Bicyclic Azoalkanes through Photosensitized Electron Transfer: Generation and Intramolecular Trapping of Radical Cations
J. Org. Chem., 1993, 58, 5316-5322

463
Adam, W.; Sendelbach, J.
Photosensitized Electron Transfer from Azoalkanes: Generation, Fragmentation, and Rearrangement of Radical Cations Structurally Related to Dicyclopentadiene
J. Org. Chem., 1993, 58, 5310-5315

461
Adam, W.; Finzel, R.; Walther, B.
On the Mechanism of the Benzophenone-Sensitized Photolysis of 2,3-Diazabicyclo[2.2.1]hept-2-ene in the Laser Jet: Evidence for Intermolecular Triplet Biradical Reactions
Chem. Ber., 1993, 126, 2137-2141

460
Adam, W.; Fröhlich, L.; Nau, W.M.; Korth, H.-G.; Sustmann, R.
Substituent Effects on the Zero-Field Splitting Parameters of Localized Triplet 1,3-Cyclopentanediyl Biradicals
Angew. Chem., 1993, 105, 1383-1384; Angew. Chem., Int. Ed. Engl., 1993, 32, 1339-1340

438
Adam, W.; Platsch, H.; Sendelbach, J.; Wirz, J.
Determination of the Triplet Lifetimes of 1,3-Cyclopentadiyl Biradicals Derived from the Photodenitrogenation of Azoalkanes with Time-Resolved Photoacoustic Calorimetry
J. Org. Chem., 1993, 58, 1477-1482

428
Adam, W.; Finzel, R.; Schulte Oestrich, R.; Sendelbach, J.
UV Laser Photochemistry: Intersystem Crossing Phenomena and Photosensitized Transformation of Radical and Triplet Diradical Species
In Proceedings of the 8th Conference on Physical Organic Chemistry, Florianopolis (Brazil), Actualidades de Fisica Quimica Or 1992; 21-40

415
Adam, W.; Deufel, T.; Finzel, R.; Griesbeck, A.G.; Hirt, J.
Generation and Interception of Isodicyclopentadiene Tautomers by Diene Transmissive Diels-Alder Reaction of a 1,5-Dihydropentalene with a Variety of Dienophiles
J. Org. Chem., 1992, 57, 3991-3994

408
Adam, W.; Denninger, U.; Finzel, R.; Kita, F.; Platsch, H.; Walter, H.; Zang, G.
Comparative Study of the Pyrolysis, Photoinduced Electron Transfer (PET), Laser-Jet and 185-nm Photochemistry of Alkyl-Substituted Bicyclic Azoalkanes
J. Am. Chem. Soc., 1992, 114, 5027-5035

405
Adam, W.; Finzel, R.; Goller, K.; Griesbeck, A.G.
Photolysis and Thermolysis of a Tetracyclic Bisazoalkane: Nitrogen Extrusion Induced by b-Cleavage
J. Am. Chem. Soc., 1992, 114, 4558-4562

404
Adam, W.; Finzel, R.
Cyclopropylcarbinyl Ring Opening as Mechanistic Probe for Differentiation between the Singlet and Triplet Spin States of Trimethylenemethane Diradicals (Non-Kekulé Species)
J. Am. Chem. Soc., 1992, 114, 4563-4568

397
Adam, W.; Walter, H.; Chen, G.-F.; Williams, F.
Photochemical and ESR Spectral Evidence for a Stereoselective Rearrangement of Radical Cations Derived from Azoalkanes and Bicyclopentanes
J. Am. Chem. Soc., 1992, 114, 3007-3014

391
Adam, W.; Bottle, S.; Finzel, R.; Kammel, T.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Walz, L.
Trapping of Cyclopentanediyl and Trimethylenemethane Triplet Diradicals with the Nitroxide 1,1,3,3-Tetramethyl-1,3-dihydroisoindolin-2-yloxyl
J. Org. Chem., 1992, 57, 982-988

382
Ess, C.; Gerson, F.; Adam, W.
The Radical Anions of Cyclic Azoalkanes: An ESR, ENDOR, and TRIPLE-Resonance Study
Helv. Chim. Acta, 1991, 74, 2078-2093

380
Wilson, R.M.; Adam, W.; Schulte-Oestrich, R.
The Photochemistry of Photochemical Transients: Multiple-Photon Chemistry in an Argon-Ion Laser Jet
Spectrum, 1991, 4, 8-17

378
Adam, W.; Bottle, S.E.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Crystal Structure of 2,4,4-Triphenyl-2-aza-3-oxabicyclo[3.3.0]oct-5-ene, C₂₄H₂₁NO
Z. Kristallogr., 1991, 197, 309-311

377
De Lucchi, O.; Adam, W.
Di-p-methane Photoisomerizations
In Comprehensive Organic Synthesis, B.M. Trost, I. Fleming; Eds. in-Chief; Combining C-C p-Bonds; Paquette, L.A., Ed.; Per 1991; Vol. 5, pp 193-214

363
Simpson, C.J.S.M.; Wilson, G.J.; Adam, W.
The Dynamics of the Thermal Decomposition of 2,3-Diazabicyclo[2.2.1]hept-2-ene
J. Am. Chem. Soc., 1991, 113, 4728-4732

362
Adam, W.; Zang, G.
185-nm Photolysis and Pyrolysis of the Spirocyclopropane-Substituted Azoalkanes of 2,3-Diazatricyclo[4.3.0.04,9]non-2-ene and their Denitrogenated Hydrocarbon Products, the Tricyclo[3.2.0.0^2,7]heptanes
J. Org. Chem., 1991, 56, 3315-3323

358
Adam, W.; Finzel, R.; Kita, F.
Benzophenone-Sensitized Two-Photon Chemistry of Azoalkanes in the Laser/Liquid Jet: Evidence for Photoinduced Hydrogen 1,2-Shift in 1,3-Cyclopentadiyl Triplet Diradicals
Tetrahedron Lett., 1991, 32, 2211-2214

355
Adam, W.; Bottle, S.E.
Benzophenone-Sensitized Photolysis of the Azoalkane Diazabicyclo[2.2.1]hept-2-ene (DBH): Trapping of the 1,3-Cyclopentadiyl Triplet Diradical by a Nitroxide
Tetrahedron Lett., 1991, 32, 1405-1408

339
Neuman,Jr., R.C.; Berge, C.T.; Binegar, G.A.; Adam, W.; Nishizawa, Y.
cis-Diazenes: Pressure Effects on their Thermal Deazatization and Isomerization Reactions.
J. Org. Chem., 1990, 55, 4564-4568

334
Adam, W.; Platsch, H.; Reinhard, G.; Wirz, J.
Effect of 2,2-Dimethyl Substitution on the Lifetimes of Cyclic Hydrocarbon Triplet 1,3-Biradicals
J. Am. Chem. Soc., 1990, 112, 4570-4571

330
Adam, W.; Finzel, R.
UV-Laser Photochemistry: Retro Cleavage in the Benzophenone-Sensitized Photolysis of D³-1,3,4-Oxadiazolines into Diazoalkanes
Tetrahedron Lett., 1990, 31, 863-866

323
Adam, W.; Platsch, H.; Wirz, J.
Oxygen Trapping and Thermochemistry of a Hydrocarbon Singlet Biradical: 1,3-Diphenylcyclopentane-1,3-diyl
J. Am. Chem. Soc., 1989, 111, 6896-6898

322
Adam, W.; De Lucchi, O.; Dörr, M.
On the Mechanism of the Di-p-methane Rearrangement of Bicyclo[3.2.1]octa-2,6-diene: Deuterium Labeling and Generation of Diradical Intermediates via Photolysis and Thermolysis of Appropriate Azoalkanes
J. Am. Chem. Soc., 1989, 111, 5209-5213

319
Adam, W.; Grabowski, S.; Platsch, H.; Hannemann, K.; Wirz, J.; Wilson, R.M.
UV-Laser Photochemistry of Azoalkanes: Surprising Effects of Phenyl Substitution on the Lifetimes of 1,3-Cyclopentadiyl and 1,4-Cyclohexanediyl Triplet Diradicals
J. Am. Chem. Soc., 1989, 111, 751-753

313
Adam, W.; Grabowski, S.
UV-Laser Photochemistry: Nitrogen Extrusion from the Azoalkane 4,5-Diazatricyclo[4.4.0.0.3,8]dec-4-ene. Lifetime Determination of Bicyclo[2.2.2]octa-2,5-diyl by Dioxygen Trapping
Tetrahedron Lett., 1988, 29, 6605-6608

311
Adam, W.; Grabowski, S.; Scherhag, F.
UV-Laser Photochemistry: Generation of the Triplet Spiro[2.6]nona-4,7-diyl Diradical by Nitrogen Extrusion from the Azoalkane 6,7-Diazaspiro[bicyclo(3.2.2)nona-6-ene-2,1'-cyclopropane]. Conformational Influence on the Lifetime of a 1,4-Cycloheptadiyl as Determined by the Cyclopropylcarbinyl "Free-Radical Clock"
Tetrahedron Lett., 1988, 29, 5637-5640

296
Adam, W.; Grabowski, S.; Miranda, M.A.; Rübenacker, M.
Generation of the 1,4-Diphenylcyclohexane-1,4-diyl Radical Cation by Ce(IV)-Catalyzed Denitrogenation of the Azoalkane 1,4-Diphenyl-2,3-diazabicyclo[2.2.2]oct-2-ene and its Reluctance to Undergo Cope Rearrangement
Chem. Commun., 1988, 142-143

292
Adam, W.; Miranda, M.A.
Thermal and Photochemical Reactions of Bicyclic Azoalkanes in Concentrated Sulfuric Acid
J. Org. Chem., 1987, 52, 5498-5500

291
Adam, W.; Grabowski, S.; Wilson, R.M.; Hannemann, K.; Wirz, J.
UV-Laser Photochemistry of the Azoalkane 1-Phenyl-2,3-diazabicyclo[2.2.2]oct-2-ene: Detection and Lifetime Determination of the Triplet Diradical 1-Phenyl-1,4-cyclohexanediyl by Trapping with Molecular Oxygen and by Time-Resolved UV Spectroscopy (Flash Photolysis)
J. Am. Chem. Soc., 1987, 109, 7572-7573

290
Adam, W.; Hössel, P.; Hümmer, W., Platsch, H.; Wilson, R.M.
UV-Laser Photochemistry: Diffusion-Controlled Trapping of Cyclic 1,3-Diradials by Molecular Oxygen - Conformational Effects on Triplet Lifetimes
J. Am. Chem. Soc., 1987, 109, 7570-7572

289
Adam, W.; Dörr, M.; Kron, J.; Rosenthal, R.J.
On the Question of Diradical Intermediates in the Di-p-Methane Rearrangement of Benzobicyclo[3.2.1]octadienes: Azoalkanes as Mechanistic Probes
J. Am. Chem. Soc., 1987, 109, 7074-7081

287
Adam, W.; Günther, E.; Hössel, P.; Platsch, H.; Wilson, R.M.
UV-Laser Photochemistry: Evidence for Through-Bond Coupling in the Lifetime of 2,2-Dimethyl-1,3-cyclopentadiyl Triplet Diradicals
Tetrahedron Lett., 1987, 28, 4407-4410

283
Adam W.; Hannemann, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Wilson, R.M.
Nitrogen Extrusion from the Bis-Azoalkane [(anti(syn))]-7,7'-Bi-2,3-diazabicyclo[2.2.1]hept-2-ene
J. Am. Chem. Soc., 1987, 109, 5250-5260

275
Adam, W.; Dörr, M.
Wagner-Meerwein Rearrangements of Radical Cations Generated by Triphenylpyrylium Tetrafluoroborate-Sensitized Electron Transfer of Azoalkanes
J. Am. Chem. Soc., 1987, 109, 1570-1572

274
Adam, W.; Dörr, M.
Evidence for Diazenyl Diradical in the Photoisomerization of 4-Methylene-3,3,5,5-tetramethylpyrazoline
J. Am. Chem. Soc., 1987, 109, 1240-1241

273
Adam, W.; Platsch, H.
Reliable and Selective Reagent for Cyclic Azo Compounds
Chem. Ber., 1987, 120, 251-252

264
Adam, W.; Dörr, M.; Hössel, P.
UV-VIS Laser Photochemistry: Intermediary Formation of Diazoalkanes versus Direct So,T1 Transitions in the Photolysis of Azoalkanes
Angew. Chem., 1986, 98, 820-822; Angew. Chem., Int. Ed. Engl., 1986, 25, 818-819

263
Adam, W.; Oppenländer, T.
185-nm Photochemistry of Olefins, Strained Hydrocarbons and Azoalkanes
Angew. Chem., 1986, 98, 659-670; Angew. Chem., Int. Ed. Engl., 1986, 25, 661-672

252
Adam, W.; Hannemann, K.; Wilson, R.M.
Sensitized UV-Laser Photolysis of Azoalkanes: Conformational Influences on Intersystem-Crossing and Lifetimes of Triplet Diradicals
Angew. Chem., 1985, 97, 1072-1073; Angew. Chem., Int. Ed. Engl., 1985, 24, 1071-1072

249
Adam, W.; Berkessel, A.; Krimm, S.
Synthesis and Homo-Diels-Alder Cleavage of the Epoxyazoalkane exo-3-Oxa-6,7-diazatricyclo[3.2.1.02,4]oct-6-ene
Chem. Ber., 1985, 118, 5018-5023

247
Adam, W.; Oppenländer, T.
Photoreluctant Azoalkanes: 185-nm Photolysis of E- and Z-Diazacyclooct-1-ene
Can. J. Chem., 1985, 63, 1829-1832

244
Adam, W.; De Lucchi, O.; Hill, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis, Thermolysis, and Photolysis of the Azoalkanes Spiro-4,5-diazatricyclo-[4.3.0.0^3,7]non-4-ene and 4,5-Diazatricyclo[4.3.0.0^3,7]non-4-en-8-one: On the Mechanism of the Oxadi-p-methane Rearrangement of 5-Norbornen-2-one
Chem. Ber., 1985, 118, 3070-3088

243
Adam, W.; Oppenländer, T.; Zang, G.
185-nm Photochemistry of the Azoalkane 2,3-Diazabicyclo[2.2.1]hept-2-ene: On the Questions of One-Bond vs Two-Bond Cleavage During the Denitrogenation, Cyclization versus Rearrangement of the 1,3-Diradicals and Double Inversion
J. Org. Chem., 1985, 50, 3303-3312

239
Adam, W.; Hill, K.
Synthesis, Thermolysis and Photolysis of the Azoalkane 4,5-Diazatricyclo[4.3.0.03,7]nona-4,8-diene: Denitrogenation versus Azirane Formation
J. Am. Chem. Soc., 1985, 107, 3686-3689

237
Adam, W.; Hannemann, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Wilson, R.M.
Laser Photolysis of the Bisazoalkane 7-syn, 7'-anti-Bis-2,3-diazabicyclo[2.2.1]hept-2-ene
Angew. Chem., 1985, 97, 417-418; Angew. Chem., Int. Ed. Engl., 1985, 24, 421-422

236
Adam, W.; Dörr, M.; Hill, K.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis, Photolysis and Thermolysis of Azoalkanes Derived from Spirocyclopropane-Substituted Norbornenes: Competitive Nitrogen Loss and Diazoalkane Formation
J. Org. Chem., 1985, 50, 587-595

235
Adam, W.; Gillaspey, W.D.; Peters, E.-M.; Peters, K.; Rosenthal, R.J.; von Schnering, H.G.
Thermolysis and Photolysis of the Azoalkane 4,5-Diaza-7,8,8-trimethyltricyclo-[4.2.1.0^3,7]non-4-ene: 1,3-Diradical and Diazoalkane Formation
J. Org. Chem., 1985, 50, 580-586

230
Adam, W.; Hannemann, K.; Wilson, R.M.
UV-Laser Photochemistry of the Azoalkane 2,3-Diazabicyclo[2.2.2]oct-3-ene: Trapping of the Short-Lived Triplet Biradical 1,4-Cyclohexadiyl by Molecular Oxygen
J. Am. Chem. Soc., 1984, 106, 7646-7647

221
Adam, W.; Oppenländer, T.
Absolute Intensity Method for the Determination of Quantum Yields in 185-nm Photochemistry: Application to the Azoalkane 2,3-Diazabicyclo(2.2.1)hept-2-ene
Photochem. Photobiol., 1984, 39, 719-723

213
Adam, W.; Hannemann, K.; Hössel, P.
Preparative UV-Laser Photochemistry of the Azoalkane Spiro-2,3-diazabicyclo(2.2.1)hept-2-ene-7',1-cyclopropane: Trapping of the 1,4-Diradical-2-(3-cyclopentenyl)ethyl by Molecular Oxygen
Tetrahedron Lett., 1984, 25, 181-184

210
Adam, W.; Carballeira, N.; De Lucchi, O.; Hill, K.
The Di-p-methane Rearrangement Revisited
In Stereochemistry and Reactivity of Systems Containing p-Electrons (Vol. 3) by W.H. Watson, Ed.; Verlag Chemie Int.: Deer 1983; Chap. 7, pp 241-278

208
Adam, W.; Carballeira, N.; Gillaspey, W.D.
Photolysis of the Azoalkane 2,3-Diazatricyclo(4.2.0.04,9)non-2-ene: Direct Observation of 4-Cyclohexenyldiazomethane
Tetrahedron Lett., 1983, 24, 5473-5476

207
Adam, W.; Mazenod, F.; Nishizawa, Y.; Engel, P.S.; Baughman, S.A.; Chae, W.-K.; Horsey, D.W.; Quast, H.; Seiferling, B.
Reluctant Azoalkanes: The Photochemical Behavior of Acyclic, Bridgehead-Centered Azoalkanes at 185-nm and 350-nm Irradiation
J. Am. Chem. Soc., 1983, 105, 6141-6145

200
Adam, W.; Gillaspey, W.D.
Competitive Diradical and Diazoalkane Formation in the Thermolysis and Photolysis of the Azoalkane 7,7,8-Trimethyl-2,3-diazatricyclo[4.2.1.0^4,8]non-2-ene
Tetrahedron Lett., 1983, 24, 1699-1702

196
Adam, W.; Oppenländer, T.
The 185-nm Photochemistry of 2,3-Diazabicyclo[2.2.1]heptene and of its Denitrogenation Products Bicyclo[2.1.0]pentane and Cyclopentene
Tetrahedron Lett., 1982, 23, 5391-5394

193
Adam, W.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Photochemical and Thermal Denitrogenation of Azoalkanes as Mechanistic Probes for the Diradical Intermediates Involved in the Di-p-methane Rearrangement of Dibenzobarrelene
J. Am. Chem. Soc., 1982, 104, 5747-5753

182
Adam, W.; De Lucchi, O.; Hill, K.
Generation and Rearrangement of the 2-Oxabicyclo[2.2.1]heptane-6,7-diyl Diradical via Nitrogen Extrusion from the Azoalkane 2,3-Diazatricyclo[4.3.0.0^4,9]non-2-en-8-one
J. Am. Chem. Soc., 1982, 104, 2934-2936

169
Adam, W.; Carballeira, N.; De Lucchi, O.
Thermolysis and Photolysis of the Azoalkane 2,3-Diazatricyclo[4.3.0.0^4,9]non-2-ene: Generation and Transformation of the Bicyclo[2.2.1]heptane-2,7-diyl Diradical
J. Am. Chem. Soc., 1981, 103, 6406-6409

168
Adam, W.; De Lucchi, O.
Generation of 2,3-Benzobicyclo[2.2.1]hept-2-ene-5,7-diyl Diradicals via Denitrogenation of Appropriate Azoalkanes and their Mechanistic Implications in the Di-p-methane Rearrangement of Benzonorbornadienes
J. Org. Chem., 1981, 46, 4133-4238

159
Adam, W.; Arias, L.A.; De Lucchi, O.
Hydrazinolysis of Urazoles: A Convenient and Mild Method for the Preparation of Azoalkanes
Synthesis, 1981, 543-545

156
Adam, W.; De Lucchi, O.
Thermal and Photochemical Denitrogenation of a Polycylic Azoalkane as Mechanistic Probe for the Di-p-Methane Rearrangement of 7,7-Dimethylenebenzonorbornadiene
Angew. Chem., 1981, 93, 408-409; Angew. Chem., Int. Ed. Engl., 1981, 20, 400-401

154
Adam, W.; Fuß, A.; Mazenod, F.P.; Quast, H.
Reluctant Azoalkanes: The Short Wavelength (185 nm) Liquid Phase Photolysis and High Temperature (400-1000 ^oC) Gas-Phase Pyrolysis of 3,3,5,5-Tetramethylpyrazolin-4-one
J. Am. Chem. Soc., 1981, 103, 998-1000

149
Adam, W.; Mazenod, F.
Facile Liquid-Phase Denitrogenation of Reluctant Azoalkanes on Photolysis with 185-nm Radiation
J. Am. Chem. Soc., 1980, 102, 7131-7132

146
Adam, W.; De Lucchi, O.
The Synthesis of Unusual Organic Molecules from Azoalkanes
Angew. Chem., 1980, 92, 815-832; Angew. Chem., Int. Ed. Engl., 1980, 19, 762-779

144
Adam, W.; De Lucchi, O.; Erden, I.
Bicyclic Azoalkanes via Urazoles Derived from Cycloaddition of N-Phenyl-1,2,4-triazoline-3,5-dione with Strained Bicycloalkanes
J. Am. Chem. Soc., 1980, 102, 4806-4809

137
Adam, W.; De Lucchi, O.
Unusual Thermal and Photochemical Transformations of the Azoalkane 2,3-Diaza-7,8-benzotricyclo[4.3.0.0^4,9]nona-2,7-diene
J. Am. Chem. Soc., 1980, 102, 2109-2110

136
Adam, W.; Carballeira, N.; De Lucchi, O.
2,3-Benzobicyclo-[2.2.2]oct-2-ene-5,7-diyl Diradical as a Common Intermediate in the Di-p-methane Rearrangement of 6,7-Benzobicyclo[3.2.1]octa-2,6-diene and the Denitrogenation of the Corresponding Tricycloazoalkane
J. Am. Chem. Soc., 1980, 102, 2107-2109

114
Adam, W.; De Lucchi, O.; Erden, I.
Polycyclic Azoalkanes via Dipolar Cycloaddition of 4-Phenyl-1,2,4-triazoline-3,5-dione with Strained Bicyclic Olefins
Angew. Chem., 1979, 91, 512-515; Angew. Chem., Int. Ed. Engl., 1979, 18, 468-469

CIDNP(3)

56
Adam, W.
The Multiplicity of the Photo-Fries Rearrangement
Chem. Commun., 1974, 289-290

50
Adam, W.; Fischer, H.; Hansen, H.-J.; Heimgartner, H.; Schmid, H.; Waespe, H.-R.
CIDNP Evidence for Divergent Behavior of Singlet and Triplet Radical Pair Encounters in the Photo-Claisen Rearrangement
Angew. Chem., 1973, 85, 669-671; Angew. Chem., Int. Ed. Engl., 1973, 12, 662-663

49
Adam, W.; Arce de Sanabia, J.; Fischer, H.
CIDNP Evidence for Radical Pair Mechanism in Photo-Fries Rearrangement
J. Org. Chem., 1973, 38, 2571-2572

Chemical Education(1)

1004
Valentín, E. M.; Montes, I.; Adam, W.
Counterion Effects in the Nucleophilic Substitution Reaction of the Acetate Ion with Alkyl Bromides in the Synthesis of Esters
J. Chem. Educ., 2009, 86, 1315-1318

Chemiluminscence(85)

1005
Ovchinnikov, M. Y.; Khursan, S. L.; Kazakov, D. V.; Adam, W.
The Theoretical Trajectory for the Chloride-Ion-Induced Generation of Singlet Oxygen in the Decomposition of Dimethyldioxirane
J. Photochem. Photobiol. A: Chem., 2010, 210, 100-107

987
Adam, W.; Trofimov, A.V.
Contemporary Trends in Dioxetane Chemistry.
In The Chemistry of Functional Groups, Peroxides , Rappoport, Z., Marek, I., Eds.; John Wiley & Sons: New York 2006; pp 1171-1209

980
Adam, W.; Kazakov, D.V.; Kazakov, V.P.
Singlet-Oxygen Chemiluminescence in Peroxide Reactions
Chem. Rev., 2005, 105, 3371-3387

975
Adam, W.; Trofimov, A.V.
On the CIEEL Mechanism of Triggerable Dioxetanes: Does the Electron Jump or is it Charge Transfer?
In Proceedings of the 13th International Symposium on Bioluminescence and Chemiluminescence; Tsuji, A., Maeda, M., Matsumoto, 2005; pp 197-200

964
Adam, W.; Saha-Möller, C.R.; Kazakov, D.V.; Kazakov, V.P.; Kiefer, W.; Latypova, R.R.; Schlueker, S.
Singlet-Oxygen Generation in the Reaction of Dioxiranes with Nucleophilic Anions
Photochem. Photobiol. Sci., 2004, 3, 182-188

924
Adam, W.; Kiefer, W.; Schlücker, S.; Saha-Möller, C.R.; Kazakov, D.V.; Kazakov, V.P.; Latypova, R.R.
Formation of Singlet Oxygen During the Decomposition of Dimethyldioxirane, Catalyzed by Anionic Nucleophiles
In Bioluminescence and Chemiluminescence: Progress and Current Applications, Proceedings of the 12th International Symposium 2002; pp 129-132

910
Adam, W.; Trofimov, A.V.
Electron-Transfer-Induced Dioxetane Chemiluminescence.
In Elektronenübertragung in Chemie und Biologie; Russow, J., Schäfer, H.-J., Eds; GDCh: Frankfurt am Main, GDCh-Monograph.;� 2002; Vol. 23, pp 55-62

905
Kazakov, D.V.; Maistrenko, G.Y.; Polyakova, N.P.; Latypova, R.R.; Kazakov, V.P.; Adam, W.; Trofimov, A.V.; Zhao, C.-G.; Kiefer, W.; Schlücker, S.
On the Chemiluminescence in the Oxidation of the Tetravalent Uranium to the Uranyl Ion by Dimethyldioxirane
Luminescence, 2002, 293-298

886
Adam, W.; Arnold, M.A.; Grüne, M.; Nau, W.N.; Pischel, U.; Saha-Möller, C.R.
Spiroiminodihydantoin is a Major Product in the Photooxidation of 2'-Deoxyguanosine by the Triplet States and Oxyl Radicals Generated from Hydroxyacetophenone Photolysis and Dioxetane Thermolysis
Org. Lett., 2002, 4, 537-540

868
Adam, W.; Trofimov, A.V.; Vasil'ev, R.R.
Elucidation of Thermally and Electron-Transfer Induced Chemiluminescence by the Semiempirical PM3 Method
In Chemiluminescence at the Turn of the Millenium. An Indispensible Tool in Modern Chemistry, Biochemistry and Medicine; Alb 2001; pp 11-14

867
Adam, W.; Trofimov, A.V.
Does the Electron Jump or is Charge Transferred in the Triggered CIEEL Mechanism of Dioxetanes?
In Chemiluminescence at the Turn of the Millenium. An Indispensible Tool in Modern Chemistry, Biochemistry and Medicine; Alb 2001; pp 7-10

858
Adam, W.; Arnold, M.A.; Saha-Möller, C.R.
Photooxidative Damage of Guanine in DG and DNA by the Radicals derived from the a Cleavage of the Electronically Excited Carbonyl Products Generated in the Thermolysis of Alkoxymethyl-Substituted Dioxetanes and the Photolysis of Alkoxyacetones
J. Org. Chem., 2001, 66, 597-604

841
Adam, W.; Trofimov, A.V.
The Effect of meta versus para Substitution on the Efficiency of Chemiexcitation in the Chemically Triggered Electron-Transfer-Initiated Decomposition of Spiroadamantyl Dioxetanes
J. Org. Chem., 2000, 65, 6474-6478

835
Adam, W.; Matsumoto, M.; Trofimov, A.V.
Viscosity Dependence of the Chemically Induced Electron-Exchange Chemiluminescence Triggered from a Bicyclic Dioxetane
J. Am. Chem. Soc., 2000, 122, 8631-8634

809
Adam, W.; Matsumoto, M.; Trofimov, A.V.
Hydrogen-Bonding Effects on the Fluorescence versus Electron-Transfer-Initiated Chemiluminescence Spectra of the m-Oxybenzoate Ion Derived from a Bicyclic Dioxetane
J. Org. Chem., 2000, 65, 2078-2082

777
Wilsey, S.; Bernardi, F.; Olivucci, M.; Robb, M.A.; Murphy, S.; Adam, W.
The Thermal Decomposition of 1,2-Dioxetane Revisited
J. Phys. Chem., 1999, 103, 1669-1677

772
Adam, W.; Bronstein, I.; Trofimov, A.V.
Unusual Hydrogen-Bonding Effect on the Fluorescence versus Chemiluminescence (CIEEL) of the Meta-Oxybenzoate Ion
In Bioluminescence and Chemiluminescence: Perspectives for the 21st Century, Proceedings of the 10th International Symposium 1999; pp 33-36

764
Adam, W.; Kurz, A.; Saha-Möller, C.R.
DNA and 2'-Deoxyguanosine Damage in the Horseradish-Peroxidase-Catalyzed Autoxidation of Aldehydes: The Search for the Oxidizing Species
Free Rad. Biol. Med., 1999, 26, 566-579

757
Adam, W.; Bronstein, I.; Trofimov, A.V.; Vasil'ev, R.F.
Solvent-Cage Effect (Viscosity Dependence) as a Diagnostic Probe for the Mechanism of the Intramolecular Chemically Initiated Electron-Exchange Luminescence (CIEEL) Triggered from a Spiroadamantyl-Substituted Dioxetane
J. Am. Chem. Soc., 1999, 121, 958-961

728
Adam, W.; Bronstein, I.; Trofimov, A.V.
Solvatochromic Effects on the Electron Exchabnge Chemiluminescence (CIEEL) of Spiroadamantyl-Substituted Dioxetanes and the Fluorescence of Relevant Oxyanions
J. Phys. Chem., 1998, 102A, 5406-5414

722
Adam, W.; Andler, S.; Nau, W.M.; Saha-Möller, C.R.
Oxidative DNA Damage by Radicals Generated in the Thermolysis of Hydroxymethyl-Substituted 1,2-Dioxetanes through the a-Cleavage of Chemiexcited Ketones
J. Am. Chem. Soc., 1998, 120, 3549-3559

720
Nagel, V.; Duschek, F.; Kiefer, W.; Görth, F.; Golsch, D.; Adam,W.; Ferrer, M.; Messeguer, A.
Detection of Singlet Oxygen During Several Organic Reactions by Chemiluminescence Spectroscopy
Asian J. Spectrosc., 1998, 35-43

680
Adam, W.; Reinhardt, D.
Chemical Triggering of Dioxetanes Derived from 9-Adamantylideneacridanes: Fluoride- and Base-Induced Chemiluminescence (CIEEL) of Siloxy- and Acetoxy-Substituted Dioxetanes
J. Chem. Soc., Perkin Trans. 2, 1997, 1453-1463

673
Adam, W.; Reinhardt, D.
Fluoride- and Base-Induced Chemiluminescence (CIEEL) of a Bifunctional Spiroacridane-Substituted Dioxetane
Liebigs Ann. Chem., 1997, 1359-1364

639
Murphy, S.; Adam, W.
The Elusive 1,4-Dioxy Biradical: Revised Mechanism for the Formation of Diol from 3,3-Dimethyldioxetane in Cyclohexadiene
J. Am. Chem. Soc., 1996, 12916-12921

636
Adam, W.; Reinhardt, D.; Saha-Möller, C.R.
From the Firefly Bioluminescence to the Dioxetane-Based (AMPPD) Chemiluminescence Immunoassay: A Retroanalysis
Analyst, 1996, 121, 1527-1531

634
Adam, W.; Bronstein, I.; Brooks, E.; Engel, T.; Reinhardt, D.; Schneider, F.W.; Trofimov, A.V.; Vasil`ev, R.F.
Electron-Exchange Luminescence of Spiroadamantane-Substituted Dioxetanes Triggered by Alkaline Phosphatase. Kinetics and Elucidation of pH Effects
J. Am. Chem. Soc., 1996, 118, 10400-10407

611
Trofimov, A.V.; Mielke, K.; Vasil'ev, R.F.; Adam, W.
Chemically Initiated Electron- Exchange Luminescence of Silyloxyaryl-Substituted Spiroadamantyl Dioxetanes. Kinetics and Excited-State Yields
Photochem. Photobiol., 1996, 63, 463-467

568
Adam, W.; Ahrweiler, M.; Vlcek, P.
Chemiluminescence of the Labile 1,2-Dioxetanes and Epoxides Produced in the Oxidation of N-Acetylated Dihydro- and Tetrahydropyrazines by Singlet Oxygen, Dimethyldioxirane, and m-Chloroperoxybenzoic Acid
J. Am. Chem. Soc., 1995, 117, 9690-9692

557
Trofimov, A.V.; Vasil'ev, R.F.; Mielke, K.; Adam, W.
Energy-Transfer-Enhanced Chemiluminescence of Adamantanone (n,p^*) and Ester (p,p^*) Singlet and Triplet Excited States in the Thermolysis of Silyloxyaryl-Substituted Spiroadamantyl Dioxetanes
Photochem. Photobiol., 1995, 62, 35-43

549
Adam, W.; Cilento, G.
From Free Radicals to Electronically Excited Species
Free Rad. Biol. Med., 1995, 19, 103-114

499
Adam, W.; Reinhardt, D.
Indole Dioxetanes and Epoxides by Oxidation of N-Acylated Indoles with Singlet Oxygen and Dimethyldioxirane: Kinetics and Chemiluminescence Yields of the Thermal Dioxetane Decomposition and Fluoride-Ion-Induced CIEEL Emission
J. Chem. Soc., Perkin Trans. 2, 1994, 1503-1507

437
Adam, W.; Fell, R.T.; Schulz, M.H.
Synthesis and Fluoride Ion-Triggered Chemiluminescence (CIEEL Mechanism) of Siloxy-Substituted Benzofuran Dioxetanes
Tetrahedron, 1993, 49, 2227-2238

432
Adam, W.; Qian, X.; Saha-Möller, C. R.
Synthesis and Photooxygenation of 2,3,6-Trimethylfuro[2,3-b][1]naphtho[4a,7a-e,f]pyrida-5,7-dione: A Potential Chemiluminescent Probe for Singlet Oxygen
Tetrahedron, 1993, 49, 417-422

426
Adam, W.; Schulz, M.H.
Base-Induced Chemiluminescence from Acetoxy-Substituted Benzofuran Dioxetanes through an Intramolecular Electron Transfer (CIEEL) Mechanism
Chem. Ber., 1992, 125, 2455-2461

400
Albrecht, S.; Brandl, H.; Schönfels, C.; Adam, W.
Angewandte Biolumineszenz: Luciferasen in der biochemischen Analytik
Chemie in unserer Zeit, 1992, 26, 63-69

399
Albrecht, S.; Brandl, H.; Adam, W.
Biochemische Analytik: Angewandte Chemilumineszenz
Nachr. Chem. Lab. Tech., 1992, 40, 547-554

347
Adam, W.; Hauer, H.; Mosandl, T.; Saha-Möller, C.R.; Wagner, W.; Wild, D.
Furocoumarin-, Naphthofuran-, and Furoquinoline-Annulated 1,2-Dioxetanes: Synthesis, Thermolysis, and Mutagenicity
Liebigs Ann. Chem., 1990, 1227-1236

344
Albrecht, S.; Brandl, H.; Adam, W.
Chemilumineszenz Reaktionen. Die Chemilumineszenz und ihre Anwendung in der klinischen Chemie, Biochemie und Medizin
Chemie in unserer Zeit, 1990, 24, 227-238

338
Adam, W.; Beinhauer, A.; Hauer, H.; Saha-Möller, C.R.
Activation Parameters and Excitation Yields of 1,2-Dioxetanes of Photogenotoxic Interest
J. Prakt. Chem., 1990, 332, 161-168

326
Adam, W.; Hückmann, S.; Vargas, F.
Direct Observation of Electron Transfer Between Phenothiazines and 1,2-Dioxetanes
Tetrahedron Lett., 1989, 30, 6315-6318

325
Adam, W.; Beinhauer, A.; Hauer, H.
Activation Parameters and Excitation Yields of 1,2-Dioxetane Chemiluminescence
In Handbook of Organic Photochemistry: Scaiano, J.C., Ed.; CRC Press: Boca Raton, Florida, USA 1989; Vol. II, pp 271-327

301
Adam, W.; Griesbeck, A.G.; Gollnick, K.; Knutzen-Mies, K.
1,2-Dioxetanes Derived from 4,5-Dimethyl-2,3-dihydrofuran and 4,5-Dimethyl-2,3-dihydrothiophene: Synthesis via Photooxygenation, Activation Parameters, and Excitation Properties
J. Org. Chem., 1988, 53, 1492-1495

260
Adam, W.; Baader, W.J.; Cilento, G.
Enols of Aldehydes in the Peroxidase-Oxidase-Promoted Generation of Excited Triplet Species
Biochim. Biophys. Acta, 1986, 881, 330-336

248
Adam, W.; Baader, W.J.; Catalani, L.H.; Cilento, G.; Rychla, L.
Energy Transfer from Chemiexcited Acetone to Substances that Display Anomalous Fluorescence
Photochem. Photobiol., 1985, 42, 587-589

246
Adam, W.; Platsch, H.; Schmidt, E.
Synthesis, Thermal Stability, and Chemiluminescence Properties of Bisdioxetanes Derived from p-Dioxins
Chem. Ber., 1985, 118, 4385-4403

234
Adam, W.; Yany, F.
1,2-Dioxetanes and a-Peroxylactones
In Small Ring Heterocycles, Hassner, A. Ed.; John Wiley and Sons: New York, 1985; Vol. 42, Part 3, Chap 4, pp 351-429

232
Adam, W.; Baader, W.J.
Effects of Methylation on the Thermal Stability and Chemiluminescence Properties of 1,2-Dioxetanes
J. Am. Chem. Soc., 1985, 107, 410-416

229
Adam, W.; Peters, E.-M.; Peters, K.; Platsch, H.; Schmidt, E.; von Schnering, H.G.; Takayama, K.
Synthesis, Thermal Stability, and Chemiluminescence Properties of the Dioxetanes Derived from 1,4-Dioxins
J. Org. Chem., 1984, 49, 3920-3928

228
Adam, W.; Baader, W.J.; Babatsikos, C.; Schmidt, E.
Four-Membered-Ring Peroxide Heterocycles: Photochemistry through the Backdoor
Bull. Soc. Chim. Belg., 1984, 93, 605-617

224
Adam, W.; Arias Encarnacion, L.A.; Cilento, G.; Haun, M.; Nassi, L.
Excitation of Chlorophyll during the Peroxidase-Catalyzed Oxidation of Ethyl a-Formylphenylacetate
Photochem. Photobiol., 1984, 40, 189-192

215
Adam, W.; Baader, W.J.
1,2-Dioxetane: Synthesis, Characterization, Stability and Chemiluminescence
Angew. Chem., 1984, 96, 156; Angew. Chem., Int. Ed. Engl., 1984, 23, 166-167

211
Adam, W.
Four-Membered Ring Peroxides: 1,2-Dioxetanes and a-Peroxylactones
In The Chemistry of Functional Groups, Peroxides, by S. Patai, Ed.; John Wiley & Sons: New York, 1983; Chap. 24, pp 830-920

199
Adam, W.; Arias Encarnacion, L.A.; Zinner, K.
Thermal Stability of Spiro(adamantane-1,2-dioxetanes)
Chem. Ber., 1983, 116, 839-846

198
Adam, W.; Hannemann, K.
The Azoalkane 7,8-Benzo-2,3-diazatricyclo[4.3.0.0^4,9]nona-2,7-diene as Spin-State-Specific Titrant of Singlet and Triplet Excitation Generated in the Thermolysis of Dioxetanes
J. Am. Chem. Soc., 1983, 105, 714-719

197
Schmidt, R.; Brauer, H.-D.; Adam, W.; Zinner, K.
Mediumabhängige Energiewanderung bei der Energietransfer-Chemilumineszenz des Systems Tetramethyl-1,2-dioxetan-9,10-Dibromanthracen in polymeren Matrizen
Z. Physik. Chem., 1982, 131, 129-138

189
Adam, W.
Determination of Chemiexcitation Yields in the Thermal Generation of Electronic Excitation from 1,2-Dioxetanes
In Chemical and Biological Generation of Excited States, Adam, W.; Cilento, G., Eds.; Academic Press: New York 1982; Chap. 4, pp 115-152

188
Adam, W.; Cilento, G.
Chemical and Biological Generation of Excited States
Adam, W.; Cilento, G., Eds.; Academic Press: New York 1982

173
Adam, W.; Cueto, O.
3,3-Dimethyl-4(2-methyl-1-propenyl)-1,2-Dioxetane: Its Thermal Stability and Chemiluminescent Properties
Z. Naturforsch., 1981, 36b, 1653-1654

172
Adam, W.; Cueto, O.; Schmidt, E.; Takayama, K.
Dihydrodioxetobenzodioxins: Synthesis and Chemiluminescence
Angew. Chem., 1981, 93, 1100-1103; Angew. Chem., Int. Ed. Engl., 1981, 20, 1031-1032

167
Adam, W.; Zinner, K.; Krebs, A.; Schmalstieg, H.
Electron-Exchange Chemiluminescence from a Sterically Stabilized Cyclobutadiene-1,2-dioxetane
Tetrahedron Lett., 1981, 22, 4567-4570

155
Adam, W.; Curci, R.
Hyperenergetic Molecules: Dioxiranes and 1,2-Dioxetanes
Chimia e Industria, 1981, 63, 20-28

150
Adam, W.
Thermal Generation of Electronic Excitation with Hyperenergetic Molecules
Pure & Appl. Chem., 1980, 52, 2591-2608

145
Adam, W.; Cilento, G.; Zinner, K.
External Heavy Atom Effect in the Energy Transfer from Chemi-Excited Triplet Acetone to Anthracene
Photochem. Photobiol., 1980, 32, 87-90

143
Adam, W.; Cadilla, C.; Cueto, O.; Rodriguez, L.O.
Fluorescer-Enhanced Chemiluminescence of a Cyclic Peroxalate via Electron Exchange
J. Am. Chem. Soc., 1980, 102, 4802-4805

140
Adam, W.
Thermische Erzeugung elektronisch angeregter Moleküle
Chemie in unserer Zeit, 1980, 14, 44-55

139
Adam, W.; Yany, F.
Thermal Generation of Electronically Excited States by a-Peroxylactones: Activation Parameters and Excitation Yields as a Function of a-Deuteration
Photochem. Photobiol., 1980, 31, 267-272

121
Adam, W.; Cueto, O.
Fluorescencer-Enhanced Chemiluminescence of a-Peroxylactones via Electron Exchange
J. Am. Chem. Soc., 1979, 101, 6511-6515

117
Adam, W.; Cilento, G., Eds.
Chemi- and Bioenergized Processes
Photochem. Photobiol., 1979, 30, 1

116
Adam, W.; Sakanishi, K.
Lack of Heavy Atom Effect on the Activation Parameters of Bromine Substituted 1,2-Dioxetanes
Photochem. Photobiol., 1979, 30, 45-48

113
Adam, W.; Cheng, C.-C.; Cueto, O.; Erden, I.; Zinner, K.
A Stable Bisdioxetane
J. Am. Chem. Soc., 1979, 101, 4735-4736

104
Adam, W.; Cheng, C.-C.; Cueto, O.; Sakanishi, K.; Zinner, K.
Chemical Titration of Thermally Generated Triplets
J. Am. Chem. Soc., 1979, 101, 1324-1325

96
Adam, W.
Bioluminescence: Its Biology, Chemistry and Physics
Revista/Review Interamericana, 1978, 8, 85-98

95
Adam, W.; Rodriguez, O.; Zinner, K.
Triplet-Singlet Energy-Transfer Parameters from Tetramethyl-1,2-dioxetane Chemi-Energized 9,10-Dibromoanthracene Fluorescene in Polymer Matrices
J. Org. Chem., 1978, 43, 4495-4498

89
Adam, W.; Cancio, E.M.; Rodriguez, O.
The Mechanism of the 9,10-Dibromoanthracene-Mediated Triplet-Singlet Energy Transfer in the Tetramethyl-1,2-dioxetane Energized Rubrene Luminescence
Photochem. Photobiol., 1978, 27, 617-624

82
Adam, W.; Cueto, O.; Yany, F.
On the Mechanism of the Rubrene-Enhanced Chemiluminescence of a-Peroxylactones
J. Am. Chem. Soc., 1978, 100, 2587-2589

77
Adam, W.; Cilento, G.; Rodriguez, L.O.; Rodriguez, O.; Sarma, A.S.; Zinner, K.
Acid-Dependent Fluorescence Quantum Yield and Tetramethyl-1,2-Dioxetane Chemi-Energized Flurescence of Ergostatetraenone
Photochem. Photobiol., 1977, 26, 299-303

63
Adam, W.
Biological Light: Peroxylates as Bioluminescent Intermediates
J. Chem. Educ., 1975, 52, 138-145

62
Adam, W.; Duran, N.; Simpson, G.A.
Singlet Acetone Efficiency and Importance of Triplet Acetone Induced Decomposition of Tetramethyl-1,2-dioxetane from Direct Chemiluminescence
J. Am. Chem. Soc., 1975, 97, 5464-5467

61
Schuster, G.B.; Turro, N.J.; Steinmetzer, H.-C.; Schaap, A.P.; Faler, G.; Adam, W.; Liu, J.-C.
Adamantylideneadamantane-1,2-dioxetane. An Investigation of the Chemiluminescence and Decomposition Kinetics of an Usually Stable 1,2-Dioxetane
J. Am. Chem. Soc., 1975, 97, 7110-7118

57
Adam, W.; Simpson, G.A.; Yany, F.
Mechanism of Direct and Rubrene Enhanced Chemiluminescence during a-Peroxylactone Decarboxylation
J. Phys. Chem., 1974, 78, 2559-2569

53
Turro, N.J.; Lechtken, P.; Schuster, G.B.; Orell, J.; Steinmetzer, H.-C.; Adam, W.
Indirect Chemiluminescence by 1,2-Dioxetanes. Evaluation of Triplet Singlet Excitation Efficiencies. A Long Range Singlet-Singlet Energy Transfer and an Efficient Triplet-Singlet Energy Transfer
J. Am. Chem. Soc., 1974, 96, 1627-1629

52
Adam, W.
Biologisches Licht
Chemie in unserer Zeit, 1973, 7, 182-192

39
Adam, W.
The Chemistry of Bioluminescence
Rev. Col. Quim. Puerto Rico, 1972, 31, 11-18

Computational(49)

994
Sajimon, M.C.; Ramaiah, D.; Suresh, C.H.; Adam, W.; Lewis, F.D.; George, M.V.
Photochromic Dibenzobarrelenes: Long-Lived Triplet Biradical Intermediates
J. Am. Chem. Soc., 2007, 129, 9439-9445

985
Sivaguru, J.; Saito, H.; Solomon, M.R.; Kaanamalle, L.; Poon, T.; Jockusch, S.; Ramamurthy, V.; Inoue, Y.; Adam, W.; Turro, N.J.
The Control of Chirality by Cations in Confined Spaces: Photooxidation of Encarbamates Inside Zeolite Supercages
Photochem. Photobiol., 2006, 82, 123-131

932
Adam, W.; Ortega Schulte, C.M.
Spin Delocalization by Triple Bonds, Assessed from the EPR-Spectral D Parameter of 1,3-Cyclopentanediyl Triplet Diradicals
J. Org. Chem., 2003, 68, 1007-1011

889
Cui, M.; Adam, W.; Shen, J.H.; Luo, X.M.; Tan, X.J.; Chen, K.X; Ji, R.Y.; Jiang, H.L.
A Density-Functional Study of the Mechanism for the Diastereoselective Epoxidation of Chiral Allylic Alcohols by the Titanium Peroxy Complexes
J. Org. Chem., 2002, 67, 1427-1435

865
Adam, W.; Bottke, N.; Engels, B.; Krebs, O.
An Experimental and Computational Study on the Reactivity and Regioselectivity for the Nitrosoarene Ene Reaction; Comparison with Triazolinedione and Singlet Oxygen
J. Am. Chem. Soc., 2001, 123, 5542-5548

777
Wilsey, S.; Bernardi, F.; Olivucci, M.; Robb, M.A.; Murphy, S.; Adam, W.
The Thermal Decomposition of 1,2-Dioxetane Revisited
J. Phys. Chem., 1999, 103, 1669-1677

738
Gernet, D.; Adam, W.; Kiefer, W.
Matrix-isolation Raman spectroscopy, semiempirical calculations and normal coordinate analysis of strained systems Part II: Bicyclo[2.1.0]pentane
Vibr. Spectrosc., 1998, 17, 31

691
Adam, W.; Harrer, H.M.
Electronic Substituent Effects in Radical Chemistry: The DD Scale for Benzyl-Type Radicals
Anales de Quimica, 1997, 93, 271-276

280
Adam, W.; Chan, Y.-Y.; Cremer, D.; Gauss, J.; Scheutzow, D.; Schindler, M.
Spectral and Chemical Properties of Dimethyldioxirane as Determined by Experiment and ab initio Calculations
J. Org. Chem., 1987, 52, 2800-2803

20
Adam, W.; Grimison, A.; Sprangle, P.-A.
Convergence of the Perturbation Theory Expansion for Spin-Spin Coupling Constants
Theoret. Chim. Acta (Berlin), 1970, 18, 385-388

19
Adam, W.
Lone-Pair Interactions in Six-Membered Ring Nitrogen Heterocycles
Jerusalem Symp. Quant. Chem., 1970, 2, 118-127

13
Adam, W.; Grimison, A.; Hoffmann, R.
Hetaryne Intermediates
J. Am. Chem. Soc., 1969, 91, 2590-2599

12
Adam, W.; Grimison, A.; Rodriguez, G.
Average-Excitation-Energy Approximation in the Calculation of Carbon-13 Chemical Shifts of Nitrogen Heterocyclics
J. Chem. Phys., 1969, 50, 645-654

11
Adam, W.; Grimison, A.; Hoffmann, R.; Zuazaga de Ortiz, C.
Hydrogen Bonding in Pyridine
J. Am. Chem. Soc., 1968, 90, 1509-1516

10
Adam, W.; Grimison, A.
Sigma-Polarization in 5-Membered Heterocyclic Ring Systems
Theoret. Chim. Acta (Berlin), 1967, 7, 342-351

9
Adam, W.; Grimison, A.; Rodriguez, G.
Effects of Protonation on Electron Densities in Nitrogen Heterocyclic Molecules
Tetrahedron, 1967, 23, 2513-2521

7
Adam, W.; Grimison, A.
Extended Hückel Theory Applied to Electrophilic Substitution in Imidazole
Tetrahedron, 1966, 22, 835-839

6
Adam, W.; Grimison, A.
Extended Hückel Theory Applied to Nucleophilic Substitution in Pyridine, Quinoline and Isoquinoline
Tetrahedron, 1965, 21, 3417-3422

Cyclic Peroxide(410)

1006
Solomon, M. R.; Sivaguru, J.; Jockusch, S.; Adam, W.; Turro, N.
Decoding Stereocontrol During the Photooxygenation of Oxazolodinone-Functionalized Enecarbamates
Org. Lett., 2010, 12, 2142-2145

1003
Solomon, M. R.; Saito , H.; Sivaguru, J.; Jokusch, S.; Inoue, Y.; Adam, W.; Turro,N.J.
Isolation and syn Elimination of a Peterson Adduct to Obtain Optically Pure Product in the Diastereoselective Synthesis of Oxazolidinone-Functionalized Enecarbamates
Lett. Org. Chem., 2009, 6, 362-366

1002
Solomon, M-R.; Sivaguru, J.; Jokusch, S.; Adam, W.; Turro, N.J.
Physical ans Chemical Quenching Rates and their Influence on the Stereoselective Photooxygenation of Oxazolidinone-Functionalized Enecarbamates
Photochem. Photobiol. Sci, 2009, 8, 912-915

1000
Adam, W.; Zhao, C.-G.; Saha-Möller, C.R.; Jakka, K.
Oxidation of Organic Compounds by Dioxiranes
Denmark, S. E., Ed.; John Wiley & Sons, Inc.: Hoboken, New Jersey 2009

998
Solomon, M.R.; Sivaguru, J.; Jockusch, S.; Adam, W.; Turro, N.J.
Vibrational Deactivation of Singlet Oxygen: Does it Play a Role in Stereselectivity during Photooxygenation?
Photochem. Photobiol. Sci., 2008, 7, 531 - 533

997
Sivaguru, J.; Solomon, M.; Poon, T.; Jockusch, S.; Bosio, S.G.; Adam, W.; Turro, N.J.
The Reaction of Singlet Oxygen with Chiral Enecarbamates: A Mechanistic Playground for Investigating Chemoselectivity, Stereoselectivity and Selective Vibratioselectivity of Photooxidations
Acc. Chem. Res., 2008, 41, 387- 400

996
Adam, W.; Zhao, C.-G.; Jakka, K.
Dioxirane Oxidations of Allenes, Alkynes and Arenes, Heteroatom Substrates, Alkanes and Silanes, and Organometallic Compounds
Org. React., 2007, 69, 1-346

992
Moscatelli, A.; Ottaviani, M.F.; Adam, W.; Buchachenko, A.; Jockusch, S.; Turro, N.J.
Interactions between Molecular Oxygen and Nitroxide Radicals: A Search for a Reversible Complex.
Helv. Chim. Acta, 2006, 89, 2441-2449

990
Sivaguru, J.; Poon, T.; Hooper, C.; Saito, H.; Solomon, M.; Jockusch, S.; Adam, W.; Inoue, Y.; Turro, N.J
A Comparative Mechanistic Analysis of the Stereoselectivity Trends Observed in the Oxidation of Chiral Oxazolidinone-Functionalized Enecarbamates by Singlet Oxygen, Ozone and Triazolinedione
Tetrahedron, 2006, 62, 10647-10659

986
Adam, W.; Zhao, C.-G.
Contemporary Dioxirane Chemistry: Epoxidations, Heteroatom Oxidations and CH Insertions.
In The Chemistry of Peroxides , Rappoport, Z., Maeak, I., Eds.; John Wiley & Sons: New York 2006; pp 1129-1169

982
Adam, W.; Zhao, C.-G.
Oxidation of Unactivated Alkanes by Dioxiranes
In Wiley-VCH Handbook of CH Transformations, Dyker, G., Ed.; Wiley-VCH Verlag GmbH: Weinheim, 2005; Chapter IV2.1.2, pp 507-516

980
Adam, W.; Kazakov, D.V.; Kazakov, V.P.
Singlet-Oxygen Chemiluminescence in Peroxide Reactions
Chem. Rev., 2005, 105, 3371-3387

976
Sivaguru, J.; Saito, H.; Poon, T.; Omonuwa, T.; Franz, R.; Jockusch, S.; Inoue, Y.; Adam, W.; Turro, N.J.
Stereoselective Photooxidation of Enecarbamates: Reactivity of Ozone versus Singlet Oxygen
Org. Lett., 2005, 7, 2089-2092

973
Adam, W.; Zhang, A.
Chiral-Auxiliary-Controlled Stereoselective Epoxidation of CC Double Bonds
Synlett, 2005, 1047-1073

971
Sivaguru, J.; Poon, T.; Franz, R.; Jockusch, S.; Adam, W.; Turro, N.J.
Stereocontrol Within Confined Spaces: Enantioselective Photooxidation of Enecarbamates Inside Zeolite Supercages
J. Am. Chem. Soc., 2004, 126, 10816-10817

969
Poon, T.; Sivaguru, J.; Franz, R.; Jockusch, S.; Martinez, C.; Washington, I.; Adam, W. ; Inoue, Y.; Turro, N.J.
Temperature and Solvent Control of the Stereoselectivity in the Reactions of Singlet Oxygen with Oxazolidinone-Substituted Enecarbamates
J. Am. Chem. Soc., 2004, 126, 10498-10499

960
Adam, W.; Zhang, A.
High p-Facial Selectivity through Magnesium Chelation in the DMD Epoxidation of a,b-Unsaturated Amides with Chiral Pyrroliginone Auxiliaries
Eur. J. Org. Chem., 2004, 147-152

959
Chapman, J.R.; Turro, N.J.; Poon, T.; Lakshminarasimhan, P.; Bosio, S.; Adam, W.; Jockusch, S.; Lei, X.; Liu, Z.; Ramamurthy, V.
An Investigation of the Induction Capabilities of Oxazolidinones in the Enantioselective Formation of Methyldeoxybenzoin
In Abstracts of Papers, 225th ACS National Meeting, New Orleans; American Chemical Society: Washington, D. C., 2003; Abstract CHED-394

958
Poon, T.; Turro, N.J.; Chapman, J.; Lakshminarasimhan, P.; Lei, X.; Jockush, S.; Franz, R.; Adam, W.; Bosio, S.G.
Stereochemical Features of the Physical and Chemical Interactions of Singlet Oxygen with Enecarbamates
Org. Lett., 2003, 5, 4951-4953

947
Poon, T.; Turro, N.J.; Chapman, J.; Lakshminarasimhan,P.; Lei, X.; Adam, W.; Bosio, S.G.
A Supramolecular 'Ship in Bottle' Strategy for Enantiomeric Selectivity in Geminate Radical Pair Recombination
Org. Lett., 2003, 5, 2025-2028

938
Adam, W.; Bosio, S.G.; Wolff, B.T.
Chiral-Auxiliary-Controlled Diastereoselectivity in the Epoxidation of Enecarbamates with DMD and m-CPBA
Org. Lett., 2003, 5, 819-822

925
Adam, W.; Zhao, C.-G.; Saha-Möller, C.R.
Dioxirane Epoxidation of Olefins
Org. React., 2002, 61, 219-516

902
Adam, W.; Bosio, S.G.; Turro, N.J.
Highly Diastereoselective Dioxetane Formation in the Photooxygenation of Enecarbamates with an Oxazolidinone Chiral Auxiliary: Steric Control in the [2+2] Cycloaddition of Singlet Oxygen through Conformational Alignment
J. Am. Chem. Soc., 2002, 124, 8814-8815

900
Adam, W.; Bosio, S.G.; Fröhling, B.; Stalke, D.
Unusual Sulfur Chemistry in the Thermal Reaction of Sultene and Thiophene-Endoperoxide Sulfur Donors with Cyclic Alkynes: Reversible Formation of a Persistent Thiirenium Ion and Trapping of a Thiirene by [4+2] Cycloaddition
J. Am. Chem. Soc., 2002, 124, 8316-8320

896
Lévai, A.; Kocevar, M.; Tóth, G.; Simon, A.; Vranicar, L.; Adam, W.
Synthesis and Dimethyldioxirane Oxidation of Tetrahydrobenzofurans
Eur. J. Org. Chem., 2002, 1830-1833

888
Voigt, B.; Porzel, A.; Adam, G.; Golsch, D.; Adam, W.; Wagner, C.; Merzweiler, K.
Synthesis of 2,24-Diepicastasterone and 3,24-Diepicastasterone as Potential Brassinosteroid Metabolites of the Cockroach Periplaneta Americana
Collect. Czech. Chem. Commun., 2002, 67, 91-102

875
Adam, W.; Saha-Möller, C.R.; Ganeshpure, P.A.
Synthetic Applications of Nonmetal Catalysts for Homogeneous Oxidation
Chem. Rev., 2001, 101, 3499-3548

872
Makosza, M.; Adam, W.; Zhao, C.-G.; Surowiec, M.
Oxidation of Nitrobenzylic Carbanions with Dimethyldioxirane. New Synthesis of Quinomethanes and Nitrobenzylic Carbinols. First Examples of Methylation of Carbanions with Dimethyldioxirane
J. Org. Chem., 2001, 66, 55022

869
Adam, W.; Peters, K.; Peters, E.-M.; Schambony, S.B.
Efficient Control of the Diastereoselectivity and Regioselectivity in the Singlet-Oxygen Ene Reaction of Chiral Oxazolidine-Substituted Alkenes by a Remote Urea NH Functionality. Comparison with Dimethyldioxirane and m-Chorobenzoic Acid Epoxidations
J. Am. Chem. Soc., 2001, 123, 7228-7232

862
Patonay, T.; Adam, W.; Lévai, A.; Köver, P.; Németh, M.; Peters, E.-M.; Peters, K.
Chemo- and Diastereoselectivity in the Dimethyldioxirane Oxidation of 2,3-Dihydro-4H-1-benzothiopyran-4-ones and 4H-1-Benzothiopyran-4-ones. Unusual Reactivity of 4H-1-Benzothiopyran-4-one-1-Oxides
J. Org. Chem., 2001, 66, 2275-2280

855
Adam, W.; Schambony, S.B.
Diastereoselective Epoxidation of Oxazolidine-Substituted Alkenes by Dimethyldioxirane and m-Chlorobenzoic Acid: p-Facial Control through Hydrogen Bonding by the Urea Functionality
Org. Lett., 2001, 3, 79-82

852
Lévai, A.; Patonay, T.; Székely, A.; Vass, E.B.; Adam, W.; Jekö, J.
A Comparative Study of the Epoxidation of 2-Substituted Isoflavones by Dimethyldioxirane, Sodium Hypochlorite, and Alkaline Hoydrogen Peroxide (Weitz-Scheffer-Reaction)
J. Heterocycl. Chem., 2000, 37, 1065-1069

838
Adam, W.; Balci, M.; Kiliç, H.
2,3-Dioxabicyclo[2.2.2]oct-7-en-5-one: Synthesis and Reactions of the Keto Endoperoxide of Phenol
J. Org. Chem., 2000, 65, 5926-5931

817
Adam, W.; Mitchell, C.M.; Saha-Möller, C.R.; Weichold, O.
Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes versus Dioxiranes
In Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations for Structure and Bonding; Meunier, B., Ed.; Springer-Verlag: B 2000; pp 237-285

812
Adam, W.; Pastor, A.; Peters, K.; Peters, E.-M.
Opposite p-Face Selectivity for the DMD and m-CPBA Epoxidations of Chiral 2,2-Dimethyloxazolidine Derivatives of Tiglic Amides: Control by Steric Interactions versus Hydrogen Bonding
Org. Lett., 2000, 2, 1019-1022

808
Li, W.; Lei, X-G.; Lem, G.; McDermott, A.E.; Turro, N.J.; Bottke, N.; Adam, W.
Oxygen and Structural Effects on Silicalite ²⁹Si Spin-Lattice Relaxation Studied by High-Resolution 29Si Solid-State NMR Spectroscopy
Chem. Mat., 2000, 12, 731-737

798
Adam, W.; Makosza, M.; Zhao, C.-G.; Surowiec, M.
On the Mechanism of the Dimethyldioxirane Oxidation of H Adducts (Meisenheimer Complexes) Generated from Nitroarenes and Carbanions
J. Org. Chem., 2000, 65, 1099-1101

786
Adam, W.; Saha-Möller, C.R.; Schambony, S.; Schmid, K.S.; Wirth, T.
Stereocontrolled Photooxygenations - A Valuable Synthetic Tool
Photochem. Photobiol., 1999, 70, 476-483

785
Adam, W.; Saha-Möller, C.R.; Zhao, C.-G.
Asymmetric C-H Oxidation of vic Diols to a-Hydroxy Ketones by a Fructose-Derived Dioxirane: Electronic Effects on the Enantioselectivity of Oxygen Transfer
J. Org. Chem., 1999, 64, 7492-7497

781
Adam, W.; Saha-Möller, C.R.; Zhao, C.-G.
Asymmetric Epoxidation of Olefins by Chiral Dioxiranes Generated in situ From Ketones of D-(-)-Quinic Acid
Tetrahedron: Asymmetry, 1999, 10, 2749-2755

779
Rodriguez, G.; Castedo, L.; Dominguez, D.; Sáa, C., Adam, W.
Regioselective Synthesis of Isoquino[1,2-b][3]benzazepines (Homoprotoberberines) through 11-Membered-Ring Stilbene Lactams Obtained by Radical Macrocyclization
J. Org. Chem., 1999, 64, 4830-4833

777
Wilsey, S.; Bernardi, F.; Olivucci, M.; Robb, M.A.; Murphy, S.; Adam, W.
The Thermal Decomposition of 1,2-Dioxetane Revisited
J. Phys. Chem., 1999, 103, 1669-1677

768
Patonay, T.; Adam, W.; Jeko, J.; Kövér, K.E.; Lévai, A.; Németh, M.; Peters, K.
Oxazepines and Thiazepines 36. Diastereoselective Sulfoxidation of 2,3-Dihydro-1,5-Benzothiazepin-4(5H)-ones by Dimethyldioxirane
Heterocycles, 1999, 51, 85-94

762
Adam, W.; Saha-Möller, C.R.; Schambony, S.B.
A Highly Diastereoselective Dioxetane Formation by the Hydroxy-Directed [2+2] Cycloaddition of Singlet Oxygen to a Chiral Allylic Alcohol
J. Am. Chem. Soc., 1999, 121, 1834-1838

756
Rodriguez, G.; Castedo, L., Dominguez, D.; Saá, C.; Adam, W.; Saha-Möller, C.R.
Dioxirane Epoxidation of 10-Membered-Ring Stilbene Lactams as Synthetic Precursors to Protoberberines
J. Org. Chem., 1999, 64, 877-883

752
Patonay, T.; Adam, W.; Levai, A.
Dimethyldioxirane Oxidations of Some Heterocycles Containing Oxygen or Sulfur: Chemo- and Stereoselectivity
In Proceedings of the Blue Danube Symposium on Heterocyclic Chemistry; Kotschy, A., Hajos, G., Eds.; Merlin Multimedia Ltd.: 1998; Paper 11/1-Paper 11/6

750
Adam, W.; Saha-Möller, C.R.; Zhao, C.-G.
Enantioselective Oxidation of vic-Diols to Optically Active a-Hydroxy Ketones by a Fructose-Derived Dioxirane
Tetrahedron: Asymmetry, 1998, 9, 4117-4122

749
Adam, W.; Makosza, M.; Saha-Möller, C.R.; Zhao, C.-G.
A Mild and Efficient Nef Reaction for the Conversion of Nitro to Carbonyl Group by Dimethyldioxirane (DMD) Oxidation of Nitronate Anions
Synlett, 1998, 1335-1336

745
Adam, W.; Balci, M.; Kiliç, H.
Oxyfunctionalization of Biphenylene by Singlet Oxygen, Hydrogen Peroxide/Methyltrioxorhenium, and Dimethyldioxirane
J. Org. Chem., 1998, 63, 8544-8546

744
Malisch, W.; Jehle, H.; Mitchell, C.M.; Adam, W.
A Catalytic Pathway for the Conversion of Tungsten Silanes into Tungsten Silanols
J. Organomet. Chem., 1998, 566, 259-262

743
Malisch, W.; Jehle, H.; Möller, S.; Saha-Möller, C.R.; Adam, W.
Regioselective Hydroxylation of Metallo Disilanes of the Iron Group - An Impressive Example of the Transition Metal Effect
Eur. J. Inorg. Chem., 1998, 1585-1587

739
Ferrer, M.; Sánchez-Baeza, F.; Messeguer, A., Adam, W.; Golsch, D.; Goerth, F.; Kiefer, W.; Nagel, W.
The Release of Singlet Oxygen in the Reaction of Dioxiranes with Amine N-Oxides
Eur. J. Org. Chem., 1998, 2527-2532

735
Lévai, A.; Adam, W.; Fell, R.T.; Gessner, R.; Patonay, T.; Simon, A.; Tóth, G.
Enantioselective Synthesis and Chiroptical Properties of Optically Active Isoflavone Epoxides
Tetrahedron, 1998, 54, 13105-13114

731
Adam, W.; Fröhling, B.; Peters, K.; Weinkötz, S.
Diastereoselective Episulfidation of Strained Cyclic Alkenes by a Thiophene Endoperoxide versus Epoxidation by Dimethyldioxirane (DMD)
J. Am. Chem. Soc., 1998, 120, 8914-8919

727
Adam, W.; Makosza, M.; Stalinski, K.; Zhao, C.-G.
DMD Oxidation of in-situ-Generated H Adducts Derived from Nitroarenes and the Carbanion of 2-Phenylpropionitrile to Phenols: The First Direct Substitution of a Nitro by a Hydroxy Group
J. Org. Chem., 1998, 63, 4390-4391

723
Adam, W.; Güthlein, M.; Peters, E.-M.; Peters, K.; Wirth, T.
Chiral-Auxiliary-Induced Diastereoselectivity in the [4+2] Cycloaddition of Optically Active 2,2-Dimethyloxazolidine Derivatives of Sorbic Acid: A Model Study with Singlet Oxygen as the Smallest Dienophile
J. Am. Chem. Soc., 1998, 120, 4091-4093

719
Adam, W.; Fell, R.T.; Lévai, A.; Patonay, T., Peters, K.; Simon, A.; Tóth, G.
Enantioselective Epoxidation of Isoflavones by Jacobsen's Mn(III)salen Catalysts and Dimethyldioxirane Oxygen-Atom Source
Tetrahedron: Asymmetry, 1998, 9, 1121-1124

702
Peters, K.; Peters, E.-M.; Adam, W.; Ahrweiler, M.; Vlcek, P.
Crystal Structure of N,N'-diacetyl-N,N'-dibenzoyl-1,2-ethylendiamine, (CH₃CO)₂(C₆H₅CO)₂C₂H₄N₂
Z. Kristallogr., 1998, 301-302

699
Adam, W.; Fell, R.T.; Saha-Möller, C.R.; Zhao, C.-G.
Synthesis of Optically Active a-Hydroxy Ketones by Enantioselective Oxidation of Silyl Enol Ethers with a Fructose-Derived Dioxirane
Tetrahedron: Asymmetry, 1998, 397-401

694
Adam, W.; Paredes, R.; Smerz, A.K.; Veloza, L.A.
Regio-, Diastereo- and Chemoselectivities in the Dioxirane Oxidation of Acyclic and Cyclic Allylic Alcohols by Methyl(trifluoromethyl)dioxirane (TFD): A Comparison with Dimethyldioxirane
Eur. J. Org. Chem., 1998, 349-354

690
Adam, W.; Zhao, C.-G.
Synthesis of Optically Active C₂-Symmetric Ketones for the Asymmetric Epoxidation of Prochiral Olefins by Dioxiranes Generated in situ with Caroate^TM as Peroxide Source
Tetrahedron: Asymmetry, 1997, 8, 3995-3998

689
Schenk, W.A.; Steinmetz, B.; Hagel, M.; Adam, W.; Saha-Möller, C.R.
Oxyfunctionalization of Allyl-Thioether-Ruthenium Complexes with Dimethyldioxirane
Z. Naturforsch., 1997, 1359-1371

674
Adam, W.; Mitchell, C.M.; Paredes, R.; Smerz, A.K.; Veloza, L.A.
1-Methylgeraniol as Novel Regio- and Diasteeoselective Probe for Hydrogen Bonding in Hydroxy-Assisted Oxygen-Transfer Reactions
Liebigs Ann. Chem., 1997, 1365-1369

673
Adam, W.; Reinhardt, D.
Fluoride- and Base-Induced Chemiluminescence (CIEEL) of a Bifunctional Spiroacridane-Substituted Dioxetane
Liebigs Ann. Chem., 1997, 1359-1364

670
Schenk, W.A.; Frisch, J.; Dürr, M.; Burzlaff, N.; Stalke, D.; Fleischner, R.; Adam, W.; Prechtl, F.; Smerz, A.
Oxidation of Thioether Ligands in Pseudotetrahedral Cyclopentadienylruthenium Complexes: Toward a New Stereoselective Synthesis of Chiral Sulfoxides
Inorg. Chem., 1997, 36, 2372-2378

662
Adam, W.; Corma, A.; Martinez, A.; Mitchell, C.M.; Reddy, I.; Renz, M.; Smerz, A.K.
Diastereoselective Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by Titanium-Containing Zeolites or Methyltrioxorhenium versus Stoichiometric Oxidation with Dimethyldioxirane: Clues on the Active Species of the Zeolite Lattice
J. Mol. Cat., 1997, 117A, 357-366

658
Adam, W.; Blancafort, L.
Reaction of a-Peroxy Lactones with C, N, P and S Nucleophiles: Adduct Formation and Nucleophilic Oxidation by Nucleophilic Attack and Biphilic Insertion into the Peroxide Bond
J. Org. Chem., 1997, 62, 1623-1629

657
Adam, W.; Smerz, A.K.; Zhao, C.-G.
Dioxiranes - Highly Reactive Oxidants for Stereoselective Oxyfunctionalizations
J. Prakt. Chem., 1997, 339, 298-300

656
Adam, W.; Lévai, A.; Mérour, J.-Y.; Nemes, C.; Patonay, T.
Dioxirane Oxidation of 2-Arylidene-2,3-dihydro-1H-indol-3-ones. Diastereoselective Formation of Spiroepoxides
Synthesis, 1997, 268-270

655
Adam, W.; Paredes, R.; Smerz, A.K.; Veloza, L.A.
Probing for Steric and Electronic Effects in Diastereoselective Dioxirane Epoxidations Compared to the Oxygen Transfer by Peroxy Acids
Liebigs Ann. Chem., 1997, 547-551

650
Adam, W.; Saha-Möller, C.R.; Schönberger, A.
Type I and Type II Photosensitized Oxidative Modification of 2'-Deoxyguanosine (dGuo) by Triplet-Excited Ketones Generated Thermally from the 1,2-Dioxetane HTMD
J. Am. Chem. Soc., 1997, 119, 719-723

646
Adam, W.; Curci, R.; D'Accolti, L.; Dinoi, A.; Fusco, C.; Gasparrini, F.; Kluge, R.; Paredes, R.; Schulz, M.; Smerz, A.K.; Veloza, L.A.; Weinkötz, S.; Winde, R.
Epoxidation and Oxygen Insertion into Alkane CH Bonds by Dioxirane Do Not Involve Detectable Radical Pathways
Chem. Eur. J., 1997, 3, 105-109

645
Adam, W.; Andler, S.; Ballmeier, D.; Emmert, S.; Epe, B.; Grimm, G.N.; Mielke, K.; Möller, M.; Rünger, T.M.; Saha-Möller, C R.; Schönberger, A.
Oxidative DNA Damage Induced by Dioxetanes, Photosensitizing Ketones, and Photo-Fenton Reagents
In Recent Results in Cancer Research; H.K. Müller-Hermelink, H.G. Neumann, W. Dekant, Eds.; Springer Verlag: Berlin, Heidelbe 1997; Vol. 143, pp 21-34

643
Saha-Möller, C.R.; Adam, W.
Four-Membered Rings with Two Oxygen Atoms: Dioxetanes
In Comprehensive Heterocyclic Chemistry, 2nd Ed. (CHEC-2), A. R. Katritzky, C. W. Rees, E. F. V. Scriven, Eds. in Chief; 3- a 1996; Chap. 1.33, pp 1041-1082

641
Heindl, D.; Josel, H.-P.; von der Eltz, H.; Herrmann, R.; Höltke, H.-J.; Beckert, R.; Weiss, D.; Adam, W.
Heterocyclische Dioxetan-Substrate, Verfahren zur Herstellung und Verwendung
Patent DE 19538708.2 1996

640
Adam, W.; Putterlik, J.; Schuhmann, R.M.; Sundermeyer, J.
Synthesis of Tris(pyrazolyl)borate-Stabilized Vinyl, Allyl and Homoallyl Tungsten Oxides and Their Selective Oxyfunctionalization by Singlet Oxygen and Dioxirane
Organometallics, 1996, 15, 4586-4596

639
Murphy, S.; Adam, W.
The Elusive 1,4-Dioxy Biradical: Revised Mechanism for the Formation of Diol from 3,3-Dimethyldioxetane in Cyclohexadiene
J. Am. Chem. Soc., 1996, 12916-12921

636
Adam, W.; Reinhardt, D.; Saha-Möller, C.R.
From the Firefly Bioluminescence to the Dioxetane-Based (AMPPD) Chemiluminescence Immunoassay: A Retroanalysis
Analyst, 1996, 121, 1527-1531

633
Adam, W.; Saha-Möller, C.R.; Schönberger, A.
Photooxidation of 8-Oxo-7,8-dihydro-2'-deoxyguanosine by Thermally Generated Triplet-Excited Ketones from 3-(Hydroxymethyl)-3,4,4-trimethyl-1,2-dioxetane and Comparison with Type I and Type II Photosensitizers
J. Am. Chem. Soc., 1996, 118, 9233-9238

630
Adam, W.; Smerz, A.K.
Chemistry of Dioxiranes: Selective Oxidations
Bull. Soc. Chim. Belg., 1996, 105, 581-599

628
Adam, W.; Jekö, J.; Lévai, A.; Majer, Z.; Nemes, C.; Patonay, T.; Párkányi, L.; Sebök, P.
Determination of the Absolute Configuration of Optically Active 2,2-Dimethyl-3,4-epoxychromans Prepared by the Catalytic Enantioselective Epoxidation with the Dimethyldioxirane/Jacobsen Mn(II)salen System
Tetrahedron: Asymmetry, 1996, 7, 2437-2446

624
Voigt, B.; Porzel, A.; Golsch, D.; Adam, W.; Adam, G.
Regioselective Oxyfunctionalization of Brassinosteroids by Methyl(trifluoromethyl)dioxirane: Synthesis of 25-Hydroxybrassinolide and 25-Hydroxy-24-epibrassinolide by Direct CH Insertion
Tetrahedron Lett., 1996, 52, 10653-10658

623
Patonay, T.; Lévai, A.; Nemes, C.; Timár, T.; Tóth, G.; Adam, W.
Synthesis and Cyclization of 1-(2-Hydroxyphenyl)-2-propene-1-one Epoxides: 3-Hydroxy-chromanones and -flavones versus 2-(1-Hydroxyalkyl)-3-coumaranones
J. Org. Chem., 1996, 61, 5375-5383

616
Adam, W.; Blancafort, L.
Steric and Stereoselective Control of the Mode Selectivity as a Function of Alkene Structure in the Reaction with Dimethyl a-Peroxy Lactone: Cycloadducts and Ene Products versus Epoxides
J. Am. Chem. Soc., 1996, 118, 4778-4787

615
Adam, W.; Smerz, A.K.
Solvent Effects in the Regio- and Diastereoselective Epoxidations of Acyclic Allylic Alcohols by Dimethyldioxirane: Hydrogen Bonding as Evidence for a Dipolar Transition State
J. Org. Chem., 1996, 61, 3506-3510

614
Adam, W.; Prein, M.
The p-Facial Diastereoselectivity in the [4+2] Cycloaddition of Singlet Oxygen as Mechanistic Probe
Acc. Chem. Res., 1996, 29, 275-283

609
Briviba, K.; Saha-Möller, C.R.; Adam, W.; Sies, H.
Formation of Singlet Oxygen in the Thermal Decomposition of 3-Hydroxymethyl-3,4,4-trimethyl-1,2-dioxetane, A Chemical Source of Triplet-Excited Ketones
Biochem. Mol. Biol. Int., 1996, 38, 647-651

607
Adam, W.; Smerz, A.K.
Nickel-Catalyzed Hydroxylation of 1,3-Dicarbonyl Compounds by Dimethyldioxirane
Tetrahedron, 1996, 52, 5799-5804

606
Adam, W.; Korb, M.
Diastereoselective Oxidation of Lithium and Chlorotitanocene Enolates Derived from Camphor
Tetrahedron, 1996, 52, 5487-5494

605
Adam, W.; Schuhmann, R.M.
Selective Oxyfunctionalization of (Tricarbonylcyclohexadiene)iron-Substituted Furans with Singlet Oxygen and Dimethyldioxirane
Liebigs Ann. Chem., 1996, 635-640

604
Lévai, A.; Adam, W.; Jekö, J.; Nemes, C.; Patonay, T.
Dimethyldioxirane Epoxidation of Chalcone and Isoflavone Glycoside Acetates
In Flavonoids and Bioflavonoids. Proceedings of the International Bioflavonoid Symposium, Vienna, Austria; S. Antus, M. Gabor 1996; pp 167-176

603
Patonay, T.; Adam, W.; Halász, J.; Lévai, A.; Nemes, C.; Tóth, G.
Oxidations of Benzopyrans, Benzofurans and Related Compounds: One Step Ahead
In Flavonoids and Bioflavonoids. Proceedings of the International Bioflavonoid Symposium, Vienna, Austria; S. Antus, M. Gabor 1996; pp 329-333

596
Adam, W.; Halász, J.; Jámbor, Z.; Lévai, A.; Nemes, C.; Patonay, T.; Tóth, G.
Synthesis and Stereochemistry of the Epoxides of 2-Arylmethylidene-1-tetralones
J. Chem. Soc., Perkin Trans. 1, 1996, 4, 395-400

590
Adam, W.; Weinkötz, S.
Synthesis of Thiiranes through Direct Sulfur Transfer to Cycloalkanes in the Thermolysis of a Thiophene Endoperoxide
Chem. Commun., 1996, 177-178

589
Adam, W.; van Barneveld, C.; Golsch, D.
Direct Synthesis of 3-Aryl-1,2,4,5-tetrazine N-1-Oxides by the Oxidation with Methyl(trifluoromethyl)-dioxirane
Tetrahedron, 1996, 52, 2377-2384

585
Lévai, A.; Adam, W.; Halász, J.; Nemes, C.; Patonay, T.; Tóth, G.
Dioxirane Oxidation of Benzopyranes, Benzothiopyrans and Related Compounds
Chem. Heterocycl. Comp.(USSR)(Engl.Tr.), 1995, 10, 1345-1349

577
Malisch, W.; Schmitzer, S.; Lankat, R.; Neumayer, M.; Prechtl, F.; Adam, W.
Metallosilanole vom Typ C₅R₅(OC)₂(Me₃P)M-SiPh₂OH (M=Cr, Mo, W): Darstellung nach der Dimethyldioxiranmethode und Überführung in funktionalisierte Metallodisiloxane
Chem. Ber., 1995, 128, 1251-1255

576
Malisch, W.; Neumayer, M.; Fey, O.; Adam, W.; Schuhmann, R.M.
Synthese des diastereomerenreinen Ferriosilanols (RS,SR)-Cp (OC) (Ph₃P)Fe-Si(Me)(Ph)(OH) und Struktur von (RR,SS)-Cp(OC)(Ph₃P)Fe-Si(Me)(Ph)Cl
Chem. Ber., 1995, 128, 1257-1260

574
Adam, W.; Smerz, A.K.
Solvent Effects in the Dimethyldioxirane Oxidation of Allylic Alcohols: Evidence for Hydrogen Bonding in the Dipolar Transition State of Oxygen Transfer
Tetrahedron, 1995, 51, 13039-13044

573
Adam, W.; Prein, M.
p-Facial Selectivity of the Singlet Oxygen [4+2] Cycloaddition to Chiral Naphthalene Derivatives: The Directing Effect of Carbon-Containing Substituents
Tetrahedron, 1995, 51, 12583-12590

572
Adam, W.; Reinhardt, D.; Reissig, H.-U.; Paulini, K.
Epoxidation of Vinylamides by Dimethyldioxirane: First Spectral Evidence for Enamide Oxides
Tetrahedron, 1995, 51, 12257-12262

571
Adam, W.; Kumar, A.S.; Saha-Möller, C.R.
Photooxygenation of Vinyl Sulfides: Substituent Effects on the [2+2] Cycloaddition versus Schenck Reaction Modes
Tetrahedron Lett., 1995, 36, 7853-7854

570
Adam, W.; Briviba, K.; Duschek, F.; Golsch, D.; Kiefer, W.; Sies, H.
Formation of Singlet Oxygen in the Deoxygenation of Heteroarene N-Oxides by Dimethyldioxirane
Chem. Commun., 1995, 1831-1832

566
Adam, W.; Weinkötz, S.
Triphenylphosphine Reduction of Thiophene Endoperoxides: Nucleophilic Attack on Sulfur versus Biphilic Insertion into the Peroxide Bond
Tetrahedron Lett., 1995, 36, 7431-7432

563
Malisch, W.; Hindahl, K.; Käb, H.; Reising, J.; Adam, W.; Prechtl, F.
Die ersten Hydroxysilandiylverbrückten Zweikernkomplexe: Selektive Oxygenierung der Silicium-Brücke in Silandiyleisen Komplexen mit Dimethyldioxiran
Chem. Ber., 1995, 128, 963-965

562
Adam, W.; Gläser, J.; Peters, K.; Prein, M.
Highly like-Selective [4+2] Cycloadditions of Chiral Dienols: The Importance of 1,3-Allylic Strain in the Hydroxy-Directed Stereocontrol
J. Am. Chem. Soc., 1995, 117, 9190-9193

559
Adam, W.; Saha-Möller, C.R.; Schönberger, A.; Berger, M.; Cadet, J.
Formation of 7,8-Dihydro-8-oxoguanine in the 1,2-Dioxetane-Induced Oxidation of Calf Thymus DNA: Evidence for Photosensitized DNA Damage by Thermally Generated Triplet Ketones in the Dark
Photochem. Photobiol., 1995, 62, 231-238

556
Adam, W.; Jekö, J.; Lévai, A.; Nemes, C.; Patonay, T.
Dimethyldioxirane Epoxidation of Chalcone and Isoflavone Glycoside Acetates
Liebigs Ann. Chem., 1995, 1547-1549

555
Adam, W.; Sauter, M.
Oxyfunctionalization of Benzofurans by Singlet Oxygen, Dioxiranes, and Peracids: Chemical Model Studies for the DNA-Damaging Activity of Benzofuran Dioxetanes (Oxidation) and Epoxides (Alkylation)
Acc. Chem. Res., 1995, 28, 289-298

554
Adam, W.; Prechtl, F.; Richter, M.J.; Smerz, A.K.
Epoxidation versus Allylic Oxidation (CH Insertion) in the Oxyfunctionalization of Vinylsilanes and b-Hydroxy Derivatives by Dimethyldioxirane
Tetrahedron Lett., 1995, 36, 4991-4994

552
Adam, W.; Griesbeck A.G.
Photooxidation of 1,3-Dienes
In CRC Handbook of Organic Chemistry and Photobiology; W.M. Horspool; P.-S. Song, Eds.; CRC Press Inc.: London 1995; pp 311-324

550
Adam, W.; Peters, E.-M.; Peters, K.; Prein, M.; von Schnering, H.G.
Diastereoselective Photooxygenation of Chiral Naphthyl Alcohols: The Hydroxy Group-Directing Effect in the Singlet Oxygen [4+2] Cycloaddition to Arenes
J. Am. Chem. Soc., 1995, 117, 6686-6690

547
Adam, W.; Jekó, J.; Lévai, A.; Nemes, C.; Patonay, T.; Sebok, P.
Enantioselective Epoxidation of 2,2-Dimethyl-2H-chromenes by Dimethyldioxirane and Jacobsen's Mn(III)salen Catalysts
Tetrahedron Lett., 1995, 36, 3669-3672

545
Adam, W.; Jacob, U.; Prein, M.
Importance of Steric Effects in the [4+2] Cycloaddition of 5-Substituted Pentamethylcyclopentadienes
Chem. Commun., 1995, 839-840

544
Adam, W.; Stössel, R.; Treiber, A.
The S_N2 Reactivity of 3,3-Disubstituted 1,2-Dioxetanes with Morpholine
J. Org. Chem., 1995, 60, 2879-2884

536
Adam, W.; Treiber, A.
Oxidation of Acetylated Guanosine by 3,3-Disubstituted 1,2-Dioxetanes through Nucleophilic Attack on the Peroxide Bond: Model Studies on the Oxidative DNA Damage by Reactive Peroxides
J. Am. Chem. Soc., 1995, 117, 2686-2693

533
Adam, W.; Ahrweiler, M.; Balci, M.; Cakmak, O.; Saha-Möller, C.R.
Rearrangement and Valence Isomerization in the Dimethyldioxirane Epoxidation of 2,3,5,6-Tetramethoxybenzobarrelene to Benzonorcaradiene endo-Ester
Tetrahedron Lett., 1995, 36, 1429-1430

530
Emmert, S.; Epe, B.; Saha-Möller, C.R.; Adam, W.; Rünger, T.M.
Assessment of Genotoxicity and Mutagenicity of 1,2-Dioxetanes in Human Cells Using a Plasmid Shuttle Vector
Photochem. Photobiol., 1995, 61, 136-141

526
Adam, W.; Schuhmann, R.M.
Synthesis of Epoxyferrocenes by the Oxidation of Acyl- and Allylsubstituted Ferrocenes with Dimethyldioxirane
J. Organomet. Chem., 1995, 487, 273-277

516
Adam, W.; Golsch, D.; Hadjiarapoglou, L.; Lévai, A.; Nemes, C.; Patonay, T.
Dioxirane Oxidation of (Z)-1-Thioaurones, (E)-3-Arylidene-1-thiochroman-4-ones and (E)-3-Arylidene-1-thioflavan-4-ones
Tetrahedron, 1994, 50 , 13113-13120

514
Adam, W.; Sauter, M.
Rearrangement of 2,3-Disubstituted Benzofuran Epoxides Prepared by Dimethyldioxirane Oxidation
Tetrahedron, 1994, 50, 11441-11446

512
Adam, W.; Harrer, H.M.; Treiber, A.
Synthesis of 1,4-Dioxa-2l⁵-phosphorinanes by Insertion of Triphenylalkylidenephosphoranes into the Peroxide Bond of 1,2-Dioxetanes: Thermolysis, Hydrolysis and Wittig Olefination
J. Am. Chem. Soc., 1994, 116, 7581-7587

509
Schenk, W.A.; Frisch, J.; Adam, W.; Prechtl, F.
Oxidation of Metal-Coordinated Thioethers with Dimethyldioxirane - A New Stereoselective Synthesis of Chiral Sulfoxides
Angew. Chem., 1994, 106, 1699-1701; Angew. Chem., Int. Ed. Engl., 1994, 33, 1609-1611

508
Adam, W.; Halász, J.; Lévai, A.; Nemes, C.; Patonay, T.; Tóth, G.
Dimethyldioxirane Oxidation of 3-Arylidenechromanones
Liebigs Ann. Chem., 1994, 795-803

507
Adam, W.; Ahrweiler, M.; Reinhardt, D.
Thermal and Bromide-Ion-Catalyzed Rearrangement of Benzofuran Dioxetanes to 1-Oxaspiro[2.5]-octa-5,7-dien-4-ones
J. Am. Chem. Soc., 1994, 116, 6713-6718

505
Adam, W.; Ahrweiler, M.; Reinhardt, D.; Sauter, M.
Facile Triphenylphosphine Deoxygenation of Benzofuran Dioxetanes, their Epoxides and Valence Isomeric Quinone Methides
Tetrahedron Lett., 1994, 35, 6063-6066

504
Adam, W.; Hadjiarapoglou, L.; Mielke, K.; Treiber, A.
Competitive Epoxidation and Quinone Formation in the Dimethyldioxirane Oxidation of Diazoquinones as Ambident Nucleophiles
Tetrahedron Lett., 1994, 35, 5625-5628

503
Adam, W.; Balci, M.; Cakmak, O.; Peters, K.; Saha-Möller, C.R.; Schulz, M.H.
Photooxygenation of Tetramethoxybenzobarrelene: Synthesis and Thermal Decomposition of Bisdioxetane and Endoperoxide
Tetrahedron, 1994, 50, 9009-9024

500
Adam, W.; Sauter, M.
Dioxirane Oxidation of Furocoumarins and Naphthofurans. Preparation of the Psoralen Epoxides
Liebigs Ann. Chem., 1994, 689-693

498
Adam, W.; Andler, S.
Thermolysis of 3,3-Bis(phenylmethyl)-1,2-dioxetane: Radical-Induced Formation of the Unusual Decomposition Product 3-Phenyl-1-(phenylmethoxy)-2-propanone
J. Am. Chem. Soc., 1994, 116, 5674-5678

497
Adam, W.; Sauter, M.
Generation of 1,2-Dioxetane Decomposition Products in the Oxidation of 3-Phenyl-2-methylbenzofuran Epoxide by Dimethyldioxirane and the Oxodiperoxomolybdenum Complex
Tetrahedron, 1994, 50, 8393-8398

493
Adam, W.; Shimizu, M.
The Acid-Catalyzed Oxidation of Methoxybenzenes to p-Benzoquinones by Dimethyldioxirane
Synthesis, 1994, 560-562

489
Adam, W.; Prein, M.
Substituent Effects in the Diastereoselective [4+2] Cycloaddition of Chiral Naphthalene Derivatives with Singlet Oxygen
Tetrahedron Lett., 1994, 35, 4331-4334

488
Adam, W.; Sauter, M.; Zünkler, C.
Preparation of 2H-Benzoxetes by Photoinduced [2+2] Cycloaddition of Quinone Methides, Accessible by Dimethyldioxirane (DMD) Oxidation of 2,3-Dimethylbenzofurans
Chem. Ber., 1994, 127, 1115-1118

487
Adam, W.; Golsch, D.
Thianthrene 5-Oxide (SSO) as a Mechanistic Probe of the Electrophilic Character in the Oxygen Transfer by Dioxiranes
Chem. Ber., 1994, 127, 1111-1113

486
Adam, W.; Ahrweiler, M.; Peters, K.; Schmiedeskamp, B.
Oxidation of N-Acylindoles by Dimethyldioxirane and Singlet Oxygen: Substituent Effects on Thermally Persistent Indole Epoxides and Dioxetanes
J. Org. Chem., 1994, 59, 2733-2739

480
Adam, W.; Prechtl, F.
Enantioselective Oxidation of Chiral Titanium Enolates Derived from Propiophenone by Dimethyldioxirane or 3-Phenyl-2-phenylsulfonyloxaziridine
Chem. Ber., 1994, 127, 667-671

478
Adam, W.; Treiber, A.
1,3-Dioxolane Formation by Nucleophilic Attack of Diazoalkanes on the Peroxide Bond of 1,2-Dioxetanes
J. Org. Chem., 1994, 59, 840-844

476
Nemes, C.; Lévai, A.; Patonay, T.; Tóth, G.; Boros, S.; Halász, J.; Adam, W.; Golsch, D.
Dioxirane Oxidation of 3-Arylideneflavanones: Diastereoselective Formation of trans,trans-Spiroepoxides from the E Isomers
J. Org. Chem., 1994, 59, 900-905

473
Adam, W.; Käb, G.; Sauter, M.
Thermal and Photochemical Rearrangement of 3-Substituted 2-Methylbenzofuran Epoxides and their Valence-Isomeric Quinone Methides
Chem. Ber., 1994, 127, 433-436

472
Adam, W.; Peters, K.; Sauter, M.
Dimethyldioxirane Epoxidation of 3-Phenyl-Substituted Benzofurans: A Reversible Valence Isomerization between Benzofuran Epoxides and Quinone Methides
Synthesis, 1994, 111-119

471
Adam, W.; Prechtl, F.; Richter, M.J.; Smerz, A.K.
Oxidation of Allylic Alcohols by Dimethyldioxirane: Competition Reactions between Epoxidation and C-H Insertion
Tetrahedron Lett., 1993, 34, 8427-8430

466
Adam, W.; Sauter, M.
Photochemical and Thermal Rearrangement of Acyl-Substituted Quinone Methides, Accessible by Dimethyldioxirane Oxidation of Benzofurans and Subsequent Valence Isomerization of the Resulting Epoxides
Chem. Ber., 1993, 126, 2697-2699

462
Adam, W.; Hadjiarapoglou, L.; Peters, K.; Sauter, M.
Dimethyldioxirane Epoxidation of Benzofurans: Reversible Thermal and Photochemical Valence Isomerization between Benzofuran Epoxides, Quinone Methides and Benzoxetenes
J. Am. Chem. Soc., 1993, 115, 8603-8608

459
Adam, W.; Ahrweiler, M.; Sauter, M.; Schmiedeskamp, B.
Oxidation of Indoles by Singlet Oxygen and Dimethyldioxirane: Isolation of Indole Dioxetanes and Epoxides by Stabilization through Nitrogen Acylation
Tetrahedron Lett., 1993, 34, 5247-5250

457
Asensio, G.; González Nuñez, M.E.; Boix Bernardini, C.; Mello, R.; Adam, W.
Regioselective Oxyfunctionalization of Unactivated Tertiary and Secondary C-H Bonds of Alkylamines by Methyl(trifluoromethyl)dioxirane in Acid Medium
J. Am. Chem. Soc., 1993, 115, 7250-7253

455
Patonay, T.; Tóth, G.; Adam, W.
A Convenient and General Synthesis of trans-3-Hydroxyflavones from Chalcones by Dimethyldioxirane Epoxidation and Subsequent Base-Catalyzed Cyclization
Tetrahedron Lett., 1993, 34, 5055-5058

454
Adam, W.; Qian, X.; Saha-Möller, C.R.
Synthesis and Photooxygenation of the 2H-4,8,9-Trimethylfuro[2',3':5,6]naphtho[1,2-b]pyran-2-one, an Unnatural Furocoumarin with a Benzene Spacer
J. Org. Chem., 1993, 58, 3769-3771

449
Adam, W.; Golsch, D.
S_N2 Reaction versus Electron Transfer in the Oxygen Transfer by Dimethyldioxirane to Nitrogen Heteroarenes
Angew. Chem., 1993, 105, 770-773; Angew. Chem., Int. Ed. Engl., 1993, 32, 737-739

448
Adam, W.; Hadjiarapoglou, L.; Peters, K.; Sauter, M.
Epoxidation of 2-Methyl-3-phenylbenzofurans with Dimethyldioxirane: A Novel, Reversible Valence Isomerization between Labile Benzofuran Epoxides and Quinone Methides, their Rearrangement, Methanolysis and Cycloaddition Chemistry
Angew. Chem., 1993, 105, 769-770; Angew. Chem., Int. Ed. Engl., 1993, 32, 735-736

442
Epe, B.; Henzel, H.; Adam, W.; Saha-Möller, C.R.
Endonuclease-Sensitive DNA Modifications Induced by Acetone and Acetophenone Photosensitization
Nucleic Acid Res., 1993, 21, 863-869

440
Adam, W.; Ahrweiler, M.; Saha-Möller, C.R.; Sauter, M.; Schönberger, A.; Epe, B.; Müller, E.; Schiffmann, D.; Stopper, H.; Wild, D.
Genotoxicity Studies of Benzofuran Dioxetanes and Epoxides with Isolated DNA, Bacteria and Mammalian Cells
Toxicol. Lett., 1993, 67, 41-55

437
Adam, W.; Fell, R.T.; Schulz, M.H.
Synthesis and Fluoride Ion-Triggered Chemiluminescence (CIEEL Mechanism) of Siloxy-Substituted Benzofuran Dioxetanes
Tetrahedron, 1993, 49, 2227-2238

436
Adam, W.; Hadjiarapoglou, L.
Dioxiranes: Oxidation Chemistry Made Easy
Top. Curr. Chem., 1993, 164, 45-62

435
Adam, W.; Ahrweiler, M.; Sauter, M.
Photosensitized Oxygenation of an Acyl Furan: Isolation of the First Furan Dioxetane by Rearrangement of its Endoperoxide and Selected Chemical Transformations
Angew. Chem., 1993, 105, 104-105; Angew. Chem., Int. Ed. Engl., 1993, 32, 80-81

431
Epe, B.; Müller, E.; Adam, W.; Saha-Möller, C.R.
Photochemical DNA Modifications Induced by 1,2-Dioxetanes
Chem.-Biol. Interactions, 1992, 85, 265-281

430
Adam, W.; Albert, R.
Synthesis and Reactions of the Cyclic Silyl Peroxide 1,1,4,4-Tetramethyl-2,3-dioxa-1,4-disilacyclohexane
Tetrahedron Lett., 1992, 52, 8015-8016

429
Adam, W.; Ahrweiler, M.; Paulini, K.; Reissig, H.-U.; Voerckel, V.
Dimethyldioxirane Oxidation of Enamines: First Spectral Evidence for Enamine Oxides by Stabilization through N-Silylation
Chem. Ber., 1992, 125, 2719-2721

427
Adam, W.; Heil, M.
Evidence for a 1,4-Dioxyl Diradical as an Intermediate in the Thermal Decomposition of 3,3-Dibenzyl-1,2-dioxetane
J. Am. Chem. Soc., 1992, 114, 8807-8809

424
Adam, W.; Sauter, M.
Oxidation of 8-Methoxypsoralen (8-MOP) by Dimethyldioxirane. Evidence for the Formation of a Furocoumarin Epoxide by Methanol Trapping, a Potential Mutagenic Agent
Liebigs Ann. Chem., 1992, 1095-1096

423
Adam, W.; Asencio, G.; Curci, R.; Marco, J. A.; González Nuñez, M.E.; Mello, R.
One-Electron Transfer Chain Decomposition of Trifluoroacetone Diperoxide: The First 1,2,4,5-Tetroxane with Oxygen-Transfer Capability
Tetrahedron Lett., 1992, 33, 5833-5836

422
Adam, W.
Introductory Remarks
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chichester 1992

421
Adam, W.; Heil, M.; Mosandl, T.; Saha-Möller, C.R.
Dioxetanes and a-Peroxy Lactones, Four-Membered-Ring Cyclic Peroxides
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chischester 1992; pp 221-254

420
Adam, W.; Hadjiarapoglou, L.; Curci, R.; Mello, R.
Dioxiranes, 3-Membered-Ring Cyclic Peroxides
In Organic Peroxides; W. Ando, Ed.; John Wiley and Sons: Chichester 1992; pp 195-219

419
Adam, W.; Asensio, G.; Curci, R.; González Nuñez, M.E.; Mello, R.
One-Electron Reduction of Methyl(trifluoromethyl)dioxirane by Iodide Ion. Evidence for an Electron-Transfer Chain Reaction Mediated by the Superoxide Ion
J. Am. Chem. Soc., 1992, 114, 8345-8349

417
Curci, R.; D'Accolti, L.; Fiorentino, M.; Fusco, C.; Adam, W.; González Nuñez, M.E.; Mello, R.
Oxidation of Acetals, an Orthoester, and Ethers by Dioxiranes Through a-CH Insertion
Tetrahedron Lett., 1992, 33, 4225-4228

414
Adam, W.; Heil, M.; Hutterer, R.
Electron versus Hydride-Ion Transfer in the Reduction of b-Halogen-Substituted 1,2-Dioxetanes by 1,4-Dihydronicotinamides
J. Org. Chem., 1992, 57, 4491-4495

413
Abou-Elzahab, M.M.; Adam, W.; Saha-Möller, C.R.
Synthesis of Furocoumarin-Type Potential Intercalative Alkylating and Oxidizing Agents of DNA Through Dimethyldioxirane Epoxidation of Imperatorin and its Derivatives
Liebigs Ann. Chem., 1992, 731-733

412
Schenk, W.A.; Frisch, J.; Adam, W.; Prechtl, F.
Ligand-Centered Oxidations of Organometallic Thiolates Using Dimethyldioxirane
Inorg. Chem., 1992, 31, 3329-3331

410
Adam, W.; Heil, M.
Reaction of 1,2-Dioxetanes with Heteroatom Nucleophiles: Adduct Formation by Nucleophilic Attack at the Peroxide Bond
J. Am. Chem. Soc., 1992, 114, 5591-5598

407
Adam, W.; Azzena, U.; Prechtl, F.; Hindahl, K.; Malisch, W.
Conversion of Ferriosilanes to Ferriosilanols by Selective Oxidation of the SiH Function by Dimethyldioxirane
Chem. Ber., 1992, 125, 1409-1411

403
Adam, W.; Peters, E. M.; Peters, K.; von Schnering, H.G.; Voerckel, V.
Epoxidation of Enamines by Dimethyldioxirane: Formation of 1,4-Dioxanes by Enamine Epoxide Dimerization
Chem. Ber., 1992, 125, 1263-1266

402
Adam, W.; Hadjiarapoglou, L.; Lévai, A.
Dimethyldioxirane Epoxidation of Aurones and Isoflavones
Synthesis, 1992, 435-438

401
Adam, W.; Andler, S.; Heil, M.; Voerckel, V.
a-Alkoxy Ketones from the Nucleophilic Substitution on the Peroxide Bond of 3,3-Disubstituted 1,2-Dioxetanes by Enamines
J. Org. Chem., 1992, 57, 2680-2682

400
Albrecht, S.; Brandl, H.; Schönfels, C.; Adam, W.
Angewandte Biolumineszenz: Luciferasen in der biochemischen Analytik
Chemie in unserer Zeit, 1992, 26, 63-69

399
Albrecht, S.; Brandl, H.; Adam, W.
Biochemische Analytik: Angewandte Chemilumineszenz
Nachr. Chem. Lab. Tech., 1992, 40, 547-554

394
Adam, W.; Hadjiarapoglou, L.; Prechtl, F.; Saha-Möller, C.R.; Sauter, M.; Schuhmann, R.M.
Selective Oxygen Transfer II: Dioxiranes
In Selective Reactions of Metal Activated Molecules; H.Werner; A.G.Griesbeck; W.Adam, G.Bringmann, W.Kiefer, Eds.; Vieweg-Ver 1992; pp 153-156

392
Adam, W.; Bialas, J.; Hadjiarapoglou, L.; Patonay, T.
Direct Epoxidation of [E]-2'-Hydroxychalcones by Dimethyldioxirane
Synthesis, 1992, 49-51

390
Adam, W.; Asensio, G.; Curci, R.; González-Nuñez, M.E.; Mello, R.
Oxygen Atom Insertion into the Benzylic Carbon-Hydrogen Bond of R(-)-2-Phenylbutane by Methyl-(trifluoromethyl)dioxirane: An Efficient and Mild Regio- and Stereoselective Synthesis of S(-)-2-Phenyl-2-butanol
J. Org. Chem., 1992, 57, 953-955

389
Adam, W.; Hadjiarapoglou, L.
a-Oxo Sulfones by Dimethyldioxirane Oxidation of Thiol Esters
Tetrahedron Lett., 1992, 33, 469-470

388
Adam, W.; Schönberger, A.
Dimethyldioxirane Oxidation of Hydroquinones into Quinones and 2,3-Dihydroxycyclohexene-1,4-diones
Tetrahedron Lett., 1992, 33, 53-56

386
Adam, W.; Heil, M.
Novel Transformation of 1,2-Dioxetanes. b-Hydroxy Ethers by Addition of Alkyllithium Reagents
Chem. Ber., 1992, 125, 235-241

385
Adam, W.; Bialas, J.; Hadjiarapoglou, L.; Sauter, M.
Epoxidation of 2,3-Dimethylbenzofurans by Dimethyldioxirane
Chem. Ber., 1992, 125, 231-234

384
Adam, W.; Golsch, D.; Hadjiarapoglou, L.; Patonay, T.
Epoxidation of Flavones by Dimethyldioxirane
J. Org. Chem., 1991, 56, 7292-7297

379
Adam, W.; Hadjiarapoglou, L.; Meffert, A.
Dimethyldioxirane Epoxidation of 6,6-Disubstituted Fulvenes
Tetrahedron Lett., 1991, 32, 6697-6700

376
Adam, W.; Hadjiarapoglou, L.; Mosandl, T.; Saha-Möller, C.R.; Wild, D.
Chemical Studies on the Mutagenesis of Benzofuran Dioxetanes in the Ames Test: Evidence for the Benzofuran Epoxide as Ultimate Mutagen
J. Am. Chem. Soc., 1991, 113, 8005-8011

375
Adam, W.; Bialas, J.; Hadjiarapoglou, L.
A Convenient Preparation of Acetone Solutions of Dimethyldioxirane
Chem. Ber., 1991, 124, 2377

374
Adam, W.; Prechtl, F.
Highly Efficient Hydroxylation of Carbonyl Compounds with Dimethyldioxirane
Chem. Ber., 1991, 124, 2369-2372

373
Adam, W.; Hadjiarapoglou, L.; Jäger, V.; Klicic, J.; Seidel, B.; Wang, X.
Epoxidation of Enol Silyl Ethers, Phosphates, Esters and Lactones by Dimethyldioxirane
Chem. Ber., 1991, 124, 2361-2368

372
Adam, W.; Curci, R.; González Nuñez, M.E.; Mello, R.
Thermally and Photochemically Initiated Radical Chain Decomposition of Ketone-Free Methyl(trifluoromethyl)dioxirane
J. Am. Chem. Soc., 1991, 113, 7654-7658

371
Adam, W.; Andler, S.; Heil, M.
Novel Reactions of Disubstituted 1,2-Dioxetanes with Olefins as p-Nucleophiles: Cycloaddition Products from Intermediary 1,6-Dipoles
Angew. Chem., 1991, 103, 1395-1396; Angew. Chem., Int. Ed. Engl., 1991, 30, 1365-1366

369
Adam, W.; Albert, R.; Dachs Grau, N.; Hasemann, L.; Nestler, B.; Peters, E.-M.; Peters, K.; Prechtl, F.; von Schnering, H.G.
Synthesis of alpha-Methylene-beta-lactones, Novel Heterocycles
J. Org. Chem., 1991, 56, 5778-5781

364
Adam, W.; Bottle, S.E.; Mello, R.
Photolysis of Dioxiranes in the Presence of a Nitroxide Radical Scavenger: The Intermediacy of Radical Anion and Diyl Species in the Production and Trapping of Methyl and Trifluoromethyl Radicals
Chem. Commun., 1991, 771-773

360
Abou-Elzahab, M.; Adam, W.; Saha-Möller, C.R.
Epoxidation of Allylic Hydroperoxides by Dimethyldioxirane and Peroxy Acids
Liebigs Ann. Chem., 1991, 445-450

356
Adam, W.; Mosandl, T.; Dall'Acqua, F.; Vedaldi, D.
Photobinding of Psoralen to DNA via Triplet Ketones Generated Thermally from Dioxetanes
J. Photochem. Photobiol. B: Biol., 1991, 8, 431-437

353
Adam, W.; Hadjiarapoglou, L.; Wang, X.
Dimethyldioxirane Epoxidation of Alkenes with Two Electron-Donating Substituents
Tetrahedron Lett., 1991, 32, 1295-1298

352
Adam, W.; Golsch, D.; Hadjiarapoglou, L.; Patonay, T.
Dimethyldioxirane Epoxidation of Flavones
Tetrahedron Lett., 1991, 32, 1041-1044

350
Adam, W.; Balci, M.; Ceylan, Z.; Hinz, R.F.
Reactions of Benzocycloheptatrienes with Dienophiles
Chem. Ber., 1991, 124, 383-386

349
Adam, W.; Hadjiarapoglou, L.; Smerz, A.
Dioxirane Epoxidation of alpha,beta-Unsaturated Ketones
Chem. Ber., 1991, 124, 227-232

348
Adam, W.; Albrecht, O.; Feineis, E.; Reuter, I.; Saha-Möller, C.R.; Seufert-Baumbach, P.; Wild, D.
Benzofuran Dioxetanes, a New Class of Mutagenic Agents: Synthesis by Photooxygenation of Benzofuran Derivatives
Liebigs Ann. Chem., 1991, 33-40

345
Adam, W.; Hadjiarapoglou, L.; Klicic, J.
Dimethyldioxirane Epoxidation of Enol Phosphates
Tetrahedron Lett., 1990, 31, 6517-6520

343
Adam, W.; Beinhauer, A.; Mosandl, T.; Saha-Möller, C.R.; Vargas, F.; Epe, B.; Müller. E.; Schiffmann, D.; Wild, D.
Photobiological Studies with Dioxetanes in Isolated DNA, Bacteria and Mammalian Cells
Environmental Health Perspectives, 1990, 88, 89-97

342
Adam, W.; Hadjiarapoglou, L.
Epoxidation of ß-Keto Enol Ethers by Dimethyldioxirane
Chem. Ber., 1990, 123, 2077-2079

341
Adam, W.
Chemiluminescence and Bioluminescence.
In Ullmann's Encyclopedia of Industrial Chemistry, Luminescent Materials; VCH: Weinheim, Germany 1990; Vol.A 15, Chap 2, pp 548-557

340
Adam, W.; Hadjiarapoglou, L.; Siegmeier, R.
Verfahren zur Herstellung von Glycidylethern durch Epoxidation der Allylether
Deutsche Patentanmeldung, Patentnummer P 40 23 741.9, 26.07.1990. 1990

338
Adam, W.; Beinhauer, A.; Hauer, H.; Saha-Möller, C.R.
Activation Parameters and Excitation Yields of 1,2-Dioxetanes of Photogenotoxic Interest
J. Prakt. Chem., 1990, 332, 161-168

337
Adam, W.; Mello, R.; Curci, R.
Oxygen-Atom Insertion into Silicon-Hydrogen Bonds by Dioxiranes: A Stereoselective and Direct Conversion into Silanols
Angew. Chem., 1990, 102, 916-917; Angew. Chem., Int. Ed. Engl., 1990, 29, 890-891

329
Camporeale, M.; Fiorani, T.; Troisi, L.; Adam, W.; Curci, R.; Edwards, J.O.
On the Mechanism of the Bayer-Villiger Oxidation of Ketones by Bis(trimethylsilyl) Peroxomonosulfate. Intermediacy of Dioxiranes
J. Org. Chem., 1990, 55, 93-98

328
Adam, W.; Hadjiarapoglou, L.; Nestler, B.
Dimethyldioxirane Epoxidation of a,b-Unsaturated Ketones, Acids and Esters
Tetrahedron Lett., 1990, 31, 331-334

327
Adam, W.; Hadjiarapoglou, L.; Wang, X.
Epoxidation of Silyl Enol Ethers, Phthalides, and Enol Esters by Dimethyldioxirane
Tetrahedron Lett., 1989, 30, 6497-6500

326
Adam, W.; Hückmann, S.; Vargas, F.
Direct Observation of Electron Transfer Between Phenothiazines and 1,2-Dioxetanes
Tetrahedron Lett., 1989, 30, 6315-6318

324
Adam, W.; Hadjiarapoglou, L.; Jäger, V.; Seidel, B.
Epoxidation of g-Methylene-b-Butyrolactones by Dimethyldioxirane
Tetrahedron Lett., 1989, 30, 4223-4226

321
Adam, W.; Curci, R.; Edwards, J.O.
Dioxiranes: A New Class of Powerful Oxidants
Acc. Chem. Res., 1989, 22, 205-211

314
Adam, W.; Hasemann, L.; Vargas, F.; Epe, B.; Schiffmann, D.; Wild, D.
Single-Electron Transfer (SET) Leading to Radical Species in the Redox Reactions of Cyclic Peroxides with Biological Substrates
In Organic Free Radicals, Fischer, H., Heimgartner, H., Eds.; Springer Verlag: Berlin 1988; pp 219-220

310
Adam, W.; Hasemann, L.; Prechtl, F.
alpha-Methylene-beta-Lactone: A Novel Heterocyclic Ring System via Deoxygenation of alpha-Methylene-beta-peroxylactones with Triphenylphosphine
Angew. Chem., 1988, 100, 1594-1595; Angew. Chem., Int. Ed. Engl., 1988, 27, 1536-1537

309
Adam, W.; Kliem, U.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Preparative Vis-Laser Photochemistry: Qinghaosu-Type 1,2,4-Trioxanes by Molecular-Oxygen Trapping of Paterno-Büchi Triplet 1,4-Diradicals Derived from the Bicyclic Enol Lactones D^1,6- and D^1,10-2-Oxabicyclo[4.4.0]decen-2-one and p-Benzoquinone
J. Prakt. Chem., 1988, 330, 391-405

308
Adam, W.; Kliem, U.; Mosandl, T.; Peters, E.-M.; Peters K.; von Schnering, H.G.
Preparative Visible-Laser Photochemistry: Qinghaosu-Type 1,2,4-Trioxanes by Molecular Trapping of Paterno-Büchi Triplet 1,4-Diradicals Derived from 3,4- Dihydro-4,4-dimethyl-2H-pyran-2-one and Quinones
J. Org. Chem., 1988, 53, 4986-4992

300
Adam, W.; Epe, B.; Schiffmann, D.; Vargas, F.; Wild, D.
Facile Reduction of 1,2-Dioxetanes by Thiols such as Glutathione as Potential Protective Measure against Photochemical Damage of Cellular DNA
Angew. Chem., 1988, 100, 443-445; Angew. Chem., Int. Ed. Engl., 1988, 27, 429-431

299
Nassi, L.; Schiffmann, D.; Favre, A.; Adam, W.; Fuchs, R.
Induction of the SOS Function sfiA in E.coli by Systems which Generate Triplet Ketones
Mutat. Res., 1988, 198, 53-60

286
Adam, W.; Fuchs, R.; Kirchgäßner, U.
Functionalized 1,2-Dioxetanes as Potential Photogenotoxic Agents: 1,2-Dioxetanes with Electrophilic Chemical Handles for the Functionalization with Protic Nucleophiles
Chem. Ber., 1987, 120, 1565-1571

285
Adam, W.; Bhushan, V.; Fuchs, R.; Kirchgäßner, U.
Functionalized 1,2-Dioxetanes as Potential Phototherapeutic Agents: The Synthesis of Carboxylate, Carbonate, Carbamate and Ether Derivatives of 3-(Hydroxymethyl)-3,4,4-trimethyl-1,2-dioxetane
J. Org. Chem., 1987, 52, 3059-3062

284
Nassi, L.; Epe, B.; Schiffmann, D.; Adam, W.; Beinhauer, A.; Griesbeck, A.G.
Induction of Morphological Transformation and Micronuclei in Syrian Hamster Embryo Fibroblasts by 1,2-Dioxetanes. Correlation with Single Strand Breaks in HL-60 Cells
Carcinogenesis, 1987, 8, 947-953

281
Adam, W.; Beinhauer, A.; Fischer, R.; Hauer, H.
Psoralen-Substituted Dioxetanes as Intercalators for Photogenotoxic Studies
Angew. Chem., 1987, 99, 817 - 818; Angew. Chem., Int. Ed. Engl., 1987, 26, 796-797

271
Adam, W.; Beinhauer, A.; Epe, B.; Fuchs, R.; Griesbeck, A.; Hauer, H.; Mützel, P.; Nassi, L.; Schiffmann, D.; Wild, D.
Genotoxic Effects of 1,2-Dioxetanes
In Friedberg, T.; Oesch, F. ,Eds.; Primary Changes and Control Factors in Carcinogenesis, Deutscher Fachschriften-Verlag: Wie 1986

268
Adam, W.; Griesbeck, A.
Regioselective Synthesis of 3-Hydroperoxy-2-methylenebutyric Acid Functionalities via Photooxygenation of Tiglic Acid Derivatives
Synthesis, 1986, 1050-1052

267
Adam, W.; Griesbeck, A.; Klärner, F.-G.; Schöer, D.
[p²+p²]-Cycloaddition of 4-Phenyl-4H-1,2,4-triazole-3,5-dione and Singlet Oxygen with Homofuran
Angew. Chem., 1986, 98, 1006-1007; Angew. Chem., Int. Ed. Engl., 1986, 25, 989-990

260
Adam, W.; Baader, W.J.; Cilento, G.
Enols of Aldehydes in the Peroxidase-Oxidase-Promoted Generation of Excited Triplet Species
Biochim. Biophys. Acta, 1986, 881, 330-336

259
Adam, W.; Kliem, U.; Lucchini, V.
Preparative UV-Vis Laser Photochemistry: Molecular Oxygen Trapping of the Paterno-Büchi Triplet Diradicals Derived from 1,4-Dioxene
Tetrahedron Lett., 1986, 27, 2953-2956

257
Adam, W.; Bhushan, V.; Dirnberger, T.; Fuchs, R.
Functionalized 1,2-Dioxetanes as Potential Chemotherpeutic Agents: The Synthesis of Dioxetane-Substituted Carbamates
Synthesis, 1986, 330-332

255
Adam, W.; Hannemann, K.; Wilson, R.M.
UV Laser Photochemistry: Triplet Biradical Trapping Efficiencies and Lifetimes
J. Am. Chem. Soc., 1986, 108, 929-935

251
Adam, W.; Griesbeck, A.G.
Synthesis of the First a-Methylene-ß-peroxylactone: Regioselective Ene Reaction of Singlet Oxygen with a,ß-Unsaturated Carboxylic Acids
Angew. Chem., 1985, 97, 1071-1072; Angew. Chem., Int. Ed. Engl., 1985, 24, 1070-1071

246
Adam, W.; Platsch, H.; Schmidt, E.
Synthesis, Thermal Stability, and Chemiluminescence Properties of Bisdioxetanes Derived from p-Dioxins
Chem. Ber., 1985, 118, 4385-4403

245
Adam, W.; Gretzke, N.; Hasemann, L.; Klug, G.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Will, B.
Cycloaddition of Singlet Oxygen and 4-Phenyl-4H-1,2,4-triazole-3,5-dione to 7-Substituted 1,3,5-Cyclooctatrienes
Chem. Ber., 1985, 118, 3357-3379

238
Adam, W.; Klug, G.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis of Endoperoxides Derived from Cyclooctatetraenes via Singlet Oxygenation
Tetrahedron, 1985, 41, 2045-2056

234
Adam, W.; Yany, F.
1,2-Dioxetanes and a-Peroxylactones
In Small Ring Heterocycles, Hassner, A. Ed.; John Wiley and Sons: New York, 1985; Vol. 42, Part 3, Chap 4, pp 351-429

233
Adam, W.; Berkessel, A.; Krimm, S.
Photochemistry of Bis(2-methyl-1-propenyl) Ether and 2,2,4,4-Tetramethyl-6-oxabicyclo[3.1.0]hexan-3-one: On the Search for the Oxydi-p-methane Rearrangement
Tetrahedron Lett., 1985, 26, 619-622

232
Adam, W.; Baader, W.J.
Effects of Methylation on the Thermal Stability and Chemiluminescence Properties of 1,2-Dioxetanes
J. Am. Chem. Soc., 1985, 107, 410-416

228
Adam, W.; Baader, W.J.; Babatsikos, C.; Schmidt, E.
Four-Membered-Ring Peroxide Heterocycles: Photochemistry through the Backdoor
Bull. Soc. Chim. Belg., 1984, 93, 605-617

227
Adam, W.; Haas, W.; Sieker, G.
Thianthrene-5-Oxide as Mechanistic Probe in Oxygen-Transfer Reactions: The Case of Carbonyl Oxides versus Dioxiranes
J. Am. Chem. Soc., 1984, 106, 5020-5022

225
Adam, W.; Gretzke, N.; Klug, G.
Thermolysis of 7,8-Dioxabicyclo[4.2.2]deca-2,4,9-trienes. An Unusual Decomposition Mode of Endoperoxides
J. Am. Chem. Soc., 1984, 106, 4300-4301

223
Adam, W.; Peters, E.-M.; Peters, K.; Rebollo, H.; Rosenthal, R.J.; von Schnering, H.G.
Cycloaddition of Singlet Oxygen and 4-Methyl-4H-1,2,4-triazole-3,5-dione to 7-Adamantylidene-1,3,5-cycloheptatriene and Derivatives
Chem. Ber., 1984, 117, 2393-2408

220
Adam, W.; Dürr, H.; Pauly, K.-H.; Peters, E.-M.; Peters, K.; Rebollo, H.; von Schnering, H.G.
Singlet Oxygenation and Triazolinedione Addition to Spirofluorene-1,3,5-cycloheptatriene
J. Org. Chem., 1984, 49, 1333-1338

219
Adam, W.; Babatsikos, C.; Cilento, G.
Functionalized 1,2-Dioxetanes as Potentially Useful Biological and Chemotherapeutic Agents
Z. Naturforsch., 1984, 39b, 679-682

218
Adam, W.; Rebollo, H.
Substituent, Temperature and Solvent Effects in the Singlet Oxygenation of 7-Alkyl- and 7-Aryl-substituted 1,3,5-Cycloheptatrienes
Israel. J. Chem., 1984, 23, 399-404

216
Adam, W.; Narita, N.; Nishizawa, Y.
On the Mechanism of the Triphenylphosphine-Azodicarboxylate (Mitsunobu Reaction) Esterification
J. Am. Chem. Soc., 1984, 106, 1843-1845

215
Adam, W.; Baader, W.J.
1,2-Dioxetane: Synthesis, Characterization, Stability and Chemiluminescence
Angew. Chem., 1984, 96, 156; Angew. Chem., Int. Ed. Engl., 1984, 23, 166-167

205
Adam, W.; Schmidt, E.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Crystal Structure of 2,4,5,7,9,10-Hexaoxa-1,3,6,8-tetraphenyltricyclo(6.2.0.0.0^3,6)decane: An Authentic Bisdioxetane
Angew. Chem., 1983, 95, 566-567; Angew. Chem., Int. Ed. Engl., 1983, 22, 546-547

202
Adam, W.; Adamsky, F.; Klärner, F.-G.; Peters, E.-M.; Peters, K.; Rebollo, H.; Rüngeler, W.; von Schnering, H.G.
Stereochemistry and Product Distribution in the Singlet Oxygen Cycloaddition with 7,7-Disubstituted 1,3,5-Cycloheptatrienes
Chem. Ber., 1983, 116, 1848-1859

199
Adam, W.; Arias Encarnacion, L.A.; Zinner, K.
Thermal Stability of Spiro(adamantane-1,2-dioxetanes)
Chem. Ber., 1983, 116, 839-846

192
Adam, W.; Rebollo, H.
Singlet Oxygenation of 7-Aryl- and 7-Alkyl-1,3,5-cycloheptatrienes: Substituent Effects on the Product Distribution of Tropilidene- and Norcaradiene-Derived Endoperoxides
Tetrahedron Lett., 1982, 23, 4907-4910

190
Adam, W.; Zinner, K.
Determination of Activation Parameters and the Thermal Stability of 1,2-Dioxetanes
In Chemical and Biological Generation of Electronic Excited States, Adam, W. and Cilento, G. Eds.; Academic Press: New York 1982; Chap. 5, pp 153-189

188
Adam, W.; Cilento, G.
Chemical and Biological Generation of Excited States
Adam, W.; Cilento, G., Eds.; Academic Press: New York 1982

187
Adam, W.; Klug, G.
The Synthesis of the Endoperoxide of Cyclooctatetraene via Photosensitized Singlet Oxygenation
Tetrahedron Lett., 1982, 23, 3155-3158

186
Adam, W.; Arias Encarnacion, L.A.
The Synthesis of Spiro(adamanantane-1,2-dioxetanes)
Chem. Ber., 1982, 115, 2592-2605

185
Adam, W., Arias, L.A.; Zahn, A.; Zinner, K.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
X-Ray Structural Parameters and the Thermal Stability of 1,2-Dioxetanes
Tetrahedron Lett., 1982, 23, 3251-3254

184
Adam, W.; Klug, G.; Scheutzow, D.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Cycloaddition of Singlet Oxygen and 4-Methyl-1,2,4-triazoline-3,5-dione (MTAD) to Methoxycyclooctatetraene (MCOT)
Tetrahedron Lett., 1982, 23, 2837-2840

183
Adam, W.; Arias, L.A.; Scheutzow, D.
Spiroadamantyl Stabilization of Sulfur-Substituted 1,2-Dioxetanes
Tetrahedron Lett., 1982, 23, 2835-2836

178
Adam, W.; Cueto, O.; De Lucchi, O.
[4+2]-Cycloaddition of Singlet Oxygen and Phenyltriazolinedione with Bicyclo[6.1.0]nona-2,4,6-triene and Derivatives
Chem. Ber., 1982, 115, 1170-1177

177
Adam, W.; Rebollo, H.; Dürr, H.; Pauly, K.-H.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Cycloaddition of Singlet Oxygen and Triazolinedione (TAD) with Spirocyclopentadienyl-1,3,5-Cycloheptatrienes: Tropilidene versus Norcaradiene Reactivity
Tetrahedron Lett., 1982, 23, 923-926

173
Adam, W.; Cueto, O.
3,3-Dimethyl-4(2-methyl-1-propenyl)-1,2-Dioxetane: Its Thermal Stability and Chemiluminescent Properties
Z. Naturforsch., 1981, 36b, 1653-1654

167
Adam, W.; Zinner, K.; Krebs, A.; Schmalstieg, H.
Electron-Exchange Chemiluminescence from a Sterically Stabilized Cyclobutadiene-1,2-dioxetane
Tetrahedron Lett., 1981, 22, 4567-4570

166
Adam, W.; Cueto, O.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Synthesis of the Endoperoxide anti-7,8-Dioxatricyclo[4.2.2.0^2,5]deca-3,9-diene via Singlet Oxygenation of the Bicyclic Valence Tautomer of Cyclooctatetraene and its Transformations
J. Am. Chem. Soc., 1981, 103, 5822-5828

165
Adam, W.; Rodriguez, A.
On the Question of Carbonyl Oxide Intermediates in the Oxygen Transfer by Furan Endoperoxides and Bicyclic Ozonides: Intramolecular Trapping Experiments
Tetrahedron Lett., 1981, 22, 3509-3512

164
Adam, W.; Rodriguez, A.
Intramolecular Silyl Migration in the Singlet Oxygenation of 2-Methyl-5-trimethylsilylfuran
Tetrahedron Lett., 1981, 22, 3505-3508

162
Adam, W.; Bloodworth, A.J.
Chemistry of Saturated Bicyclic Peroxides (The Prostaglandin Connection)
Top. Curr. Chem., 1981, 97, 121-158

160
Adam, W.; Rebollo, H.
Singlet Oxygenation of Cycloheptatriene: Isolation and Characterization of 1,2-Dioxetane
Tetrahedron Lett., 1981, 3049-3052

158
Adam, W.; Cueto, O.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Triepoxides of Bicyclo[4.2.0]octa-2,4,7-triene
Angew. Chem., 1981, 93, 618-619; Angew. Chem., Int. Ed. Engl., 1981, 20, 580-581

155
Adam, W.; Curci, R.
Hyperenergetic Molecules: Dioxiranes and 1,2-Dioxetanes
Chimia e Industria, 1981, 63, 20-28

153
Adam, W.; Cadiz, C.; Mazenod, F.P.
Vacuum Flash Pyrolysis (VFP) of Malonyl Peroxides: Decarboxylation versus Decarbonylation of the Intermediary a-Lactones
Tetrahedron Lett., 1981, 22, 1203-1206

151
Adam, W.; Cueto, O.; De Lucchi, O.
Oxygen Functionalization in Cyclooctatetraene via Singlet Oxygenation: Synthesis and Transformation of anti-7,8-Dioxytricyclo[4.2.2.0^2,5]deca-3,9-diene, the Endoperoxide of the Bicyclic Valence Tautomer of Cyclooctatetraene
J. Org. Chem., 1980, 45, 5220-5221

150
Adam, W.
Thermal Generation of Electronic Excitation with Hyperenergetic Molecules
Pure & Appl. Chem., 1980, 52, 2591-2608

148
Adam, W.; Balci, M.; Pietrzak, B.; Rebollo, H.
Oxygen Functionalization of Cycloheptatriene via Sensitized Photooxygenation
Synthesis, 1980, 10, 820-823

145
Adam, W.; Cilento, G.; Zinner, K.
External Heavy Atom Effect in the Energy Transfer from Chemi-Excited Triplet Acetone to Anthracene
Photochem. Photobiol., 1980, 32, 87-90

143
Adam, W.; Cadilla, C.; Cueto, O.; Rodriguez, L.O.
Fluorescer-Enhanced Chemiluminescence of a Cyclic Peroxalate via Electron Exchange
J. Am. Chem. Soc., 1980, 102, 4802-4805

142
Gleiter, R.; Schang, P.; Adam, W.; Eggelte, H.J.; Erden, I.; Bloodworth, A.J.
Photoelectron Spectra of Bicyclic Peroxides
J. Electron. Spec. Rel. Phenom., 1980, 19, 223-230

140
Adam, W.
Thermische Erzeugung elektronisch angeregter Moleküle
Chemie in unserer Zeit, 1980, 14, 44-55

135
Adam, W.; Cueto, O.; Guedes, L.N.
On the Mechanism of ß-Peroxylactone Decarboxylation
J. Am. Chem. Soc., 1980, 102, 2106-2107

134
Adam, W.; Balci, M.
The Stereoselective Synthesis of the Three Trioxides of 1,3,5-Cycloheptatriene via the Endoperoxide-Diepoxide Rearrangement
J. Am. Chem. Soc., 1980, 102, 1961-1966

133
Adam, W.; Balci, M.
Stereoselective Synthesis of Cycloheptatriene Trioxides
Angew. Chem., 1980, 92, 54-55; Angew. Chem., Int. Ed. Engl., 1980, 19, 48-49

131
Adam, W.; Rodriguez, A.
Oxygen-Atom Transfer by Furan Endoperoxides
J. Am. Chem. Soc., 1980, 102, 404-406

129
Adam, W.; Balci, M.; Rivera, J.
A Convenient Synthesis of Homobenzoquinones
Synthesis, 1979, 807-808

128
Adam, W.; Balci, M.
Photooxygenation of 1,3,5-Cycloheptatriene: Transformation of Endoperoxides
J. Am. Chem. Soc., 1979, 101, 7542-7547

127
Adam, W.; Balci, M.
Photooxygenation of 1,3,5-Cycloheptatrine: Isolation and Characterization of Endoperoxides
J. Am. Chem. Soc., 1979, 101, 7537-7541

126
Srinivasan, R.; Brown, K.H.; Ors, J.A.; White, L.S.; Adam, W.
Organic Photochemistry with 6.7 eV Photons: Ascaridole
J. Am. Chem. Soc., 1979, 101, 7424-7425

125
Adam, W.
Oxygen Diradicals Derived from Cyclic Peroxides
Acc. Chem. Res., 1979, 11, 390-396

122
Adam, W.; Bakker, B.H.
Singlet Oxygenation of cis,cis-1,5-Cyclooctadiene: A Convenient Synthetic Entry into 5,8-Difunctionalized Oxygen Derivatives of 1,3-Cyclooctadiene
Tetrahedron Lett., 1979, 4171-4174

121
Adam, W.; Cueto, O.
Fluorescencer-Enhanced Chemiluminescence of a-Peroxylactones via Electron Exchange
J. Am. Chem. Soc., 1979, 101, 6511-6515

120
Adam, W.; Balci, M.; Cueto, O.; Pietrzak, B.
8,9-Dioxa-6-methylbicyclo[5.2.0]nona-2,4-diene: A 1,2-Dioxetane formed by [2+2]-Cycloaddition of Singlet Oxygen to 7-Methyl-1,3,5-Cycloheptatriene
Tetrahedron Lett., 1979, 4137-4140

119
Adam, W.; Balci, M.; Pietrzak, B.
Reaction of 7-Substituted Cycloheptatrienes with Singlet Oxygen and 4-Phenyl-1,2,4-triazoline-3,5-dione
J. Am. Chem. Soc., 1979, 101, 6285-6291

118
Adam, W.; Erden, I.
a-Pyrone Endoperoxides. Synthesis, Thermal Decomposition, and Chemiluminescence
J. Am. Chem. Soc., 1979, 101, 5692-5696

117
Adam, W.; Cilento, G., Eds.
Chemi- and Bioenergized Processes
Photochem. Photobiol., 1979, 30, 1

116
Adam, W.; Sakanishi, K.
Lack of Heavy Atom Effect on the Activation Parameters of Bromine Substituted 1,2-Dioxetanes
Photochem. Photobiol., 1979, 30, 45-48

115
Adam, W.; Erden, I.
Singlet Oxygenation of Cycloocta-1,3,5-triene: Formation of (4.2.2)- and (2.2.2)-Cycloadducts
Tetrahedron Lett., 1979, 2781-2784

113
Adam, W.; Cheng, C.-C.; Cueto, O.; Erden, I.; Zinner, K.
A Stable Bisdioxetane
J. Am. Chem. Soc., 1979, 101, 4735-4736

111
Adam, W.; Eggelte, H.J.; Rodriguez, A.
A Convenient Method for the Preparation of Bicyclic Ozonides Possessing the 2,3,7-Trioxabicyclo(2.2.1)heptane Structure
Synthesis, 1979, 383-384

110
Adam, W.; Takayama, K.
1,4-Dimethyl-2,3,7-trioxabicyclo(2.2.1)hept-5-ene
J. Org. Chem., 1979, 44, 1727-1728

109
Adam, W.; Erden, I.
Dienic Reactivity of 3,5-Cycloheptadienone: Reaction with Singlet Oxygen
Tetrahedron Lett., 1979, 1975-1978

107
Adam, W.; Balci, M.
endo- and exo-7-Cyanonorcaradiene Endoperoxides: Synthesis, Characterization, and Transformations
J. Org. Chem., 1979, 44, 1189-1190

105
Adam, W.; Erden, I.; Cox, O.
Dienic Reactivity of 3,5-Cycloheptadien-1-one
J. Org. Chem., 1979, 44, 861-864

104
Adam, W.; Cheng, C.-C.; Cueto, O.; Sakanishi, K.; Zinner, K.
Chemical Titration of Thermally Generated Triplets
J. Am. Chem. Soc., 1979, 101, 1324-1325

102
Srinivasan, R.; Brown, K. H.; Ors, J.A.; Adam, W.
Organic Photochemistry with 6.7 eV Photons: Ascaridole
In Proceedings of 7th IUPAC Symposium on Photochemistry; Catholic University, Louvain, Belgium 1978; pp 313-316

101
Adam, W.; Bloodworth, A.J.
Organic Peroxides, Biological and Synthetic Aspects
Ann. Reports (B), 1978, 342-369

100
Adam, W.
Singlet Molecular Oxygen and its Role in Organic Peroxide Chemistry
W.M. Weigert, Ed., Hüthig Verlag: Heidelberg, 1978

99
Adam, W.; Balci, M.
Norcaradiene and Cycloheptatriene Endoperoxides
Angew. Chem., 1978, 90, 1014-1015; Angew. Chem., Int. Ed. Engl., 1978, 17, 954-955

94
Adam, W.; Eggelte, H.J.
2,3-Dioxa-7-thiabicyclo[2.2.1]heptane: A New Heterocyclic System Possessing the Thiaozonide Structure
Angew. Chem., 1978, 90, 811; Angew. Chem., Int. Ed. Engl., 1978, 17, 765

93
Adam, W.; Ruchtäschel, R.
Photolysis and Thermolysis of Di-n-Butylmalonyl Peroxide. Evidence for a-Lactone Intermediates
J. Org. Chem., 1978, 43, 3886-3890

92
Adam, W.; Erden, I.
Synthesis and Characterization of 7-Spirocyclopropyl-2,3-dioxabicyclo(2.2.1)hept-2-ene
J. Org. Chem., 1978, 43, 2737-2738

91
Campos, V.; Robeson, J.; Duran, N.; Adam, W.
New Peroxides and their Antimicrobial Acitivity
Rev. Brasil. Pesquisa Med. Bio., 1978, 11, 131-133

90
Adam, W.; Sakanishi, K.
Mercuric Trifluoroacetate-Catalyzed Decomposition of an Allylic Hydroperoxide via a Mercury-Substituted 1,2-Dioxetane
J. Am. Chem. Soc., 1978, 100, 3935-3936

88
Adam, W.; Erden, I.
Trapping of Unstable a-Pyrone/Singlet Oxygen Adducts by Reduction with Diazene
Angew. Chem., 1978, 90, 223; Angew. Chem., Int. Ed. Engl., 1978, 17, 211-212

87
Adam, W.; Erden, I.
Trapping of Unstable Fulvene/Singlet Oxygen Adducts by Reduction with Diazene
Angew. Chem., 1978, 90, 223; Angew. Chem., Int. Ed. Engl., 1978, 17, 210-211

86
Adam, W.; Bloodworth, A.J.; Eggelte, H.J.; Loveitt, M.E.
Regioselective Synthesis of Isomeric Bicyclic Peroxides
Angew. Chem., 1978, 90, 216; Angew. Chem., Int. Ed. Engl., 1978, 17, 209-210

85
Adam, W.; Cueto, O.; Guedes, L.N.; Rodriguez, L.O.
Solvent Effects and Secondary Isotope Effects for Probing Diradical Character in the Thermal Decarboxylation of ß-Peroxy Lactones
J. Org. Chem., 1978, 43, 1466-1467

83
Adam, W.; Birke, A.; Cadiz, C.; Diaz, S.; Rodriguez, A.
Prostanoid Endoperoxide Model Compounds: Preparation of 1,2-Dioxolanes from Cyclopropanes
J. Org. Chem., 1978, 43, 1154-1158

80
Adam, W.; Eggelte, H.J.
Prostanoid Endoperoxide Model Compounds: 2,3-Dioxabicyclo[2.2.1]heptane via Selective Diimide Reduction
J. Org. Chem., 1977, 42, 3987-3988

79
Adam, W.; Eggelte, H.J.
2,3-Dioxabicyclo[2.2.2]octane by Selective Reduction of Double Bonds with Azodicarboxylate
Angew. Chem., 1977, 89, 726; Angew. Chem., Int. Ed. Engl., 1977, 16, 713-714

78
Turro, N.J.; Ito, Y.; Chow, M.-F.; Adam, W.; Rodriguez, O.; Yany, F.
Synthesis of a-Peroxylactones by Direct Oxygenation of Ketenes. Evidence for an Intermediate
J. Am. Chem. Soc., 1977, 99, 5836-5838

76
Adam, W.; Alzerreca, A.; Liu, J.-C.; Yany, F.
a-Peroxylactones via Dehydrative Cyclization of a-Hydroperoxy Acids
J. Am. Chem. Soc., 1977, 99, 5768-5773

74
Adam, W.; Sanabia, J.
Prostanoid Endoperoxide Model Compounds: 1,6-Diradicals in the Thermolysis and Photolysis of 1,2-Dioxanes and Cyclic Peroxalates
J. Am. Chem. Soc., 1977, 99, 2735-2739

73
Adam, W.; Duran, N.
Prostanoid Endoperoxide Model Compounds: 1-Oxatrimethylene Diradicals in the Thermolysis and Photolysis of 1,2-Dioxolanes
J. Am. Chem. Soc., 1977, 99, 2729-2734

72
Adam, W.
The Chemistry of 1,2-Dioxetanes
Adv. Het. Chem., 1977, 21, 437-481

71
Adam, W.; Tsai,S.-C.
Electron Impact Behaviour of ß-Peroxylactones
J. Org. Chem., 1977, 42, 537-541

66
Adam, W.; Liu, J.-C.; Strating, J.; Wieringa, J. H.; Wynberg, H.
Bisadamantylidene-1,2-dioxetane
Org. Photochem. Synth., 1976, 2, 10-12

65
Adam, W.; Liu, J.-C.; Rodriguez, O.
Bis(Trifluoromethyl)acetolactone
Org. Photochem. Synth., 1976, 2, 13-16

64
Adam, W.
The Synthesis of Unusual Organic Molecules Using Cyclic Peroxide
New Synthetic Methods, 1975, 1, 109-132

59
Adam, W.; Arce, J.
Thermolysis of the Cyclic Peroxide 4-Ethylidene-3,3,5,5-tetramethyl-1,2-dioxolane. Generation and Trapping of a 1,5-Diradical
J. Am. Chem. Soc., 1975, 97, 926-928

58
Adam, W.; Szendrey, L.M.
Intervention of the 1,4-Diradical 1-Oxatetramethylene in the Thermodecarboxylation of g-Peroxylactones
J. Am. Chem. Soc., 1974, 96, 7135-7137

57
Adam, W.; Simpson, G.A.; Yany, F.
Mechanism of Direct and Rubrene Enhanced Chemiluminescence during a-Peroxylactone Decarboxylation
J. Phys. Chem., 1974, 78, 2559-2569

55
Adam, W.
The Synthesis of Unusual Organic Molecules Using Cyclic Peroxides
Angew. Chem., 1974, 8, 683-691; Angew. Chem., Int. Ed. Engl., 1974, 13, 619-628

54
Batich, C.; Adam, W.
The Photoelectron Spectra of Alkyl Peroxides
Tetrahedron Lett., 1974, 1467-1470

51
Adam, W.; Sanabia, J.
Concerted Fragmentation of a 1,6-Diradical on Thermolysis of 1,2-Dioxanes
Angew. Chem., 1973, 85, 914-915; Angew. Chem., Int. Ed. Engl., 1973, 12, 843-845

48
Adam, W.; Liu, J.-C.; Rodriguez, O.
Bis(trifluoromethyl)acetolactone, a Stable a-Lactone
J. Org. Chem., 1973, 38, 2269-2270

47
Adam, W.; Duran, N.
1,3-Diradicals via Thermolysis of 1,2-Dioxolanes
J. Org. Chem., 1973, 38, 1434-1436

46
Adam, W.; Rucktäschel, R.
Cyclic Peroxides XVII. Solvolysis of Di-n-butylmalonoyl Peroxide
J. Org. Chem., 1972, 37, 4128-4133

45
Adam, W.; Rojas, C.I.
Novel Synthesis of ß-Peroxylactones via Perhydrolysis of ß-Lactones
Synthesis, 1972, 616-618

44
Adam, W.; Diehl, J.W.
Triphenylphosphine Deoxygenation of Malonyl Peroxides. A Novel Route to Malonyl Anhydrides
Chem. Commun., 1972, 797-798

43
Adam, W.; Steinmetzer, H.-C.
(1-Adamantyl)-a-peroxylactone: Synthesis, Kinetics and Luminescence
Angew. Chem., 1972, 94, 590-592; Angew. Chem., Int. Ed. Engl., 1972, 11, 540-542

41
Adam, W.; Duran, N.
1,2,4-Trioxepans: Synthesis and Mass Spectral Behaviour
Chem. Commun., 1972, 798-799

40
Adam, W.; Liu, J.-C.
An a-Peroxylactone. Synthesis and Chemiluminescence
J. Am. Chem. Soc., 1972, 94, 2894-2895

36
Adam, W.; Duran, N.
Photolysis of 1,2-Dioxolanes
Tetrahedron Lett., 1972, 1357-1358

35
Adam, W.; Duran, N.
Thermolysis of 1,2-Dioxolanes
Chem. Commun., 1972, 1357-1358

34
Chapman, O.L.; Wojtkowski, P.W.; Adam, W.; Rodriguez, O.; Rucktäschel, R.
Synthesis and Chemistry of a-Lactones
J. Am. Chem. Soc., 1972, 95, 1365-1367

33
Adam, W.; Baeza, J.
Conformational Effects in the Rearrangement of Thermally Generated Oxygen Diradicals
Chem. Commun., 1972, 103-104

32
Adam, W.; Sanabia, J.
Synthesis of a Novel Cyclic Peroxalate, its Thermolysis and Photolysis
Chem. Commun., 1972, 174-175

27
Adam, W.; Wilkerson, C.
Suprafacial Alkyl 1,2-Shift in the Rearrangement of Thermally Generated Oxygen Diradicals
Chem. Commun., 1971, 1569-1570

26
Adam, W.; Szendrey, L.M.
Synthesis of g-Methyl-g-peroxyvalerolactone, its Thermolysis and Photolysis
Chem. Commun., 1971, 1299-1300

25
Adam, W.; Santiago Aponte, G.
Cyclic Peroxides. VI. Oxatrimethylene Diradicals via Photodecarboxylation of ß-Peroxylactones
J. Am. Chem. Soc., 1971, 93, 4300-4301

22
Adam, W.; Rucktäschel, R.
Cyclic Peroxides: V. An a-Lactone Intemediate via Photodecarboxylation of a Monomeric Malonyl Peroxide
J. Am. Chem. Soc., 1971, 93, 557-559

16
Adam, W.; Cheng, Y.M.; Wilkerson, C.; Zaidi, W.A.
Cyclic Peroxyesters. IV. Stereochemistry of the Rearrangement of Thermally Generated Oxygen Diradicals
J. Am. Chem. Soc., 1969, 91, 2111-2112

15
Adam, W.; Cheng, Y.M.
Cyclic Peroxyesters III. Kinetics and Products of the Rearrangement of Thermally Generated Oxygen Diradicals
J. Am. Chem. Soc., 1969, 91, 2109-2110

14
Adam, W.; Ramirez, R.J.; Tsai, S.-C.
Cyclic Peroxyesters II. A Novel Ketene Elimination and Decarboxylation Reaction
J. Am. Chem. Soc., 1969, 91, 1254-1256

8
Greene, F.D.; Adam, W.; Knudsen, G.A., Jr.
A Cyclic Peroxy Ester, ß-Methyl-ß-phenyl-ß-peroxypropiolactone
J. Org. Chem., 1966, 31, 2087-2090

Cycloaddition(186)

995
Adam, W. ; Gogonas, E.P.; Nyxas, I.A.; Hadjiarapoglou, L.P.
[3+2] Cycloaddition of Phenyliodonium Bis(arylsulfonyl)methylides with a,b Enones
Synthesis, 2007, 3211-3218

957
Simon, A,; Tóth, G.; Librera, C.P.; Adam, W.
¹H, ¹³C and ¹⁵N NMR Investigation of a New , Condensed Hexahydro-1,3,5-triazine
Magn. Reson. Chem., 2003, 41, 541-544

948
Adam, W.; Gogonas, E.P.; Hadjiarapoglou, L.
Alkenyl CH Insertion of a b-Disulfone Iodonium Ylide into Flavones
Tetrahedron, 2003, 59, 7929-7934

942
Adam, W.; Gogonas, E.P.; Hadjiarapoglou L.
Bis(sulfonyl)methyl Insertion into Alkenyl versus Phenyl Carbon-Hydrogen Bonds in the Reaction of Bis(sulfonyl)iodonium Ylides with Highly Phenylated Ethylenes
Eur. J. Org. Chem., 2003, 1064-1068

941
Adam, W.; Gogonas, E.P.; Hadjiarapoglou, L.
A Remarkable Cycloaddition of Bis(arylsulfonyl)iodonium Ylide with Norbornene Derivatives for the Direct Synthesis of Functionalized Indanes
Synlett, 2003, 1165-1169

917
Adam, W.; Krebs, O.; Orfanopoulos, M.; Stratakis, M.
Control of Regioselectivity by the Lone Substituent through Steric and Electronic Effects in the Nitrosoarene Ene Reaction of Deuterium-Labeled Trisubstituted Alkenes
J. Org. Chem., 2002, 67, 8395-8399

903
Adam, W.; Bosio, S.G.; Gogonas, E.P.; Hadjiarapoglou; L.P.
A Stereoselective and Regioselective Synthesis of trans,trans-Configured 1, 2, 3-Trisubstituted Indanes: Cycloaddition of Alkenes with Iodonium Ylides of beta-Disulfones
Synthesis, 2002, 14, 2084-2090

892
Adam, W.; Stegmann, V.R.
Unusual Temperature Dependence in the cis/trans-Oxetane Formation Discloses Competitive syn versus anti Attack for the Paterno-Büchi Reaction of Triplet-Excited Ketones with cis and trans Cylooctenes. Conformational Control of Diastereoselectivity in the Cyclization and Cleavage of Preoxet
J. Am. Chem. Soc., 2002, 124, 3600-3607

866
Adam, W.; Stegmann, V.R.
Hydroxy-Group Directivity in the Regioselective and Diastereoselective [2+2] Photocycloaddition (Patern�-B�chi Reaction) of Aromatic Carbonyl Compounds to Chiral and Achiral Allylic Substrates: The Preparation of Oxetanes with up to Three Stereogenic Centers as Synthetic Building Blocks
Synthesis, 2001, 8, 1203-1214

863
Adam, W., Bargon, R.M.
Episulfidation of Strained Cycloalkenes in the Thermolysis of 5-Aryloxy-1,2,3,4-thiatriazoles
Eur. J. Org. Chem., 2001, 1959-1962

861
Adam, W.; Stegmann, V.R.; Weinkötz, S.
Unusual Temperature-Dependent Diastereoselectivity in the [2+2] Photocycloaddition (Paterno-Büchi Reaction) of Benzophenone to cis- and trans-Cyclooctene through Conformational Control
J. Am. Chem. Soc., 2001, 123, 2452-2453

857
Peters, E.-M.; Peters, K; Librera C.P.; Adam, W.
Crystal Structure of (3aa,8aa,13aß)-3a,4,8a,9,13a,14-hexamethyl-1,2,3,3a,6,7,8,8a,1,12,12,13a-tris(cyclopenta[4,5:4',5':4'',5'']pyrazolo)[1,5-a:1',5'-c:1'',5''-e]triazine, C₂₄H₃₆N₆
Z. Kristallogr., 2001, 216, 123-125

833
Adam, W.; Fröhling, B.
An a,a'-Dioxothione in the Reaction of Ninhydrin with Potassium Thiotosylate and its [4+2] Cycloaddition with trans-Cyclooctene
Org. Lett., 2000, 2, 2519-2522

825
Adam, W.; Bottke, N.; Krebs, O.
The New skew and the Established cis and gem Regioselectivities in the Ene Reaction of Trisubstituted Olefins: Comparison of the Singlet Oxygen, Triazolinedione, and Nitrosoarene Enophiles
J. Am. Chem. Soc., 2000, 122, 6791-6792

813
Adam, W.; Pastor, A.; Wirth, T.
Direct Amination of Olefins through Sequential Triazolinedione Ene Reaction and Carbanion-Assisted Cleavage of the N-N Urazole Bond
Org. Lett., 2000, 2, 1295-1297

810
Adam, W.; Peters, K. Peters, E.-M.; Stegmann, V.R.
Hydroxy-Directed Regio- and Diastereoselective [2+2] Photocycloaddition (Paterno-Büchi Reaction) of Benzophenone to Chiral Allylic Alcohols
J. Am. Chem. Soc., 2000, 122, 2958-2959

796
Adam, W.; Nikolaus, A.
Photoreduction of Polycyclic DBO-Type Azoalkane with Amines to Hydrazine Products
J. Am. Chem. Soc., 2000, 122, 884-888

751
Adam, W.; Fröhling, B.; Weinkötz, S.
Thermal and Photochemical 1,3-Dipolar Cycloaddition of Fluorenethione S-oxide (Sulfine) to the Strained Triple Bond of Cyclooctyne
J. Org. Chem., 1998, 63, 9154-9155

725
Adam, W.; Weinkötz, S.
1,3-Dipolar Cycloaddition of Fluorenethione S-Oxide and trans-Cyclooctene: Isolation of a Sultene and Its Novel Acid-Catalyzed Diastereoselective Sulfur-Atom Transfer to Cyclic Olefins
J. Am. Chem. Soc., 1998, 120, 4861-4862

718
Adam, W.; Korb, M.N.; Saha-Möller, C.R.
Optically Active Epoxy Diols by Titanium-Catalyzed Oxidation of Enantiomerically Enriched Hydroperoxy and Hydroxy Homoallylic Alcohols
Eur. J. Org. Chem., 1998, 907-912

710
Adam, W.; Nestler, B.; Pastor, A.; Wirth, T.
Hydroxy-Directed Diastereoselective Ene Reaction of Triazolinediones with Chiral Allylic Alcohols
Tetrahedron Lett., 1998, 2625

707
Peters, K.; Peters, E.-M.; Adam, W.; Ahrweiler; M.; Reinhardt, D.
Crystal Structure of 13-Acetyl-4,13-dimethyl-12-oxacylopropane-12-spiro[2,4,6]triazatricyclo-[5.2.2.0^2.6]undec-10-ene-3,5,9-trione, C₁₃H₁₃N₃O₅
Z. Kristallogr., 1998, 311-312

706
Peters, K.; Peters, E.-M.; Adam, W.; Jacob, U.; Prein, M.
Crystal Structure of anti-10-Formyl-1,4,7,8,9,10-hexamethyl-2,4,6-triazatricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione, (CH₃)₆(CHO)C₇N₃O₂
Z. Kristallogr., 1998, 309-310

705
Peters,K.; Peters, E.-M.; Adam, W.; Jacob, U.; Prein, M.
Crystal Structure of anti-1,4,7,8,9,10-hexamethyl-10-methylthio-2,4,6-triazatricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione, (CH₃)₇C₇N₃O₂S
Z. Kristallogr., 1998, 307-308

704
Peters, K.; Peters, E.-M.; Adam, W.; Nestler, B.
Crystal Structure of 2-Benzoyl-4-methyl-1-[1-(methylethenyl)-2-benzoyloxypropyl]-1,2,4-triazolidine-3,3-dione, C₂₃H₂₃N₃O₅
Z. Kristallogr., 1998, 305-306

701
Adam, W.; Wirth, T.; Pastor, A.; Peters, K.
Dramatic Diastereoselectivity in the Asymmetric Ene Reactions of Triazolinediones and Singlet Oxygen with Chiral 2,2-Dimethyloxazolidine Derivatives of Tiglic Acid
Eur. J. Org. Chem., 1998, 501-506

697
Adam, W.; Fell, R.T.; Stegmann, V.R.; Saha-Möller, C.R.
Synthesis of Optically Active a-Hydroxy Carbonyl Compounds by the Catalytic, Enantioselective Oxidation of Silyl Enol Ethers and Ketene Acetals with (Salen)manganese(III) Complexes
J. Am. Chem. Soc., 1998, 120, 708-714

637
Adam, W.; Blancafort, L.
Stereoselective Cycloaddition and Epoxidation of Enol Ethers by a-Peroxy Lactone as a Function of Steric and Stereoelectronic Effects
J. Org. Chem., 1996, 61, 8432-8438

617
Peters, K.; Peters, E.-M.; Adam, W.; Walter, H.; Sahin, C.
Crystal Structure of the anti-10-Methyl-4-methyl-2,4,6-triazatricyclo[5.2.10^2,6]dex-8-en-3,5-dione
Z. Kristallogr., 1996, 211, 433-434

614
Adam, W.; Prein, M.
The p-Facial Diastereoselectivity in the [4+2] Cycloaddition of Singlet Oxygen as Mechanistic Probe
Acc. Chem. Res., 1996, 29, 275-283

600
Adam, W.; Bottle, S.E.; Grice, I.D.; Pfeiler, D.; Wentrup, C.
The Cheletropic Trapping of Nitric Oxide by the bis-Ketene 1,2-Dicarbonylcyclohexa-3,5-diene and the Diene 3,4-Diphenyl-2,5-dimethyl-2,4-hexadiene
Tetrahedron Lett., 1996, 37, 2113-2116

591
Adam, W.; Schuhmann, R.M.
Iron Tricarbonyl Complexes in Oxidation Chemistry: Regio- and Stereoselective Oxyfunctionalization of Trienes by Singlet Oxygen and Dimethyldioxirane
J. Org. Chem., 1996, 61, 874-878

560
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rosenthal, R.J.
Crystal Structure of 6,7-Benzo-3,3-Dichloro-8-diphenylmethylenentricyclo[3.2.1.0^2.4]oct-4-ene, C₂₅H₁₈Cl₂
Z. Kristallogr., 1995, 210, 613-614

551
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rosenthal, J.
Crystal Structure of N-Methyl-anti-7-Carboethoxy-2,3-diazabicyclo[2.2.1]hept-5-ene-2,3-carboximide, C₁₂H₁₅N₃O₄
Z. Kristallogr., 1995, 210, 545-546

545
Adam, W.; Jacob, U.; Prein, M.
Importance of Steric Effects in the [4+2] Cycloaddition of 5-Substituted Pentamethylcyclopentadienes
Chem. Commun., 1995, 839-840

529
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Seguchi, K.
Crystal Structure of N-phenyl-2,3-diaza-5-(E)-carbomethoxymethylenetricyclo-[4.3.0.0^4,9]nonane-2,3dicarboximide, C₁₈H₁₇N₃O₄
Z. Kristallogr., 1995, 210, 160-161

528
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Seguchi, K.
Crystal Structure of N-phenyl-7,8-benzo-5-(E)-methylmethylene-2,3-diazatricyclo-[4.4.0.0^4,9]non-2-enedicarboximide, C₂₁H₁₇N₃O₂
Z. Kristallogr., 1995, 210, 158-159

489
Adam, W.; Prein, M.
Substituent Effects in the Diastereoselective [4+2] Cycloaddition of Chiral Naphthalene Derivatives with Singlet Oxygen
Tetrahedron Lett., 1994, 35, 4331-4334

450
Adam, W.; Nava Salgado, V.O.; Peters, E.-M.; Peters, K.; von Schnering H.-G.
Synthesis of a,b-trans-Spiro-b-lactones by Diels-Alder of 1,3-Dienes to a-Methylene-b-lactone and their Decarboxylation by Pyrolysis to (E)-Alkylidenecycloalkenes, a Convenient Olefination Method
Chem. Ber., 1993, 126, 1481-1486

446
Adam, W.; Prein, M.
Diastereoselective [4+2] Cycloaddition of Singlet Oxygen in the Photooxygenation of Chiral Naphthyl Alcohols: Evidence for a Hydroxy Group-Directing Effect
J. Am. Chem. Soc., 1993, 115, 3766-3767

434
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Hill, K.
Crystal Structure of (Z-8-Phenylmethylene-4,5-diazatricyclo-[4.3.0.03,7]non-4-ene
Z. Kristallogr., 1993, 203, 101-103

393
Adam, W.; Griesbeck, A.G.; Klug, P.; Nestler, B.; Richter, M.; Wang, X.
Selective Oxygen Transfer I: Singlet Oxygen
In Selective Reactions of Metal Activated Molecules; H.Werner; A.G.Griesbeck; W.Adam; G.Bringmann, W.Kiefer, Eds.; Vieweg Ver 1992; pp 149-152

381
Adam, W.; Hasemann, L.
a-Methylene-b-Lactones as Novel Allene Equivalents: Regioselective [4+2] Cycloaddition and Stereoselective Decarboxylation for the Introduction of exo-Alkylidene Functionalitites
Tetrahedron Lett., 1991, 32, 7033-7036

370
Adam, W.; Albert, R.; Hasemann, L.; Nava Salgado, V.O.; Nestler, B.; Peters, E.M.; Peters, K.; Prechtl, F.; von Schnering, H.G.
a-Methylene-b-lactones as Masked Allenes and Allene Equivalents: Some Selected Chemical Transformations
J. Org. Chem., 1991, 56, 5782-5785

367
Adam, W.; Bottle, S.E.; Peters, K.
Cycloaddition of Nitrosobenzene to a Trimethylenemethane Diradical: The First Case of Isoxazoline Formation from in situ Generated Nitroxides through Spin Trapping
Tetrahedron Lett., 1991, 32, 4283-4286

351
Adam, W.; Hadjiarapoglou, L.; Mosandl, T.; Saha-Möller, C.R.; Wild, D.
Synthesis of 2,3-Epoxide of 2,3-Dimethylbenzo[b]furan, the Proposed Ultimate Mutagen of the Benzofuran Dioxetanes
Angew. Chem., 1991, 103, 187-189; Angew. Chem., Int. Ed. Engl., 1991, 30, 200-202

333
Adam, W.; Grabowski, S.; Wilson, R.M.
Localized Cyclic Triplet Diradicals. Lifetime Determination by Trapping with Molecular Oxygen
Acc. Chem. Res., 1990, 23, 165-172

331
Adam, W.; Wang, X.
Photooxygenation of 1,2-Bis(Silyloxy)cycloalkenes
Tetrahedron Lett., 1990, 31, 1245-1248

323
Adam, W.; Platsch, H.; Wirz, J.
Oxygen Trapping and Thermochemistry of a Hydrocarbon Singlet Biradical: 1,3-Diphenylcyclopentane-1,3-diyl
J. Am. Chem. Soc., 1989, 111, 6896-6898

320
Adam, W.; Grabowski, S.; Wilson, R.M.
UV-Laser Photochemistry: Trapping of the Norrish Type II Triplet Diradical 1-Hydroxy-4-methyl-1-phenyl-1,4-pentanediyl with Molecular Oxygen
Chem. Ber., 1989, 122, 561-564

317
Adam, W.; Lucchini, V.; Peters, M.-E.; Peters, K.; Pasquato, L.; von Schnering, H.G.; Seguchi, K.; Walter, H.; Will, B.
Cycloaddition of 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD) to 7-Alkylidene-2,3-benzonorbornadienes
Chem. Ber., 1989, 122, 133-143

306
Adam, W.; Kliem, U.; Lucchini, V.
Preparative UV-Vis Laser Photochemistry: Photocycloaddition of Methylenelactones with Benzophenone and p-Benzoquinone. Oxygen Trapping of Paterno-Büchi Triplet 1,4-Diradicals as Model Reactions for Qinghaosu-Type 1,2,4-Trioxanes
Liebigs Ann. Chem., 1988, 869-875

304
Adam, W.; Schwarm, M.
How Mechanistically Equivalent are Singlet Oxygen and Triazolinedione? Regiochemical and Stereochemical Differences in their Ene Reactions with Allyl Silanes
J. Org. Chem., 1988, 53, 3129-3130

302
Adam, W.; Kliem, U.; Lucchini, V.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
[4+2] Cycloaddition of Disubstituted Homobenzoquinones with Cyclopentadiene
Chem. Ber., 1988, 121, 1063-1067

278
Adam, W.; Carballeira, N.; Crämer, E.; Lucchini, V.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
1,3-Dipolar Cycloadditions with the Keto- and Spirocyclopropane-Substituted Norbornenes Bicyclo[2.2.1]hept-5-en-2-one and Spiro(bicyclo[2.2.1]hept-5-ene-2,1'-cyclopropane)
Chem. Ber., 1987, 120, 695-703

277
Adam, W.; De Lucchi, O.; Pasquato, L.; Will, B.
Cycloaddition Behavior of 2-Substituted Norbornadienes towards 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD): Homo Diels-Alder Reactivity versus Insertion, Rearrangement and [2+2] Cycloaddition
Chem. Ber., 1987, 120, 531-535

266
Adam, W.; Lucchini, V.; Pasquato, L.; Peters, E.-M.; Peters, K.; von Schnering, H.G.; Seguchi, K.
Unusual Rearrangement in the Cycloaddition of 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD) with Substituted 7-Methylenenorbornenes
Chem. Ber., 1986, 119, 2932-2941

265
Adam, W.; Dörr, M.
Synthesis of Urazoles via Cycloaddition by Employing 4-Phenyl-4H-1,2,4-triazole-3,5-dione (PTAD) Transfer
Synthesis, 1986, 854-855

249
Adam, W.; Berkessel, A.; Krimm, S.
Synthesis and Homo-Diels-Alder Cleavage of the Epoxyazoalkane exo-3-Oxa-6,7-diazatricyclo[3.2.1.02,4]oct-6-ene
Chem. Ber., 1985, 118, 5018-5023

246
Adam, W.; Platsch, H.; Schmidt, E.
Synthesis, Thermal Stability, and Chemiluminescence Properties of Bisdioxetanes Derived from p-Dioxins
Chem. Ber., 1985, 118, 4385-4403

238
Adam, W.; Klug, G.; Peters, E.-M.; Peters, K.; von Schnering, H.G.
Synthesis of Endoperoxides Derived from Cyclooctatetraenes via Singlet Oxygenation
Tetrahedron, 1985, 41, 2045-2056

225
Adam, W.; Gretzke, N.; Klug, G.
Thermolysis of 7,8-Dioxabicyclo[4.2.2]deca-2,4,9-trienes. An Unusual Decomposition Mode of Endoperoxides
J. Am. Chem. Soc., 1984, 106, 4300-4301

222
Adam, W.; Carballeira, N.
On the Mechanism of the Cycloaddition of 1,2,4-Triazoline-3,5-diones with Bicycloalkenes Leading to Rearranged Urazoles
J. Am. Chem. Soc., 1984, 106, 2874-2882

218
Adam, W.; Rebollo, H.
Substituent, Temperature and Solvent Effects in the Singlet Oxygenation of 7-Alkyl- and 7-Aryl-substituted 1,3,5-Cycloheptatrienes
Israel. J. Chem., 1984, 23, 399-404

209
Adam, W.; Beinhauer, A.; De Lucchi, O.; Rosenthal, R.J.
Dienophilic and Dipolar Additions to Bicyclo(2.1.0)pent-2-ene
Tetrahedron Lett., 1983, 24, 5727-5730

199
Adam, W.; Arias Encarnacion, L.A.; Zinner, K.
Thermal Stability of Spiro(adamantane-1,2-dioxetanes)
Chem. Ber., 1983, 116, 839-846

195
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rebollo, H.
Crystal Structure of 4-Phenyl-2,4,6-triazatricyclo[5.3.2.0^2,6]dodeca-9,11-dien-3,5,8-trione
Z. Kristallogr., 1982, 160, 149-152

194
Peters, K.; Peters, E.-M.; von Schnering, H.G.; Adam, W.; Rebollo, H.
Crystal Structure of 4-Phenyl-2,4,6-triazatetracyclo(5.3.2.0^2,6.0^8,10)dodec-11-ene-3,5-dione
Z. Kristallogr., 1982, 160, 145-148

187
Adam, W.; Klug, G.
The Synthesis of the Endoperoxide of Cyclooctatetraene via Photosensitized Singlet Oxygenation
Tetrahedron Lett., 1982, 23, 3155-3158

186
Adam, W.; Arias Encarnacion, L.A.
The Synthesis of Spiro(adamanantane-1,2-dioxetanes)
Chem. Ber., 1982, 115, 2592-2605

183
Adam, W.; Arias, L.A.; Scheutzow, D.
Spiroadamantyl Stabilization of Sulfur-Substituted 1,2-Dioxetanes
Tetrahedron Lett., 1982, 23, 2835-2836

179
Adam, W.; De Lucchi, O.; Hill, K.
Reaction of 4-Phenyl-1,2,4-triazoline-3,5-dione (PTAD) with Bicyclic Monoterpenes
Chem. Ber., 1982, 115, 1982-1989

178
Adam, W.; Cueto, O.; De Lucchi, O.
[4+2]-Cycloaddition of Singlet Oxygen and Phenyltriazolinedione with Bicyclo[6.1.0]nona-2,4,6-triene and Derivatives
Chem. Ber., 1982, 115, 1170-1177

176
Adam, W.; De Lucchi, O.; Peters, K.; Peters, E.-M.; von Schnering, H.G.
Reaction of Bicyclo(3.2.1)octa-2,6-diene with 1,2,4-Triazoline-3,5-diones: Competitive Dipolar and Homocycloaddition
J. Am. Chem. Soc., 1982, 104, 161-166

175
Adam, W.; Arias, L.A.; De Lucchi, O.
Unusual Cycloaddition Behavior of 2-Substituted Norbornadienes with Triazolinediones
Tetrahedron Lett., 1982, 23, 399-402

170
Adam, W.; De Lucchi, O.; Scheutzow, D.
Cycloaddition of Substituted Bicyclo(3.2.1)octa-2,6-diene with 4-Phenyl-1,2,4-triazoline-3,5-dione
J. Org. Chem., 1981, 46, 4130-4132

167
Adam, W.; Zinner, K.; Krebs, A.; Schmalstieg, H.
Electron-Exchange Chemiluminescence from a Sterically Stabilized Cyclobutadiene-1,2-dioxetane
Tetrahedron Lett., 1981, 22, 4567-4570

164
Adam, W.; Rodriguez, A.
Intramolecular Silyl Migration in the Singlet Oxygenation of 2-Methyl-5-trimethylsilylfuran
Tetrahedron Lett., 1981, 22, 3505-3508

163
Adam, W.; De Lucchi, O.
Reaction of Bicyclo[3.2.1]octadiene with 4-Methyl-1,2,4-triazoline-3,5-dione: Competitive Dipolar and Homo Cycloaddition
Tetrahedron Lett., 1981, 22, 3501-3504

152
Adam, W.; De Lucchi, O.
[2+2]-Cycloaddition of Triazolinediones to Strained Bicycloalkenes
Tetrahedron Lett., 1981, 22, 929-932

148
Adam, W.; Balci, M.; Pietrzak, B.; Rebollo, H.
Oxygen Functionalization of Cycloheptatriene via Sensitized Photooxygenation
Synthesis, 1980, 10, 820-823

146
Adam, W.; De Lucchi, O.
The Synthesis of Unusual Organic Molecules from Azoalkanes
Angew. Chem., 1980, 92, 815-832; Angew. Chem., Int. Ed. Engl., 1980, 19, 762-779

141
Adam, W.; Balci, M.
Cyclic Polyepoxides: Synthetic, Structural and Biological Aspects
Tetrahedron, 1980, 36, 833-858

134
Adam, W.; Balci, M.
The Stereoselective Synthesis of the Three Trioxides of 1,3,5-Cycloheptatriene via the Endoperoxide-Diepoxide Rearrangement
J. Am. Chem. Soc., 1980, 102, 1961-1966

133
Adam, W.; Balci, M.
Stereoselective Synthesis of Cycloheptatriene Trioxides
Angew. Chem., 1980, 92, 54-55; Angew. Chem., Int. Ed. Engl., 1980, 19, 48-49

131
Adam, W.; Rodriguez, A.
Oxygen-Atom Transfer by Furan Endoperoxides
J. Am. Chem. Soc., 1980, 102, 404-406

129
Adam, W.; Balci, M.; Rivera, J.
A Convenient Synthesis of Homobenzoquinones
Synthesis, 1979, 807-808

128
Adam, W.; Balci, M.
Photooxygenation of 1,3,5-Cycloheptatriene: Transformation of Endoperoxides
J. Am. Chem. Soc., 1979, 101, 7542-7547

127
Adam, W.; Balci, M.
Photooxygenation of 1,3,5-Cycloheptatrine: Isolation and Characterization of Endoperoxides
J. Am. Chem. Soc., 1979, 101, 7537-7541

124
Adam, W.; De Lucchi, O.; Quast, H.; Recktenwald, R.; Yany, F.
A 3-Imino-1,2-dioxetane via Singlet Oxygenation of a Ketenimine
Angew. Chem., 1979, 91, 855-856; Angew. Chem., Int. Ed. Engl., 1979, 18, 788-789

123
Adam, W.; De Lucchi, O.
Cycloaddition of 4-Phenyl-1,2,4-triazoline-3,5-dione (PTAD) to Bicycloalkenes via Rearrangement of Zwitterionic Intermediates
Tetrahedron Lett., 1979, 4367-4370